1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯

1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯 基本信息
CAS号 87121-06-0 分子式 C10H22O2Si2
分子量 230.45100 精确质量  230.11600
PSA  18.46000 LogP  3.71680

基本信息 展开↓

CAS号:
87121-06-0
3D弹球模型:
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分子式:
C10H22O2Si2
分子量:
230.45100
中文名称:
1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯
英文名称:
trimethyl(1-trimethylsilyloxybuta-1,3-dienoxy)silane
中文别名:
1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯
英文别名:
trimethyl(1-trimethylsilyloxybuta-1,3-dienoxy)silane;
3,5-Dioxa-2,6-disilaheptane,2,2,6,6-tetramethyl-4-(2-propen-1-ylidene);
3,5-Dioxa-2,6-disilaheptane,2,2,6,6-tetramethyl-4-(2-propenylidene)-(9CI);
1,1-bis(trimethylsilyloxy)-buta-1,3-diene;
ketene bis(trimethylsilyl)acetal of crotonic acid;
1,1-BIS(TRIMETHYLSILYLOXY)-1,3-BUTADIENE
精确分子量/精确质量:
230.11600
极性分子表面积/PSA:
18.46000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: KRDZQGWHCOOABR-UHFFFAOYSA-N

物化性质展开↓

沸点:
80ºC (11 mmHg)

安全信息展开↓

海关代码:
2931900090
安全说明:
24/25

合成路线查看所有的合成路线

  • 75-77-4

    三甲基氯硅烷

  • +

  • 18269-64-2

    三甲基甲硅烷丁烯酸酯

  • ~74%

  • 87121-06-0

    1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯

  • 75-77-4

    三甲基氯硅烷

  • +

  • 88239-44-5

    trimethylsilyl but-2-enoate

  • ~9%

  • 87121-06-0

    1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯

  • 107-93-7

    巴豆酸

  • +

  • 999-97-3

    六甲基二硅氮烷

  • 87121-06-0

    1,1-双(三甲基甲硅烷基氧基)-1,3-丁二烯

MSDS 展开↓

Name: 1 1-Bis(trimethylsilyloxy)-1 3-butadiene Material Safety Data Sheet
Synonym: None
CAS: 87121-06-0
Section 1 - Chemical Product   MSDS Name:1 1-Bis(trimethylsilyloxy)-1 3-butadiene Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
87121-06-0 1,1-Bis(trimethylsilyloxy)-1,3-butadie 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 87121-06-0: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 80 deg C @ 11 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H22O2Si2
Molecular Weight: 230.45

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 87121-06-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,1-Bis(trimethylsilyloxy)-1,3-butadiene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 87121-06-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 87121-06-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 87121-06-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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