碳酸钾倍半水合物

碳酸钾倍半水合物 基本信息
CAS号 6381-79-9 分子式 C2H6K4O9
分子量 330.45700 精确质量  329.85600
PSA  154.07000 LogP  -5.08690

基本信息 展开↓

CAS号:
6381-79-9
分子式:
C2H6K4O9
分子量:
330.45700
中文名称:
碳酸钾倍半水合物
英文名称:
POTASSIUM CARBONATE, SESQUIHYDRATE
中文别名:
碳酸钾倍半水合物;
结晶碳酸钾;
倍半水合碳酸钾;
碳酸钾一点五水合物
英文别名:
POTASSIUM CARBONATE, SESQUIHYDRATE;
tetrapotassium,dicarbonate,trihydrate
精确分子量/精确质量:
329.85600
极性分子表面积/PSA:
154.07000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
209-529-3
PubChem:
24854510
InChI:
InChI=1/2CH2O3.4K.3H2O/c2*2-1(3)4;;;;;;;/h2*(H2,2,3,4);;;;;3*1H2/q;;4*+1;;;/p-4

生产制备方法及用途展开↓

制备方法


1.氯化钾与碳酸铵经离子交换反应后,通入二氧化碳,再经结晶、脱水、干燥而制得。或由桐碱和草木灰经浸渍制得。

合成制备方法


1.氯化钾与碳酸铵经离子交换反应后,通入二氧化碳,再经结晶、脱水、干燥而制得。或由桐碱和草木灰经浸渍制得。

用途简介


1.用于制钾肥皂、化妆品和玻璃、搪瓷、印染工业及医药原料、无机盐原料、染料、电焊条、炸药、电渡、陶瓷建筑材料、电子管、显像管、日用化工等。

用途


1.用于制钾肥皂、化妆品和玻璃、搪瓷、印染工业及医药原料、无机盐原料、染料、电焊条、炸药、电渡、陶瓷建筑材料、电子管、显像管、日用化工等。

物化性质展开↓

熔点:
891ºC
沸点:
333.6ºC at 760 mmHg
闪点:
169.8ºC
存储条件/存储方法:

 避光,阴凉干燥处,密封保存

稳定性相关:

1.常温常压下稳定,白色结晶 。

2.极易潮解。暴露于空气中能吸收二氧化碳和水转度为碳酸氢钾。

其它信息:

1.       性状:无色结晶或白色颗粒。

2.      相对 密度(g/mL,20℃/4℃):2.428

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):891

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,12mmHg):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º,):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:易溶于水,几乎不溶于乙醇和醚。

安全信息展开↓

危险类别码:
22-36/38
安全说明:
26
危险标志:
Xn

毒理性展开↓

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态数据:

对水少是稍微危害的,不要让未稀释或大量的产品接触地下水、水道或污水系统

若无政府许可,勿将材料排入周围环境.

MSDS 展开↓


Section 1. Chemical Product and Company Identification
    Potassium carbonate Sesquihydrate
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Potassium carbonate Sesquihydrate
    CARCINOGENIC EFFECTS: Not available.
    Potential Chronic Health
    Effects        MUTAGENIC EFFECTS: Not available.    
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    The substance is toxic to mucous membranes.
    The substance may be toxic to skin, eyes.
    Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the
    eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction,
    or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. Get medical attention immediately.
    Skin Contact        In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated    
    clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
    reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate    
    medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention immediately.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Products of Combustion        Not available.    
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards
    Potassium carbonate Sesquihydrate

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize    
    the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated
    surface and dispose of according to local and regional authority requirements.
    Large Spill        Corrosive solid.    
    Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
    disposal. Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the
    contaminated surface and allow to evacuate through the sanitary system.

Section 7. Handling and Storage
    Precautions        Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient    
    ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the
    container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
    metals, acids.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or    
    equivalent. Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus
    a Large Spill        should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a    
    specialist BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Powdered solid. Deliquescent solid.)        Odor        Odorless.    
    Taste        Not available.    
    165.23 g/mole
    Molecular Weight
    Color        White.    
    pH (1% soln/water)        11.6 [Basic.]    
    Boiling Point        Decomposes.    
    Melting Point        891.11°C (1636°F)    
    Critical Temperature        Not available.    
    Specific Gravity        Not available.    
    Not applicable.
    Vapor Pressure
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Not available.
    Ionicity (in Water)
    Dispersion Properties        See solubility in water.    
    Soluble in cold water.
    Solubility
    Potassium carbonate Sesquihydrate

Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Instability Temperature        Not available.    
    Dust generation, moist air, water, incompatible materials.
    Conditions of Instability
    Reactive with oxidizing agents, metals, acids.
    Incompatibility with various
    Slightly reactive to reactive with moisture.
    substances
    Corrosivity        Non-corrosive in presence of glass.    
    Special Remarks on        Reacts with water to evolve heat.    
    Reactivity        When it contains the full amount of water it is not hygroscopic.    
    Incompatible with KCO, chlorine trifluoride, calcium oxide, and magnesium
    Not available.
    Special Remarks on
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Eye contact. Inhalation. Ingestion.    
    Toxicity to Animals        Acute oral toxicity (LD50): 1870 mg/kg [Rat ].    
    Chronic Effects on Humans        Causes damage to the following organs: mucous membranes.    
    May cause damage to the following organs: skin, eyes.
    Other Toxic Effects on
    Extremely hazardous in case of skin contact (corrosive), of inhalation (lung corrosive).
    Humans        Hazardous in case of skin contact (irritant), of ingestion, .    
    Slightly hazardous in case of eye contact (corrosive).
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: Causes severe skin irritation.    
    Eyes: It is severely irritating to the eyes and its mucous membranes. It may cause corneal injury. It may cause
    burns and loss of vision. It may cause permanent damage. The amount of tissue damage depends on the length
    of contact.
    Ingestion: It causes gastrointestinal irritation with nausea, vomiting, abdominal pain, swollen glottis, increased
    respiration, and possible burns to the lips, tongue, oral mucosa, hypopharynx, stomach, or esophagus. It may
    affect the cardiovascular system(circulatory collapse), urinary system, and metabolism.
    Inhalation: Causes respiratory tract and mucous membrane irritation. Exposure can cause coughing, chest
    pains, and difficulty breathing (dyspnea).

Section 12. Ecological Information
    Not available.
    Ecotoxicity
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    The products of degradation are less toxic than the product itself.
    Toxicity of the Products
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation
    Potassium carbonate Sesquihydrate

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Not applicable.
    Identification
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    No products were found.
    Federal and State
    Regulations
    California
    Proposition 65
    Warnings
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)        R22- Harmful if swallowed.        S1/2- Keep locked up and out of the reach of    
    R36/37/38- Irritating to eyes,        children.    
    respiratory system and skin.        S26- In case of contact with eyes, rinse    
    immediately with plenty of water and seek
    medical advice.
    S36/37/39- Wear suitable protective clothing,
    gloves and eye/face protection.
    S45- In case of accident or if you feel unwell,
    seek medical advice immediately (show the
    label where possible).
    S46- If swallowed, seek medical advice
    immediately and show this container or label.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    1
    Specific hazard
    Personal Protection
    j
    WHMIS (Canada)
    (Pictograms)
    Potassium carbonate Sesquihydrate
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Synthetic apron.
    Vapor and dust respirator. Be sure to
    use an approved/certified respirator or
    equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:3

3.氢键受体数量:9

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积129

7.重原子数量:15

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:9

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