二叔十二烷基二硫化物

二叔十二烷基二硫化物 基本信息
CAS号 27458-90-8 分子式 C24H50S2
分子量 402.78400 精确质量  402.33500
PSA  50.60000 LogP  10.20640

基本信息 展开↓

CAS号:
27458-90-8
分子式:
C24H50S2
分子量:
402.78400
中文名称:
二叔十二烷基二硫化物
英文名称:
2-methyl-2-(2-methylundecan-2-yldisulfanyl)undecane
中文别名:
二叔十二烷基二硫化物
英文别名:
2-methyl-2-(2-methylundecan-2-yldisulfanyl)undecane;
Di-tert-dodecyl Disulfide;
Di-tert-dodecyl disulfide;
2-methyl-2-[(2-methylundecan-2-yl)disulfanyl]undecane;
tert-Dodecyl polysulfide;
Di-tert-dodecyl disulphide;
tert-Dodecyl Disulfide;
Disulfide,di-tert-dodecyl;
Di-tert-dodecyl polysulfide
精确分子量/精确质量:
402.33500
极性分子表面积/PSA:
50.60000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
248-468-7

物化性质展开↓

密度:
0.889g/cm3
沸点:
466.9ºC at 760mmHg
闪点:
90.2ºC
折射率:
1.482
蒸汽压:
1.9E-08mmHg at 25°C
其它信息:

1.       性状: 未确定

2.       密度(g/mL,25/4):0.91

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):118

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

安全信息展开↓

海关代码:
2930909090

MSDS 展开↓


Section I.Chemical Product and Company Identification
    Chemical Name        Di-tert-dodecyl Disulfide    
    (mixture of isomers)
    Portland OR
    Disulfide, di-tert-dodecyl (CA INDEX NAME);
    Synonym
    tert-Dodecyl Disulfide
    Chemical Formula        C12H50S2    
    27458-90-8
    CAS Number

Section II.        Composition and Information on Ingredients    
    Chemical Name        CAS Number Percent (%)        TLV/PEL        Toxicology Data    
    Di-tert-dodecyl Disulfide        27458-90-8 Not available. Not available.        Not available.    
    (mixture of isomers)

Section III. Hazards Identification
    No specific information is available in our data base regarding the toxic effects of this material for humans. However,
    Acute Health Effects
    exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
    inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
    this compound.
    CARCINOGENIC EFFECTS : Not available.
    Chronic Health Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

Section IV.        First Aid Measures    
    Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
    Eye Contact
    minutes. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing    
    before reuse. Thoroughly clean shoes before reuse. Get medical attention.
    Inhalation        If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
    improve.
    Ingestion        INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.    
    Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic
    material was ingested; the absence of such signs, however, is not conclusive.

Section V.        Fire and Explosion Data    
    Not available.
    Auto-Ignition
    Flammability        May be combustible at high temperature.    
    Flammable Limits        Not available.    
    Flash Points        118°C (244.4°F).    
    Combustion Products        These products are toxic carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...).    
    Fire Hazards
    Not available.
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards
    Risks of explosion of the product in presence of static discharge: Not available.
    Fire Fighting Media
    SMALL FIRE: Use DRY chemical powder.
    LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
    and Instructions
    Consult with local fire authorities before attempting large scale fire-fighting operations.
    Continued on Next Page
    Di-tert-dodecyl Disulfide
    (mixture of isomers)

Section VI.        Accidental Release Measures    
    Spill Cleanup        Moisture sensitive material.    
    Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning the spill by rinsing
    Instructions
    any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on
    disposal.

Section VII. Handling and Storage
    Handling and Storage        MOISTURE SENSITIVE. STORE UNDER ARGON. Keep away from heat. Mechanical exhaust required. When not in use,    
    tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. Do not breathe gas/fumes/
    Information
    vapor/spray.
    Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
    Engineering Controls        Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective    
    threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
    Personal Protection        Splash goggles. Lab coat. Vapor respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a    
    specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
    Exposure Limits        Not available.    

Section IX. Physical and Chemical Properties
    Liquid. (Clear. Colorless - yellow.)        Solubility    
    Physical state @ 20°C        Very slightly soluble in water.    
    0.91 (water=1)
    Specific Gravity
    Molecular Weight        402.78        Partition Coefficient        Not available.    
    Boiling Point        321°C (609.8°F)        Vapor Pressure        Not available.    
    Melting Point        Not available.        Vapor Density        >1 (Air = 1)    
    1.49        Volatility        Not available.    
    Refractive Index
    Nearly odorless.
    Critical Temperature        Not available.        Odor    
    Viscosity        Not available.        Taste        Not available.    

Section X.        Stability and Reactivity Data    
    Stability    
This material is stable if stored under proper conditions. (See Section VII for instructions)    
    Conditions of Instability        Avoid excessive heat and light. Moisture sensitive.    
    Incompatibilities
    Reactive with oxidizing agents.

Section XI. Toxicological Information
    RTECS Number        Not available.    
    Eye Contact. Ingestion. Inhalation.
    Routes of Exposure
    Toxicity Data        Not available.    
    CARCINOGENIC EFFECTS : Not available.
    Chronic Toxic Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
    Acute Toxic Effects        No specific information is available in our data base regarding the toxic effects of this material for humans. However,    
    exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
    inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling this
    compound.

Section XII.        Ecological Information    
    Ecotoxicity        Not available.    
    Not available.
    Environmental Fate
    Continued on Next Page
    Di-tert-dodecyl Disulfide
    (mixture of isomers)

Section XIII.        Disposal Considerations    
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
    Waste Disposal
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    PIN Number        Not applicable.    
    Proper Shipping Name        Not applicable.    
    Packing Group (PG)        Not applicable.    
    DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.    
    (EPA)
    WHMIS Classification        On DSL.    
    (Canada)
    EINECS Number (EEC) 248-468-7
    EEC Risk Statements        Not available.    
    Japanese Regulatory Data        ENCS no.: 2-473;    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2930909090

概述:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

分子结构与计算化学数据展开↓

分子结构数据


1   摩尔折射率:129.16

2   摩尔体积m3/mol452.7

3   等张比容(90.2K):1078.4

4   表面张力dyne/cm32.2

5   极化率10-24cm351.20

计算化学数据


1.疏水参数计算参考值(XlogP):11.1

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:19

5.互变异构体数量:无

6.拓扑分子极性表面积50.6

7.重原子数量:26

8.表面电荷:0

9.复杂度:267

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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