萘烯酸铁

萘烯酸铁 基本信息
CAS号 1338-14-3 分子式 C22H14FeO4
分子量 398.18900 精确质量  398.02400
PSA  80.26000 LogP  2.40410

基本信息 展开↓

CAS号:
1338-14-3
分子式:
C22H14FeO4
分子量:
398.18900
中文名称:
萘烯酸铁
英文名称:
iron(2+),naphthalene-2-carboxylate
中文别名:
萘烯酸铁;
环烷酸铁;
萘酸铁;
Copper(II) naphthenate;
Ammoniak;
Amoniak [Polish];
AZAN;
Nitro-sil;
Peramine;
Ammonia water;
Ammonium hydroxide;
Carbon black(C.I.77266);
Carbon nanotubes;
Xylene mixture;
Xylene mixture (60% m-xylene, 9% o-xylene, 14% p-xylene, 17% ethylbenzene);
Xylene, (total);
Xylene (mixed isomers);
Scintiverse E Cocktail;
Scintilene Cocktail;
Petroleum xylene;
Xylene mixture (m-xylene, o-xylene, p-xylene);
azo-33;
azo-55;
azo-55tt;
azo-66;
azo-66tt;
ZNO;
oxozinc;
zinc oxygen(-2) anion;
Zinc oxide
英文别名:
iron(2+),naphthalene-2-carboxylate;
Iron naphthenate;
naphthalene-2-carboxylate;
FERRIC NAPHTHENATE;
iron ion(2+) bis(2-naphthoate)
精确分子量/精确质量:
398.02400
极性分子表面积/PSA:
80.26000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00147295
EINECS:
215-660-7
InChI:
InChI=1/2C11H8O2.Fe/c2*12-11(13)10-6-5-8-3-1-2-4-9(8)7-10;/h2*1-7H,(H,12,13);/q;;+2/p-2

生产制备方法及用途展开↓

制备方法


作为涂料用催干剂及重质燃料的助燃剂

用途简介


用途


作为涂料用催干剂及重质燃料的助燃剂

物化性质展开↓

外观与性状:
棕色液体
存储条件/存储方法:

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

稳定性相关:

如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物

其它信息:

1.       性状:棕色液体。

2.       密度(g/mL,25/4): 0.9

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa): 未确定

7.       折射率: 未确定

8.       闪点(ºC): 40

9.       比旋光度(º): 未确定

10.    自燃点或引燃温度(ºC): 未确定

11.    蒸气压(kPa,25ºC): 未确定

12.    饱和蒸气压(kPa,60ºC): 未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC): 未确定

15.    临界压力(KPa): 未确定

16.    油水(辛醇/水)分配系数的对数值: 未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V): 未确定

19.    溶解性:不溶于水。

安全信息展开↓

包装等级:
III
危险类别码:
R10
安全说明:
S16-S26-S36/37/39
安全标志:
S16:远离火源。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

毒理性展开↓

生态数据:

通常来说对水是无害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Iron naphthenate, 80% in mineral spirits (12% Fe)    
   CAS Registry Number:       1338-14-3    
   Formula:       Fe salt of napthenic acid    
   EINECS Number:       none    
   Chemical Family:       metal carboxylate    
   Synonym:       Naphthenic acid, iron salt, in petroleum spirits, paraffin oil.    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       1338-14-3       80%       no data       no data    
   mineral spirits       64475-85-0       20%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Liquid is irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, eyes, inhalation, skin    
   Eye Contact:       Causes irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Vapor is irritating to the nose, mucous membranes and respiratory tract, and cause drowsiness.    
   Ingestion:       Ingestion may cause gastrointestinal distress, dizziness, weakness, and drowsiness.    
   Irritating to skin, eyes and respiratory tract. Mineral spirits entering lungs during vomiting can cause severe
   Acute Health Affects:
   pulmonary injury.
   Chronic Health Affects:       No data available    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Do not
   Ingestion:
   induce vomiting unless directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       >100 °F    
   Autoignition Temperature:       445 °F (mineral sp    
   Explosion Limits:       0.7-8.9% in air (mineral s    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable material. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Eliminate all ignition sources. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable
   Spill and Leak Procedures:
   adsorbent, and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container and store in a cool place. Handle in a well ventilated area.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a vapor. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a vapor. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       brown liq.    
   Molecular Weight:       not applicable    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       organic odor    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Keep away from heat and ignition sources including open flame and electrostatic discharge.    
   Incompatibility:       Oxidizing agents    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.    

SECTION 11: Toxicological Information
   No information available in the RTECS files for title compound. For Mineral Spirits: Oral (rat); LD50:>34600
   RTECS Data:       mg/Kg; Inhalation (rat) LC50: >21400 mg/m3/4H; Intraperitoneal (rat) LDLo: 8560 mg/kg; Skin (rabbit)    
   LD50: 15400 mg/kg.
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       III    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquid, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       III    
   UN ID Number (IATA):       UN# 1993    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       Listed in the TSCA inventory    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积80.3

7.重原子数量:27

8.表面电荷:0

9.复杂度:195

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

立即下载安装“化学加”APP
专业、功能强大,随时调用更加方便