六氟乙酰丙酮铂(II)

六氟乙酰丙酮铂(II) 基本信息
CAS号 65353-51-7 分子式 C10H2F12O4Pt
分子量 609.17900 精确质量  608.94100
PSA  52.60000 LogP  4.08730

基本信息 展开↓

CAS号:
65353-51-7
分子式:
C10H2F12O4Pt
分子量:
609.17900
中文名称:
六氟乙酰丙酮铂(II)
英文名称:
(Z)-1,1,1,5,5,5-hexafluoro-4-hydroxypent-3-en-2-one,platinum
中文别名:
六氟乙酰丙酮铂(II);
1,1,1,5,5,5-六氟乙酰丙酮铂(II);
1,1,5,5,5-六氟乙酰丙酮铂(II);
双(六氟乙酰丙酮)化铂(II)
英文别名:
(Z)-1,1,1,5,5,5-hexafluoro-4-hydroxypent-3-en-2-one,platinum;
PLATINUM HEXAFLUOROPENTANEDIONATE;
PLATINUM 1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONATE
精确分子量/精确质量:
608.94100
极性分子表面积/PSA:
52.60000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。

生产制备方法及用途展开↓

合成制备方法


将4.15g(20mmol)六氟乙酰丙酮与20mL浓度为1mol/L的氢氧化钠溶液混合,搅拌后制得六氟乙酰丙酮钠水溶液。将4.6g(10mmol)Pt(SO4)·4H2O溶于15mL水中,并加入到六氟乙酰丙酮钠溶液中,搅拌1h后得到六氟乙酰丙酮铂粗产品。滤出,用水洗涤,并在无水氯化钙存在下进行干燥。粗产品可用少量热正己烷溶解后,冷却到-78℃得到橘黄色的晶体产品。还可进一步通过升华纯化。

物化性质展开↓

熔点:
143-145ºC
沸点:
65ºC 0,1mm
闪点:
22.8ºC
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 遵照规定使用和储存则不会分解。在65℃升华。可溶于许多有机溶剂中。

其它信息:

1.       性状:橘黄色晶体。

2.       密度(g/mL,25/4℃):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):143-145

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

安全信息展开↓

危险类别码:
R36/37/38
安全说明:
26-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi: Irritant;

毒理性展开↓

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Platinum (II) hexafluoroacetylacetonate, 98% (99.9%-Pt)    
   CAS Registry Number:       65353-51-7    
   Formula:       Pt(CF3COCHCOCF3)2    
   EINECS Number:       None    
   Chemical Family:       metal fluorobeta-diketonate complexes    
   Synonym:       Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)platinum (II)    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       65353-51-7       100%       2.5mg/m3 (as F)       2.5mg/m3 (as F)    

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds has been shown to cause
   Emergency Overview:
   wheezing, coughing, and running of the nose. Inhalation or ingestion may cause fluoride poisoning.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, inhalation of dust.    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation of the dust causes irritation of the nose, mucous membranes and respiratory tract, wheezing,
   Inhalation:
   coughing, shortness of breath.
   Ingestion:       Ingestion may lead to fluoride poisoning, dizziness, abdominal cramps, and vomiting.    
   Acute Health Affects:       Irritating to skin, eyes, mucous membranes, and respiratory tract.    
   Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate
   Chronic Health Affects:       fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth    
   structure, kidney and liver damage.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange xtl.    
   Molecular Weight:       609.22    
   Melting Point:       143-145°    
   Boiling Point:       subl. 65°C /0.1mm    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, halogens, and active metals    
   Decomposition Products:       carbon monoxide, carbon dioxide, carbonyl fluoride, hydrogen fluoride, organic fumes, and platinum salts.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Not regulated by Title 313.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据


1、   疏水参数计算参考值(XlogP):6.8

2、   氢键供体数量:1

3、   氢键受体数量:3

4、   可旋转化学键数量:8

5、   拓扑分子极性表面积(TPSA):32.7

6、   重原子数量:29

7、   表面电荷:0

8、   复杂度:493

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:1

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

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