六氟钛酸钠

六氟钛酸钠 基本信息
CAS号 17116-13-1 分子式 F6Na2Ti
分子量 207.83700 精确质量  207.91800
PSA  0.00000 LogP  2.52120

基本信息 展开↓

CAS号:
17116-13-1
分子式:
F6Na2Ti
分子量:
207.83700
中文名称:
六氟钛酸钠
英文名称:
disodium,hexafluorotitanium(2-)
中文别名:
六氟钛酸钠;
六氟钛磷酸钠
英文别名:
disodium,hexafluorotitanium(2-);
disodium hexafluorotitaniumdiuide;
PC6514
精确分子量/精确质量:
207.91800
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00014244
EINECS:
241-181-8

物化性质展开↓

外观与性状:
白色结晶粉末
熔点:
146-156 °C(lit.)
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

安全信息展开↓

危险类别码:
R36/37/38
安全说明:
S37/39-S26-S45-S36/37/39-S36
危险标志:
Xi: Irritant;C: Corrosive;

毒理性展开↓

生态数据:

 

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Sodium hexafluorotitanate (IV), 98%    
   CAS Registry Number:       17116-13-1    
   Formula:       Na2TiF6    
   EINECS Number:       241-181-8    
   Chemical Family:       halometallate salts    
   Synonym:       Disodium hexafluorotitanate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       17116-13-1       100%       2.5mg/m3 (as F)       2.5mg/m3 (as F)    

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. If inhaled or swallowed, this compound may cause fluoride
   Emergency Overview:
   poisoning. Early symptoms include nausea, vomiting, diarrhea, and weakness
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Causes irritation and serious eye damage. Effects may not immediately appear.    
   Causes irritation, with redness and pain. Soluble fluoride may be corrosive. Effects may not appear
   Skin Contact:
   immediately
   Inhalation of causes severe irritation to the respiratory tract, causing coughing, sore throat, and labored
   Inhalation:
   breathing.
   Ingestion:       May cause salivation, nausea, vomiting, diarrhea, and abdominal pain.    
   Irritating to skin, eyes and respiratory tract. Fluoride poisoning may cause nausea, vomiting, diarrhea,
   Acute Health Affects:
   weakness, coma, respiratory failure and cardiovascular collapse.
   Chronic Health Affects:       Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
   Skin Exposure:
   or water soluble calcium salts as antidote. Seek medical assistance.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       None. Material is non-flammable.    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       If involved in a fire this material may emit corrosive fumes of hydrofluoric acid.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid
   Spill and Leak Procedures:       raising dust. Spillage in areas not adequately ventilated may require an evacuation of area. Emergency    
   response teams will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed non-glass container away from moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       The material must be handled in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       The material must be handled in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white pwdr.    
   Molecular Weight:       207.87    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals and strong mineral acids    
   Decomposition Products:       Hydrofluoric acid, metal fluorides and metal oxyfluorides    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:7

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:9

8.表面电荷:0

9.复杂度:62.7

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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