六氟代锑酸锂

六氟代锑酸锂 基本信息
CAS号 18424-17-4 分子式 F6LiSb
分子量 242.69100 精确质量  241.91000
PSA  0.00000 LogP  2.52120

基本信息 展开↓

CAS号:
18424-17-4
3D弹球模型:
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分子式:
F6LiSb
分子量:
242.69100
中文名称:
六氟代锑酸锂
英文名称:
lithium,hexafluoroantimony(1-)
中文别名:
六氟代锑酸锂;
六氟锑酸锂
英文别名:
lithium,hexafluoroantimony(1-);
lithium hexafluorostiboranuide;
hexafluorostibine,lithium salt;
Lithium hexafluoroantimonate
精确分子量/精确质量:
241.91000
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00042319
InChI:
The Key: YVBBFYDVCPCHHG-UHFFFAOYSA-H

物化性质展开↓

存储条件/存储方法:

常温密闭避光,通风干燥

稳定性相关:

常温常压下稳定

避免的物料:水分/潮湿 酸

其它信息:

1.       性状:粉状

2.       密度(g/mL,25/4):不确定

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):不确定

5.       沸点ºC,常压):不确定

6.       沸点(ºC, 5.2kPa):不确定

7.       折射率:不确定

8.       闪点(ºC):不确定

9.       比旋光度(º):不确定

10.    自燃点或引燃温度(ºC):不确定

11.    蒸气压(kPa,25ºC):不确定

12.    饱和蒸气压(kPa,60ºC):不确定

13.    燃烧热(KJ/mol):不确定

14.    临界温度(ºC):不确定

15.    临界压力(KPa):不确定

16.    油水(辛醇/水)分配系数的对数值:不确定

17.    爆炸上限(%,V/V):不确定

18.    爆炸下限(%,V/V):不确定

19.    溶解性:不确定

安全信息展开↓

包装等级:
III
风险类别:
6.1
危险类别码:
20/22-51/53
安全说明:
S61
安全标志:
S61:避免排放到环境中。参考专门的说明/安全数据表。
危险标志:
Xi,T,N,Xn

毒理性展开↓

生态数据:

对水体是危害的,即使小量产品不能接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Lithium hexafluoroantimonate,min. 97%    
   CAS Registry Number:       18424-17-4    
   Formula:       LiSbF6    
   EINECS Number:       none    
   Chemical Family:       halometallate salts    
   Synonym:       Lithium antimony hexafluoride    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       18424-17-4       100%       0.5mg/m3 (as Sb)       0.5mg/m3 (as Sb)    

Section 3: Hazards Identification
   Dust causes burns to skin and eyes, bleeding gums, laryngitis, headache, anemia, skin eruptions, liver and
   Emergency Overview:
   kidney damage. Fluoride poisoning may cause nausea, diarrhea, and weakness
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Causes burns and serious eye damage. Effects may not immediately appear.    
   Skin Contact:       Corrosive. Effects may not appear immediately. Antimony may cause dermatitis and skin eruptions.    
   Inhalation of dust causes burning to the respiratory tract, causing coughing, sore throat, and labored
   Inhalation:
   breathing.
   Ingestion:       Ingestion may lead to nausea, vomiting, bloody diarrhea, weakness, and convulsions. Lithium salts are toxic.    
   Burns to eyes and skin. Fluoride poisoning may cause nausea, vomiting and cardiovascular collapse. Lithium
   Acute Health Affects:
   salts are toxic to the central nervous system.
   Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure.
   Chronic Health Affects:       Antimony dust may cause bleeding gums, laryngitis, headache, anemia, skin eruptions, liver and kidney    
   damage
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
   Skin Exposure:
   or water soluble calcium salts as antidote. Seek medical assistance.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       None. Material is non-flammable.    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       If involved in a fire this material may emit corrosive fumes of hydrofluoric acid.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid
   Spill and Leak Procedures:       raising dust. Spillage in areas not adequately ventilated may require an evacuation of area. Emergency    
   response teams will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
   Store solid in a tightly sealed container away from moisture. Handle under a dry atmosphere of air or nitrogen.
   Handling and Storage:
   Prolonged exposure to the atmosphere may degrade the product.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       The material must be handled in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       The material must be handled in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to off-white pwdr.    
   Molecular Weight:       242.68    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       active metals and strong mineral acids    
   Decomposition Products:       Hydrofluoric acid, metal fluorides and antimony oxyfluorides    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Corrosive solids, toxic, N.O.S.    
   Hazard Class (CFR):       8    
   Additional Hazard Class (CFR):       6.1    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 2923    
   Shipping Name (IATA):       Corrosive Solid, Toxic, N.O.S.    
   Hazard Class (IATA):       8    
   Additional Hazard Class (IATA):       6.1    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 2923    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N010 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:7

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:8

8.表面电荷:0

9.复杂度:62.7

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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