N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸

N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸 基本信息
CAS号 145206-40-2 分子式 C12H17NO5
分子量 255.26700 精确质量  255.11100
PSA  88.77000 LogP  2.19090

基本信息 展开↓

CAS号:
145206-40-2
3D弹球模型:
立即前往扯扯看
分子式:
C12H17NO5
分子量:
255.26700
中文名称:
N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸
英文名称:
BOC-L-2-FURYLALANINE DCHA SALT
中文别名:
N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸;
BOC-L-2-呋喃丙氨酸二环己胺盐;
Boc-l-3-(2-呋喃基)丙氨酸
英文别名:
BOC-L-2-FURYLALANINE DCHA SALT;
Boc-furan-OH;
BOC-L-2-FURYLALANINE-DCHA
精确分子量/精确质量:
255.11100
极性分子表面积/PSA:
88.77000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
InChI=1/C12H17NO5.C12H23N/c1-12(2,3)18-11(16)13-9(10(14)15)7-8-5-4-6-17-8;1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h4-6,9H,7H2,1-3H3,(H,13,16)(H,14,15);11-13H,1-10H2/t9-;/m1./s1

物化性质展开↓

沸点:
406.4ºC at 760mmHg
闪点:
199.6ºC
蒸汽压:
1.65E-14mmHg at 25°C

安全信息展开↓

海关代码:
2932190090
安全说明:
S24/25
危险标志:
Xi

合成路线查看所有的合成路线

  • 24424-99-5

    二碳酸二叔丁酯

  • +

  • 121786-31-0

    3-(2-呋喃基)-L-丙氨酸

  • ~99%

  • 145206-40-2

    N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸

  • 251325-69-6

    (S)-tert-butyl (1-(furan-2-yl)-3-hydroxypropan-2-yl)carbamate

  • ~44%

  • 145206-40-2

    N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸

  • 849340-21-2

    methyl (Z)-2-((tert-butoxycarbonyl)amino)-3-(furan-2-yl)acrylate

  • 145206-40-2

    N-叔丁氧羰基-L-3-(2-呋喃基)丙氨酸

MSDS 展开↓

Name: (S)-N-BOC-2-Furylalanine, 95%, (98% E.E.) Material Safety Data Sheet
Synonym: N-tert-Butoxycarbonyl-2-Furyl-L-Alanine.
CAS: 145206-40-2
Section 1 - Chemical Product MSDS Name: (S)-N-BOC-2-Furylalanine, 95%, (98% E.E.) Material Safety Data Sheet
Synonym: N-tert-Butoxycarbonyl-2-Furyl-L-Alanine.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
145206-40-2 (S)-N-BOC-2-Furylalanine 95% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
SECTION 4 - FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 145206-40-2: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Viscous liquid
Color: orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H17NO5
Molecular Weight: 255.27
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 145206-40-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(S)-N-BOC-2-Furylalanine - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 145206-40-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 145206-40-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 145206-40-2 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 1/16/2002 Revision #2 Date: 10/05/2004 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2932190090

概述:
2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

上下游相关产品

上游产品

更多
  • 24424-99-5

    二碳酸二叔丁酯

  • 121786-31-0

    3-(2-呋喃基)-L-丙氨酸

  • 251325-69-6

    (S)-tert-butyl (1-(furan-2-yl)-3-hydroxypropan-2-yl)carbamate

  • 867193-17-7

    tert-butyl (4S)-4-(2-hydroxybut-3-en-1-yl)-2,2-dimethyloxazolidine-3-carboxylate

  • 867193-18-8

    tert-butyl (4S)-4-(2-(allyloxy)but-3-en-1-yl)-2,2-dimethyloxazolidine-3-carboxylate

立即下载安装“化学加”APP
专业、功能强大,随时调用更加方便