---

Section 1: Product Identification
   Chemical Name:       Hafnium (IV) ethoxide, 99%    
   CAS Registry Number:       13428-80-3    
   Formula:       Hf4O(OC2H5)14.2C2H5OH    
   EINECS Number:
   Chemical Family:       metal alkoxide    
   Synonym:       hafnium ethanolate. ethanol, hafnium salt.    

---

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13428-80-3       100%       0.5mg/m3 (as Hf)       0.5mg/m3 (as Hf)    

---

Section 3: Hazards Identification
   Emergency Overview:       Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Inhalation, ingestion, contact with skin and eyes.    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to skin, eyes and respiratory tract.    
   Ingestion:       Ingestion may cause gastrointestinal distress, nausea, vomiting and headache.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   No data is available for this product. Prolonged exposure to ethanol vapors may be harmful to nerves and
   Chronic Health Affects:
   liver.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

---

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Ingestion:       Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).    

---

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

---

SECTION 6: Accidental Release Measures
   Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable
   Spill and Leak Procedures:
   adsorbent, and swept up.

---

SECTION 7: Handling and Storage
   Store in a tightly sealed container in a dry place. If container is left open, product may adsorb moisture and
   Handling and Storage:
   carbon dioxide from the atmosphere and release ethanol vapor.

---

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

---

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to off-white xtl.    
   Molecular Weight:       358.73    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       alcohol-like odor    
   Solubility in Water:       Reacts with water    

---

SECTION 10: Stability and Reactivity
   Stability:       air and moisture sensitive solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       Oxidizing agents and halogens    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.    

---

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

---

SECTION 12: Ecological Information
   Ecological Information:       No information available    

---

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

---

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

---

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    

---

SECTION 16 - ADDITIONAL INFORMATION
N/A