三氯化镨七水

三氯化镨七水 基本信息
CAS号 10025-90-8 分子式 CH15Cl3O7
分子量 245.48500 精确质量  243.98800
PSA  64.61000 LogP  1.53630

基本信息 展开↓

CAS号:
10025-90-8
分子式:
CH15Cl3O7
分子量:
245.48500
中文名称:
三氯化镨七水
英文名称:
praseodymium(3+),trichloride,heptahydrate
中文别名:
三氯化镨七水;
氯化镨;
氯化镨七水合物;
氯化镨(III) 七水合物
英文别名:
praseodymium(3+),trichloride,heptahydrate;
PRASEODYMIUM CHLORIDE HEPTAHYDRATE;
PRASEODYMIUM CHLORIDE HYDRATE;
praseodymiumchlorideheptahydrate99.9;
PRASEODYMIUM CHLORIDE,HYDROUS
精确分子量/精确质量:
243.98800
极性分子表面积/PSA:
64.61000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。

生产制备方法及用途展开↓

制备方法


适量镨氧化物溶解于过量的2mol/L HCl中,煮沸使进一步浓缩后,在盛无水硫酸钙的保干器中放置数星期后析出晶体。

合成制备方法


适量镨氧化物溶解于过量的2mol/L HCl中,煮沸使进一步浓缩后,在盛无水硫酸钙的保干器中放置数星期后析出晶体。

用途简介


物化性质展开↓

密度:
2.25 g/cm3
熔点:
115ºC
存储条件/存储方法:

2-8°C密闭、阴凉干燥处

稳定性相关:

易吸湿,溶解度334g/100g H2O(13℃)。180~200℃下在HCl气流中加热可以脱掉七个水。

其它信息:

1.       性状:绿色晶体

2.       密度(g/mL,25℃):2.250

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC): 115

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

安全信息展开↓

危险类别码:
R36/37/38
安全说明:
26-36-37/39
危险标志:
Xi: Irritant;

化学图谱

  1. 三氯化镨七水红外图谱(IR1)

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MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Praseodymium (III) chloride heptahydrate (99.9%-Pr) (REO)    
   CAS Registry Number:       10025-90-8    
   Formula:       PrCl3.7H2O    
   EINECS Number:       233-794-4    
   Chemical Family:       metal halide    
   Synonym:       Praseodymium trichloride, hexahydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10025-90-8       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin and eyes. Inhalation can lead to irritation of the respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes mild irritation to the eyes.    
   Skin Contact:       Causes slight irritation of the skin.    
   Inhalation:       Inhalation of dust can lead to irritation of the respiratory tract.    
   Ingestion:       No information is available on the physiological effects of ingestion in humans    
   Acute Health Affects:       Irritating to skin and eyes.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       Material is non-flammable.    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate powder and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store material in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       green xtl.    
   Molecular Weight:       247.27(373.38)    
   Melting Point:       115°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       2.25    
   Odor:       none    
   Solubility in Water:

SECTION 10: Stability and Reactivity
   Stability:       hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       Active metals    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:371.888111 Da

8、标称质量:372 Da

9、平均质量:373.3736 Da

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:7

3.氢键受体数量:10

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积7

7.重原子数量:11

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:11

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