硝酸钇(3+)

硝酸钇(3+) 基本信息
CAS号 10361-93-0 分子式 N3O9Y
分子量 274.92100 精确质量  274.86900
PSA  206.64000 LogP  0.85230

基本信息 展开↓

CAS号:
10361-93-0
3D弹球模型:
立即前往扯扯看
分子式:
N3O9Y
分子量:
274.92100
中文名称:
硝酸钇(3+)
英文名称:
yttrium(3+),trinitrate
中文别名:
硝酸钇(3+);
釔標準液
英文别名:
yttrium(3+),trinitrate;
Yttrium nitrate;
Yttrium(3+) nitrate;
Nitric acid,yttrium(3+) salt;
Yttrium trinitrate;
yttrium(3+) trinitrate;
Yttrium(III) nitrate;
EINECS 233-802-6
精确分子量/精确质量:
274.86900
极性分子表面积/PSA:
206.64000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
233-802-6
InChI:
The Key: XVQGURFRRNLSBZ-UHFFFAOYSA-N

生产制备方法及用途展开↓

制备方法


催化剂、造纸助剂、发光材料等。

用途简介


毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZG3675000
CAS REGISTRY NUMBER :
10361-93-0
LAST UPDATED :
199712
DATA ITEMS CITED :
25
MOLECULAR FORMULA :
N3-O9.Y
MOLECULAR WEIGHT :
274.94
WISWESSER LINE NOTATION :
YT N-O3*3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
350 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1710 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
515 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1300 mg/kg/60W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - leukemia Lungs, Thorax, or Respiration - bronchiogenic carcinoma
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratesticular
DOSE :
5 mg/kg
SEX/DURATION :
male 1 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct

MUTATION DATA

TEST SYSTEM :
Mammal - domestic
DOSE/DURATION :
5 mg/kg
REFERENCE :
IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 11,143,1973 *** REVIEWS *** ACGIH TLV-TWA 1 mg(Y)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 54,663,1965 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg(Y)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Y)/m3 JAN 1993 OEL-DENMARK:TWA 1 mg(Y)/m3 JAN 1993 OEL-FINLAND:TWA 1 mg(Y)/m3 JAN 1993 OEL-FRANCE:TWA 1 mg(Y)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Y)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Y)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 ppm (25 mg(Y)/m3) JAN 1993 OEL-SWITZERLAND:TWA 1 mg(Y)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Y)/m3;STEL 3 mg(Y)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

MSDS 展开↓


Section 1. Chemical Product and Company Identification
    Yttrium Nitrate, hydrate
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Yttrium Nitrate, hydrate

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove    
    contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
    before reuse. Get medical attention.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical    
    attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. Seek medical attention.
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Products of Combustion        Not available.    
    Fire Hazards in Presence of of combustible materials of organic materials
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    Risks of explosion of the product in presence of static discharge: Not available.
    of Various Substances
    Not applicable.
    Fire Fighting Media
    and Instructions
    Special Remarks on        Danger! Oxidizer!    
    Contact with other material may cause fire. Contact with combustible or organic materials may cause fire.
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container.    
    Large Spill
    Oxidizing material.
    Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance
    damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
    Yttrium Nitrate, hydrate

Section 7. Handling and Storage
    Precautions        Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do not    
    breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label
    when possible. Avoid contact with skin and eyes. Keep away from incompatibles such as combustible materials,
    organic materials, alkalis.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies,    
    reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers.

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Crystalline solid.)        Odor        Odorless.    
    Not available.
    Taste
    Molecular Weight        274.94 g/mole    
    White.
    Color
    Not available.
    pH (1% soln/water)
    Boiling Point        Not available.    
    Melting Point        Not available.    
    Critical Temperature        Not available.    
    Specific Gravity        Not available.    
    Not applicable.
    Vapor Pressure
    Vapor Density        Not available.    
    Not available.
    Volatility
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        See solubility in water.    
    Solubility        Soluble in cold water, hot water.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Instability Temperature        Not available.    
    Conditions of Instability        Dust generation, incompatibles    
    Incompatibility with various        Highly reactive with combustible materials, organic materials.    
    substances        Reactive with alkalis.    
    Corrosivity        Not available.    
    Yttrium Nitrate, hydrate
    Special Remarks on        Oxidizer    
    Reactivity        Incompatible with strong bases, easily oxidized materials, organic materials, flammable substances.    
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans May cause damage to the following organs: blood.
    Other Toxic Effects on        Hazardous in case of skin contact (irritant), of ingestion.    
    Humans        Slightly hazardous in case of inhalation.    
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        May cause adverse reproductive effects based on animal data.    
    Chronic Effects on Humans        May affect genetic material based on animal data.    
    May cause cancer (tumorigenic) based on animal data.
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: Causes moderate skin irritation.    
    Eyes: Causes moderate to severe eye irritation.
    Inhalation: Dust may cause respiratory tract irritation, chemical pneumonia, shortness of breath and wheezing.
    Ingestion: May be harmful if ingested. May cause gastrointestinal tract irritation with nausea, vomiting and
    possible holes in the esophagus.
    The first clinical signs associated with nitrate poisoning include: Gastroenteritis, abdominal pain, nausea,
    vomiting(spontaneous vomiting), diarrhea, metabolic acidosis. Purging and diuresis can be expected. The toxicity
    of nitrates is due to the in vivo conversion to nitrites. The primary toxic effects of nitrites include orthostatic
    hypotension (due to perpheral vasodilation) and methemoglobinemia (the formation of methemoglobin in the blood
    which causes deficient oxygenation of the blood due to decreased available hemoglobin). Other symptoms may
    include muscular weakness, dizziness, lightheadness, fatigue, throbbing headache, general depression, mental
    impairment, incoordination, seizures convulsions, bradycardia or tachydardia (slow or fast heart beat),
    dysrhythmias, dyspnea. Furthermore, methemoglobinemia due to inadequate oxygenation of the blood can lead to
    progressive cyanosis, and coma. Cyanosis is first visible as a bluish discoloration of the mucous membranes and
    unpigmented areas of the body.
    Chronic Potential Health Effects:
    Ingestion: Under some circumstances methemoglobinemia occurs individuals when the nitrate is converted by
    bacteria in the stomach to the nitrite. Nausea, vomiting, dizziness, rapid or slow heart beat, irregular breathing,
    convulsions, symptoms similar to acute ingestion, coma and death can occur should this conversion take place.
    Repeated or prolonged ingestion may also affect the liver and cause anorexia (weight loss).

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    Toxicity of the Products        The product itself and its products of degradation are not toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation
    Yttrium Nitrate, hydrate

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        CLASS 5.1: Oxidizing material.    
    : Nitrate, Inorganic, n.o.s (Yttrium Nitrate) UNNA: 1477 PG: III
    Identification
    Not available.
    Special Provisions for
    Transport
    DOT (Pictograms)
    OXIDIZER
    5.1

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Yttrium Nitrate
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
    CLASS C: Oxidizing material.
    Other Classifications        WHMIS (Canada)    
    CLASS D-2B: Material causing other toxic effects (TOXIC).
    DSCL (EEC)
    R8- Contact with combustible material        S26- In case of contact with eyes, rinse    
    may cause fire.        immediately with plenty of water and seek    
    R36/38- Irritating to eyes and skin.        medical advice.    
    S36- Wear suitable protective clothing.
    S46- If swallowed, seek medical advice
    immediately and show this container or label.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    Yttrium Nitrate, hydrate
    TDG (Canada)
    (Pictograms)
    5.1
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent. Wear appropriate respirator
    when ventilation is inadequate.


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:9

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积:189

7.重原子数量:13

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

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