碘化铑

碘化铑 基本信息
CAS号 15492-38-3 分子式 I3Rh
分子量 483.61900 精确质量  483.61900
PSA  0.00000 LogP  2.65710

基本信息 展开↓

CAS号:
15492-38-3
3D弹球模型:
立即前往扯扯看
分子式:
I3Rh
分子量:
483.61900
中文名称:
碘化铑
英文名称:
Rhodium triiodide
中文别名:
碘化铑;
碘化铑(III)
英文别名:
Rhodium triiodide;
Triiodorhodium(III);
rhodium(3+) triiodide;
rhodiumiodide(rhi3);
RHI3;
Rhodium(III) iodide;
Rhodium(III)iodide(-Rh);
rhodium iodide;
RHODIUM(LLL)IODIDE
精确分子量/精确质量:
483.61900
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00016311
EINECS:
239-521-5
InChI:
InChI=1/3HI.Rh/h3*1H;/q;;;+3/p-3/rI3Rh/c1-4(2)3

生产制备方法及用途展开↓

制备方法


用金属铑粉与I2在400℃下反应,可以生成结晶态的碘化铑,若将KI溶液加入到RhCl3溶液中,则生成无定形的RhI3沉淀。

合成制备方法


用金属铑粉与I2在400℃下反应,可以生成结晶态的碘化铑,若将KI溶液加入到RhCl3溶液中,则生成无定形的RhI3沉淀。

用途简介


物化性质展开↓

外观与性状:
黑色结晶粉末
存储条件/存储方法:

常温密闭避光,通风干燥惰性气体下

稳定性相关:

常温常压下稳定

避免的物料:水分/潮湿 氧化物  酸。黑色的固体,单斜系结晶,类似于AlCl3结晶,密度为665g/cm3,在675℃时开始发生分解。

其它信息:

1. 性状:黑色的固体

2. 密度(g/mL,25/4℃):6.65

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:未确定

安全信息展开↓

包装等级:
I; II; III
海关代码:
2827600000
WGK_Germany:
3
德国有关水污染物质的分类清单
安全说明:
S22-S24/25
RTECS号:
YU7300000

毒理性展开↓

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Rhodium (III) iodide (99.9+%-Rh)    
   CAS Registry Number:       15492-38-3    
   Formula:       RhI3    
   EINECS Number:       239-521-5    
   Chemical Family:       metal halide    
   Synonym:       Rhodium triiodide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       15492-38-3       100%       0.01mg/m3 (as Rh       0.001mg/m3 (as Rh    

Section 3: Hazards Identification
   Irritating to the respiratory tract. May be harmful if swallowed. Prolonged exposure to iodide salts may
   Emergency Overview:
   produce a mild toxic syndrome known as iodism.
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Contact with eyes causes irritation, redness, and pain.    
   Skin Contact:       Causes irritation to skin. Symptoms include redness, itching, and pain, pimples, boils, hives and blisters.    
   Inhalation:       Causes irritation to the respiratory tract. Symptoms may include coughing and shortness of breath.    
   Ingestion:       Large oral doses may cause irritation to the gastrointestinal tract    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and
   Chronic Health Affects:
   irritation of mucous membranes.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       black pwdr.    
   Molecular Weight:       483.62    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       halogens, hydrogen peroxide, chlorates and hypochlorites and active metals    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1、 疏水参数计算参考值(XlogP):

2、 氢键供体数量:0

3、 氢键受体数量:3

4、 可旋转化学键数量:0

5、 互变异构体数量:

6、 拓扑分子极性表面积(TPSA):0

7、 重原子数量:4

8、 表面电荷:0

9、 复杂度:0

10、 同位素原子数量:0

11、 确定原子立构中心数量:0

12、 不确定原子立构中心数量:0

13、 确定化学键立构中心数量:0

14、 不确定化学键立构中心数量:0

15、 共价键单元数量:4

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