黄血盐钠

黄血盐钠 基本信息
CAS号 14434-22-1 分子式 C6H20FeN6Na4O10
分子量 484.06100 精确质量  484.01800
PSA  235.04000 LogP  -0.54482

基本信息 展开↓

CAS号:
14434-22-1
分子式:
C6H20FeN6Na4O10
分子量:
484.06100
中文名称:
黄血盐钠
英文名称:
Sodium ferrocyanide
中文别名:
黄血盐钠;
亚铁氰化钠十水合物;
六氰基铁(II)酸钠十水合物;
六氰基铁(II)酸钠
英文别名:
Sodium ferrocyanide;
Sodium hexacyanoferrate(II) decahydrate;
Tetrasodium hexacyanoferrate decahydrate;
Sodium Ferrocyanide;
Sodiumferrocyanide;
YELLOW PRUSSIATE OF SODA DECAHYDRATE;
SODIUM FERROCYANIDE DECAHYDRATE
精确分子量/精确质量:
484.01800
极性分子表面积/PSA:
235.04000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00149274
EINECS:
237-081-9
PubChem:
24848141

物化性质展开↓

外观与性状:
固体
密度:
1,458 g/cm3
沸点:
25.7ºC at 760mmHg
闪点:
435°C
水溶解性:
soluble
蒸汽压:
740mmHg at 25°C
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):1.458

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):435

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:可溶于水

安全信息展开↓

海关代码:
2837200090
危险类别码:
R32
安全说明:
S22-S24/25-S36-S26
安全标志:
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。
危险标志:
Xi: Irritant;

毒理性展开↓

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Sodium hexacyanoferrate (II) decahydrate    
   CAS Registry Number:       14434-22-1    
   Formula:       Na4Fe(CN)6.10H2O    
   EINECS Number:       237-081-9    
   Chemical Family:       metal cyano complex    
   Synonym:       Sodium ferrocyanide decahydrate; Ferrate(4-), hexacyano-, sodium    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       14434-22-1       100%       1mg/m3 (as Fe - soluble)       10mg/m3 (as Fe)    

Section 3: Hazards Identification
   May be irritating to skin, eyes and respiratory tract. May be harmful through inhalation, ingestion and skin
   Emergency Overview:
   absorption.
   Primary Routes of Exposure:       Ingestion, inhalation, skin.    
   Eye Contact:       May cause mild to moderate irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       May be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Approved by the FDA as an anti-caking additive to table salt in low concentration.    
   Acute Health Affects:       May be irritating to skin, eyes and respiratory tract.    
   No information available on long term chronic effects. Hexacyanoferrate passes through the body with only
   Chronic Health Affects:
   slight dissociation. Z NATURFORSCH SECT C BIOSCI; 45 (6). 1990. 681-690
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, toxic oxidation or decomposition products may form.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Non-flammable. No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Sweep up the solid and dispose of properly.    

SECTION 7: Handling and Storage
   Handling and Storage:       No special storage conditions required.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Handle the material in an efficient fume hood. Reaction with mineral acids can release toxic fumes of
   Ventilation:
   hydrogen cyanide.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Handle the material in an efficient fume hood. Reaction with mineral acids can release toxic fumes of
   Ventilation:
   hydrogen cyanide.
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       pale yellow xtl.    
   Molecular Weight:       303.88 (484.04)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       1.458    
   Odor:       none    
   Solubility in Water:       31.8g/100cc (20C)    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       No hazardous polymerization    
   Conditions to Avoid:       Do not heat with strong mineral acid.    
   Incompatibility:       oxidizing agents, mineral acids, halogens and active metals.    
   Decomposition Products:       iron oxide, nitrogen oxides and sodium oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

 

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:10

3.氢键受体数量:22

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积153

7.重原子数量:27

8.表面电荷:0

9.复杂度:127

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:21

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