硅化铁

硅化铁 基本信息
CAS号 12022-99-0 分子式 FeH4Si2
分子量 116.04800 精确质量  115.92000
PSA  0.00000 LogP  -1.83490

基本信息 展开↓

CAS号:
12022-99-0
分子式:
FeH4Si2
分子量:
116.04800
中文名称:
硅化铁
英文名称:
IRON SILICIDE
中文别名:
硅化铁;
二硅化铁, 99.9% (METALS BASIS);
二硅化铁
英文别名:
IRON SILICIDE;
Ironsilicide;
Ironsilicidegraypowder;
Iron disilicide;
iron disilicide;
Iron silicon;
Iron disilicon;
Iron silicide
精确分子量/精确质量:
115.92000
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00016087
EINECS:
234-671-8

生产制备方法及用途展开↓

制备方法


将摩尔比为1∶2的铁粉与硅粉混匀,在真空或惰性气氛中共熔或烧结。

合成制备方法


将摩尔比为1∶2的铁粉与硅粉混匀,在真空或惰性气氛中共熔或烧结。

用途简介


用作氢的催化氧化、甲烷化催化剂。

用途


用作氢的催化氧化、甲烷化催化剂。

物化性质展开↓

密度:
4.75
熔点:
1220ºC
存储条件/存储方法:

常温密闭,阴凉通风干燥处

稳定性相关:

常温常压下稳定

避免光,明火,高温。钢灰色的不透明体。在EtONa存在下与EtOH反应生成Si(OEt)4。用作焊接助熔剂的脱氧剂、湿度传感器、FeSi2热电偶、热电太阳能电池。

其它信息:

1.       性状:灰色粉末,无气味,四方晶

2.       密度(g/mL,25℃):4.79

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):1220

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,1mmHg):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:不溶于水

安全信息展开↓

安全说明:
S26-S37
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S37:使用合适的防护手套。

毒理性展开↓

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Iron silicide, 99%    
   CAS Registry Number:       12022-99-0    
   Formula:       FeSi2    
   EINECS Number:       234-671-8    
   Chemical Family:       metal silicide    
   Synonym:       Ferrosilicon    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       12022-99-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin and eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May be a mild to severe irritant to the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Do not breath dust. Inhalation of powder may lead to irritation of the respiratory tract.    
   Ingestion:       Ingestion may lead to vomiting, and diarrhea.    
   Acute Health Affects:       May be irritating to skin, eyes, mucous membranes and respiratory tract. Do not breath dust.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may produce silica dust.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable solid. Dust may form explosive mixtures with air. Evolves flammable hydrogen with steam.

SECTION 6: Accidental Release Measures
   In the case of a spill, the material should be covered with dry soda ash, limestone, or sand. Place in open
   Spill and Leak Procedures:
   container. Flammable hydrogen evolution may occur if wet.

SECTION 7: Handling and Storage
   Store in a tightly sealed container in a cool dry place. Use good housekeeping practice to avoid accumulation
   Handling and Storage:
   of spilled dust, a fire hazard.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       gray pwdr.    
   Molecular Weight:       112.02    
   Melting Point:       1220 °C    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       4.75    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Mixtures of fine dust with air. Contact with an ignition source.    
   Incompatibility:       Oxidizing agents and halogens    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:3

8.表面电荷:0

9.复杂度:18.3

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

立即下载安装“化学加”APP
专业、功能强大,随时调用更加方便