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Section 1. Chemical Product and Company Identification
    Barium Chlorate, Monohydrate
    Common Name/
    Trade Name
    Barium Chlorate, Monohydrate
    Potential Chronic Health        CARCINOGENIC EFFECTS: Not available.    
    MUTAGENIC EFFECTS: Not available.
    Effects
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    The substance may be toxic to blood, kidneys, lungs.
    Repeated or prolonged exposure to the substance can produce target organs damage.

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Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for    
    at least 15 minutes. Cold water may be used. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.    
    Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly
    clean shoes before reuse. Get medical attention.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate    
    medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.    
    Get medical attention.
    Serious Inhalation        Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth
    resuscitation when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen
    tight clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

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Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Products of Combustion        Not available.    
    Fire Hazards in Presence of of organic materials of combustible materials
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of static discharge: Not available.
    of Various Substances        Slightly explosive in presence of shocks, of heat, of combustible materials, of organic materials.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Powerful oxidizing agent; may ignite oxidizable materials. Contact with combustible or organic materials may    
    Fire Hazards        cause fire.    
    A mixture of sulfur and barium chlorate ignites at about 108-111 C.
    Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts,
    spontaneous decomposition and ignition may result.
    Special Remarks on Explosion A combination of finely divided aluminum, arsenic, carbon, copper, metal sulfides, organic matter,
    Hazards        phosphorus, or sulfur with finely divided chlorates of barium can be exploded by heat, percussion, and    
    sometimes light friction.
    Contact with strong sulfuric acid can cause fires or explosions.
    Mixtures of finely divided combustible materials (such as certain dusty forms of floor sweepings/saw dust),
    charcoal with chlorates can explode virtually spontaneously.
    Chlorates can also present a dangerous explosion hazard when shocked, exposed to heat, or rubbed,
    particularly when contaminated with As2S3, CaH2, Hg3P4, Manganese dioxide, NaH2PO2, PHI4, SCN,
    ammonium compounds, cyanides, metals + acids, organic acids, phosphorus or antimony sulfide, selenium,
    shellac, starch, sugar.
    Barium Chlorate, Monohydrate

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Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container.    
    Large Spill        Oxidizing material. Organic peroxide.    
    Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep
    substance damp using water spray. Do not use metal tools or equipment. Do not touch spilled material. Use
    for assistance on disposal. Be careful that the product is not present at a concentration level above TLV.
    Check TLV on the MSDS and with local authorities.

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Section 7. Handling and Storage
    Precautions        Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do not    
    ingest. Do not breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately
    and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such
    as reducing agents, combustible materials, organic materials, metals, acids.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies,    
    reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers.

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Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
    exposure to airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be
    a Large Spill        used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a    
    specialist BEFORE handling this product.
    TWA: 0.5 (mg(Ba)/m3) from OSHA (PEL) [United States]
    Exposure Limits
    Consult local authorities for acceptable exposure limits.

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Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Crystals solid. Powdered solid.)        Odorless.    
    Odor
    Taste        Not available.    
    Molecular Weight        322.26 g/mole    
    Color        White.    
    pH (1% soln/water)        Not available.    
    Boiling Point        Not available.    
    250°C (482°F)
    Melting Point
    Critical Temperature        Not available.    
    Density: 3.179 (Water = 1)
    Specific Gravity
    Not applicable.
    Vapor Pressure
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Not available.
    Ionicity (in Water)
    Dispersion Properties        See solubility in water.    
    Solubility        Soluble in cold water.    
    Very slightly soluble in acetone.
    Solubility in Water: 27.4 g/100 ml water at 15 deg. C.; 111.2 g/100 ml water at 100 deg. C.
    Slightly soluble in alcohol, Hydrochloric acid.
    Moderately soluble in Ethylamine.
    Practically insoluble in Ethyl acetate, Pyridine.
    Barium Chlorate, Monohydrate

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Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Instability Temperature        Not available.    
    Conditions of Instability        Incompatible materials    
    Incompatibility with various        Highly reactive with reducing agents, combustible materials, organic materials, metals, acids.    
    substances
    Not available.
    Corrosivity
    Special Remarks on        Loses its water of hydration at 120 C. Gives off oxygen at 250 C.    
    Reactivity        Incompatible with combustible materials (oil, wood, paper, leather, chlothing), finely powedered metals,    
    aluminum
    Not available.
    Special Remarks on
    Corrosivity
    Polymerization        Will not occur.    

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Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans May cause damage to the following organs: blood, kidneys, lungs.
    Other Toxic Effects on        Hazardous in case of skin contact (irritant), of ingestion.    
    Humans        Slightly hazardous in case of inhalation.    
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: Causes skin irritation.    
    Eyes: Causes eye irritation.
    Inhalation: May cause respiratory tract irritation.
    Ingestion: Harmful if swallowed. Causes abdominal cramping, nausea, vomiting, diarrhea or colic. In very
    acute or fatal cases the following may occur: pale complexion (pallor), hypotension (low blood pressure),
    irregular heartbeat, hemolysis with methemoglobin formation which reduces the oxygen carrying capacity of
    the blood resulting in cyanosis(a bluish discoloration of the skin, and lips), seizures, tremors, muscle
    twitching, headache, fatigue, dizziness, trouble breathing, leukocytosis, thrombocytopenic disorder. In
    chlorate poisoning, early death is usually due to anoxia. Renal failure and hyperkalemia may also occur.
    Later death is generally due to renal failure.

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Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Possibly hazardous short term degradation products are not likely. However, long term degradation products
    Products of Biodegradation
    may arise.
    The products of degradation are less toxic than the product itself.
    Toxicity of the Products
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation
    Barium Chlorate, Monohydrate

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Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

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Section 14. Transport Information
    DOT Classification
    CLASS 5.1: Oxidizing material.
    CLASS 6.1: Poisonous material.
    : Barium Chlorate, solid UNNA: 1445 PG: II
    Identification
    Special Provisions for        Not available.    
    Transport
    DOT (Pictograms)
    OXIDIZER
    5.1

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Section 15. Other Regulatory Information and Pictograms
    Pennsylvania RTK: Barium Chlorate, Monohydrate
    Federal and State
    Minnesota: Barium Chlorate, Monohydrate
    Regulations
    New Jersey: Barium Chlorate, Monohydrate
    New Jersey spill list: Barium Chlorate, Monohydrate
    Louisiana spill reporting: Barium Chlorate, Monohydrate
    California Director's List of Hazardous Substances: Barium Chlorate, Monohydrate
    SARA 313 toxic chemical notification and release reporting: Barium Chlorate, Monohydrate
    California        California prop. 65: This product contains the following ingredients for which the State of California has    
    Proposition 65        found to cause cancer which would require a warning under the statute: No products were found.    
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has
    found to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    For CAS number 13477-00-4 (anhydrous form):
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. (EINECS
    No. 236-760-7)
    Canada: Listed on Canadian Non-Domestic Substance List (NDSL).
    China: Listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Not listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    CAS number 10294-38-9(monohydrate form) is not on the following inventories: European (EINECS),
    Canadian NDSL/DSL, China, Japan (ENCS), or Australia (AICS).
    CAS number 10294-38-9(monohydrate form) is on the following inventories: Korea (KECI), Philippines
    (PICCS)
    CLASS C: Oxidizing material.
    Other Classifications        WHMIS (Canada)    
    CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
    DSCL (EEC)        R9- Explosive when mixed with        S13- Keep away from food, drink and animal    
    combustible material.        feedingstuffs.    
    R20/22- Harmful by inhalation and if        S27- Take off immediately all contaminated    
    swallowed.        clothing.    
    R51/53- Toxic to aquatic organisms,        S61- Avoid release to the environment. Refer    
    may cause long-term adverse effects        to special instructions/Safety data sheets.    
    in the aquatic environment.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    1
    Specific hazard
    Personal Protection
    E
    Barium Chlorate, Monohydrate
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    5.1
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent. Wear appropriate
    respirator when ventilation is
    inadequate.

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SECTION 16 - ADDITIONAL INFORMATION
N/A