(s)-(O-(N-苄基脯氨基酸)氨基I(苯基)..N,N,N-镍

(s)-(O-(N-苄基脯氨基酸)氨基I(苯基)..N,N,N-镍 基本信息
CAS号 96293-19-5 分子式 C27H25N3NiO3
分子量 498.19900 精确质量  497.12500
PSA  62.21000 LogP  3.43190

基本信息 展开↓

CAS号:
96293-19-5
3D弹球模型:
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分子式:
C27H25N3NiO3
分子量:
498.19900
中文名称:
(s)-(O-(N-苄基脯氨基酸)氨基I(苯基)..N,N,N-镍
英文名称:
(s)-(o-(N-benzylprolyl)amino)(phenyl)methyleneiminoacetate
中文别名:
(s)-(O-(N-苄基脯氨基酸)氨基I(苯基)..N,N,N-镍;
[N-[苯基[2-[[[1-苄基-2-吡咯烷基]羰基]氨基]苯基]亚甲基]甘氨酸(2-)-N,N',N'',O1]-镍;
(S)-(o-(n-苄基脯氨酰)氨基)(苯基)亚甲基亚氨基乙酸酯;
(S)-(O-(N-苄基脯氨基酸)氨基I(苯基)..N,N,N-镍
英文别名:
(s)-(o-(N-benzylprolyl)amino)(phenyl)methyleneiminoacetate;
(S)-2-{o-{(N-benzylprolyl)aMino}phenyl}-benzylideneaMino-acetato(2-)-N,N',N''-nickel(II);
NI-(S)-BPB-GLY;
Ni-(S)-BPB-GLy(S)-[O-[(N-Benzylprolyl)amino](phenyl)methyleneiminoacetate(2-)-N,N',N''-nickel(II);
(S)-O-[(N-BENZYLPROLYL)AMINO](PHENYL)METHYLENEIMINOACETATE(2)-N,N',N''-NICKEL(II);
(s)-(o-(N-benzylprolyl)amino)(phenyl);
[N-[Phenyl[2-[[[1-(phenylmethyl)-2-pyrrolidinyl]carbonyl]amino]phenyl]methylene]glycinato(2-)-N,N',N'',O1]-nickel
精确分子量/精确质量:
497.12500
极性分子表面积/PSA:
62.21000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: AXOAXZULMRICBL-UHFFFAOYSA-L

物化性质展开↓

熔点:
219-222ºC
折射率:
1.62

安全信息展开↓

安全说明:
S24/25

MSDS 展开↓

Name: Ni-(S)-BPB-GLy 99% Material Safety Data Sheet
Synonym:
CAS: 96293-19-5
Section 1 - Chemical Product   MSDS Name:Ni-(S)-BPB-GLy 99% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
96293-19-5 Ni-(S)-BPB-GLy 99 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 96293-19-5: United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL (as Ni) Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA (inhalable fraction, as Ni) Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC Ni) Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: bordeux
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 219.00 - 222.00 deg C
Autoignition Temperature: > 250 deg C (> 482.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >250 deg C
Solubility in water: insoluble
Specific Gravity/Density: Not available.
Molecular Formula: C27H25N3NiO3
Molecular Weight: 498.20

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 96293-19-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ni-(S)-BPB-GLy - California: carcinogen, initial date 5/7/04 (listed as Nickel compound NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 96293-19-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 96293-19-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96293-19-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
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