硝酸亚汞

硝酸亚汞 基本信息
CAS号 10415-75-5 分子式 HNO3.Hg
分子量 263.60019 精确质量  264.96628
PSA  68.88000 LogP  0.28160

基本信息 展开↓

CAS号:
10415-75-5
3D弹球模型:
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分子式:
HNO3.Hg
分子量:
263.60019
中文名称:
硝酸亚汞
英文名称:
Nitric acid, mercury(1+) salt (1:1)
中文别名:
硝酸亚汞;
二水硝酸亚汞
英文别名:
Nitric acid, mercury(1+) salt (1:1);
Nitric acid, mercury(1+) salt (8CI,9CI);
Dimercury dinitrate;
Dimercury(1+) dinitrate;
Mercurous nitrate;
Mercury nitrate (Hg2(NO3)2);
Mercury nitrate (HgNO3);
Mercury(I) nitrate;
Monomercury nitrate
精确分子量/精确质量:
264.96628
极性分子表面积/PSA:
68.88000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
233-886-4
InChI:
InChI=1/2Hg.2NO3/c;;2*2-1(3)4/q2*+2;2*-1

生产制备方法及用途展开↓

制备方法


制法将稀硝酸加入耐酸反应器中,加热40~50 ℃,缓慢加入汞进行反应,经蒸发浓缩,冷却结晶,离心分离,制得二水硝酸亚汞。

合成制备方法


制法将稀硝酸加入耐酸反应器中,加热40~50 ℃,缓慢加入汞进行反应,经蒸发浓缩,冷却结晶,离心分离,制得二水硝酸亚汞。

用途简介


用作分析试剂及氧化剂。

用途


用途用于制药、用作氧化剂、通用分析试剂。

物化性质展开↓

沸点:
83ºC at 760mmHg
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物,食品原料分开存放
稳定性相关:

失火时,消防人员须穿戴全身防护服。用雾状水、砂土和各种灭火器扑救灭火。

其它信息:

1.性状:无色板状或棱柱状结晶

2.相对密度(3.9ºC):4.785

3.熔点(ºC,分解):70

4.溶解性:易溶于水、并水解。溶于稀硝酸。不溶于乙醇、乙醚。

 

 

安全信息展开↓

包装等级:
II
风险类别:
6.1(a)
海关代码:
2834299090

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OW8000000
CAS REGISTRY NUMBER :
10415-75-5
LAST UPDATED :
199712
DATA ITEMS CITED :
28
MOLECULAR FORMULA :
N-O3.Hg
MOLECULAR WEIGHT :
262.60
WISWESSER LINE NOTATION :
HG N-O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
170 mg/kg
TOXIC EFFECTS :
Gastrointestinal - hypermotility, diarrhea
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(8),12,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2330 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
49300 ug/kg
TOXIC EFFECTS :
Gastrointestinal - hypermotility, diarrhea
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(8),12,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5 mg/kg
REFERENCE :
ATXKA8 Archiv fuer Toxikologie. (Berlin, Fed. Rep. Ger.) V.15-31, 1954-74. For publisher information, see ARTODN. Volume(issue)/page/year: 20,226,1964 *** REVIEWS *** ACGIH TLV-TWA 0.025 mg(Hg)/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.05 mg(Hg)/m3 DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,22,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FINLAND:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FRANCE:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-GERMANY:TWA 0.01 ppm (0.1 mg(Hg)/m3) JAN 1993 OEL-HUNGARY:TWA 0.02 mg(Hg)/m3;STEL 0.04 mg(Hg)/m3 JAN 1993 OEL-JAPAN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-POLAND:TWA 0.01 mg(Hg)/m3 JAN 1993 OEL-RUSSIA:TWA 0.05 mg(Hg)/m3;STEL 0.01 mg(Hg)/m3 JAN 1993 OEL-SWEDEN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THAILAND:STEL 0.05 mg(Hg)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO MERCURY, ARYL AND INORGANIC-air:CL 0.1 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84776 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 62 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84776 No. of Facilities: 87 (estimated) No. of Industries: 3 No. of Occupations: 3 No. of Employees: 1934 (estimated) No. of Female Employees: 1316 (estimated)
毒理学数据:

口服- 大鼠 LD50: 170  毫克/ 公斤; 口服- 小鼠 LD50: 49.3 毫克/ 公斤

MSDS 展开↓

Name: Mercury(I) nitrate dihydrate p.a. Material Safety Data Sheet
Synonym: Nitric acid, mercury(1+)salt, dihydrate
CAS: 10415-75-5
Section 1 - Chemical Product   MSDS Name:Mercury(I) nitrate dihydrate p.a. Material Safety Data Sheet
Synonym:Nitric acid, mercury(1+)salt, dihydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10415-75-5 Mercury(I) nitrate dihydrate >98 unlisted
Hazard Symbols: T+
Risk Phrases: 26/27/28 33

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.Light sensitive.
Potential Health Effects
Eye:
May cause chemical conjunctivitis. Causes eye irritation and possible injury.
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
May cause dermatitis.
Ingestion:
May be fatal if swallowed. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Inorganic mercury compounds may cause central and peripheral nervous system effects.
Inhalation:
May be fatal if inhaled. Exposure produces central nervous system depression. May produce general weakness, vomiting, diarrhea, chest pains, coughing, shortness of breath, and cardiac insufficiency.
Causes irritation of the mucous membrane and upper respiratory tract.
Chronic:
Chronic ingestion may cause accumulation of mercury in body tissues.
There is a danger of cumulative effects. May cause kidney damage.
Prolonged or repeated exposure may cause inflammation of the mouth and gums, excessive salivation, and loosening of the teeth.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May decompose explosively when heated or involved in a fire.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Store protected from light. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Poison room locked. Store protected from light. Store in a cool, dry area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 10415-75-5: CAS# 14836-60-3: United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds): mg/m3 VLE (as Hg) France - VME: (listed as mercury, aryl and inorganic compounds): mg/m3 VME (as Hg) Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m VME (as Hg) Germany: (listed as mercury inorganic compounds): Skin absorber Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1 mg/m3 TWA (as Hg) Netherlands: (listed as mercury inorganic compounds): 0.15 mg/m3 Netherlands: (listed as mercury inorganic compounds): 0.05 mg/m3 Russia: (listed as mercury inorganic compounds): 0.2 mg/m3 TWA (a Hg) Russia: (listed as mercury inorganic compounds): 0.05 mg/m3 STEL Hg) Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/ VLA-ED (as Hg) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 70 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 20 g/l (20 c)
Specific Gravity/Density: 4.7800g/cm3
Molecular Formula: HgNO3.2H2O
Molecular Weight: 298.60

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. Light sensitive.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Metals, reducing agents, ammonia, copper, acetylene, lithium, rubidium, sodium carbide, calcium, chlorine dioxide, azides, heat, direct light, wood, combustible materials.
Hazardous Decomposition Products:
Nitrogen oxides, nitrogen, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10415-75-5: OW8000000 CAS# 14836-60-3 unlisted.
LD50/LC50:
CAS# 10415-75-5: Oral, mouse: LD50 = 49300 ug/kg; Oral, rat: LD50 = 170 mg/kg; Skin, rat: LD50 = 2330 mg/kg.
CAS# 14836-60-3.
Carcinogenicity:
Mercurous nitrate - Not listed by ACGIH, IARC, or NTP.
Mercury(I) nitrate dihydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: MERCUROUS NITRATE
Hazard Class: 6.1
UN Number: 1627
Packing Group: II
IMO
Shipping Name: MERCUROUS NITRATE
Hazard Class: 6.1
UN Number: 1627
Packing Group: II
RID/ADR
Shipping Name: MERCUROUS NITRATE
Hazard Class: 6.1
UN Number: 1627
Packing group: II
USA RQ: CAS# 10415-75-5: 10 lb final RQ; 4.54 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 1/2 Keep locked up and out of reach of children.
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10415-75-5: 3
CAS# 14836-60-3: No information available.
Canada
CAS# 10415-75-5 is listed on Canada's DSL List.
CAS# 10415-75-5 is listed on Canada's Ingredient Disclosure List.
CAS# 14836-60-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10415-75-5 is listed on the TSCA inventory.
CAS# 14836-60-3 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积62.9

7.重原子数量:5

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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