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Section 1: Product Identification
   Chemical Name:       (R)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97% (10 wt% in hexanes)    
   CAS Registry Number:       428514-91-4    
   Formula:       C17H20NP    
   EINECS Number:       none    
   Chemical Family:       organophosphine ligand    
   Synonym:       (R)-2-[(Diphenylphosphano)methyl]pyrrolidine    

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Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       428514-91-4       10%       no data       no data    
   Hexane       73513-42-5       90%       50ppm       1800mg/m3    

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Section 3: Hazards Identification
   Extremely flammable liquid. Vapors irritating to skin, eyes and respiratory tract. Inhalation of vapors may
   Emergency Overview:
   depress central nervous system causing dizziness, headache and nausea.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Contact will cause irritation, redness and a burning sensation.    
   Skin Contact:       Contact with skin can result in local irritation. May be absorbed throuh skin.    
   Inhalation of vapors may depress the central nervous system causing dizziness, difficulty in walking and
   Inhalation:
   irritation to the lungs.
   Ingestion may cause gastrointestinal irritation, nausea, vomiting and headache. May cause lung damage if
   Ingestion:
   swallowed.
   Irritating to skin, eyes and respiratory tract. Harmful by inhalation. Ingestion may cause gastrointestinal
   Acute Health Affects:
   irritation, nausea, vomiting and headache. Possible risk of harm to the unborn child.
   Chronic Health Affects:       No information on long-term chronic effects. Possible risk of impaired fertility.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

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SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
   Flash Point:       -14.8°F (hexane)    
   Autoignition Temperature:       no data    
   Explosion Limits:       LEL (1.7%) UEL (7.7%)    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic and irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Extremely flammable

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SECTION 6: Accidental Release Measures
   If spilled, all personnel must be immediately evacuated and the area sealed off. The material may self-ignite
   Spill and Leak Procedures:       releasing toxic and corrosive fumes of phosphorus pentoxide. Ventilation should be available. If entry into the    
   area is requires, personnel should be fitted with a self-contained breathing apparatus.

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SECTION 7: Handling and Storage
   Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat.
   Handling and Storage:
   Material should be transferred under an inert atmosphere of nitrogen or argon in an efficient fume hood.

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SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Wear protective clothing and gloves. Consult with a glove manufacturer to determine the proper type of glove.
   Skin Protection:
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

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SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless liquid    
   Molecular Weight:       269.32    
   Melting Point:       no data    
   Boiling Point:       68°C (hexane)    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       pungent and noxious    
   Solubility in Water:       Insoluble    

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SECTION 10: Stability and Reactivity
   Stability:       air sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with oxidizing agents, ignition sources and prolonged exposure to air    
   Incompatibility:       strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorous pentoxide and organic fumes    

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SECTION 11: Toxicological Information
   No information available on title compound. For hexane -- Standard Draize Test (rabbit); 10mg (mild).
   Inhalation (human); TCLo: 190ppm/8W. Oral (rat); LD50: 28710mg/kg. Inhalation (rat); LC50: 48000ppm/4H.
   Intraperitoneal (rat); LDLo: 9100mg/kg. Intravenous (mouse); LDLo: 831mg/kg. Inhalation (rat); TCLo:
   RTECS Data:
   2000ppm/12H/24W-I. Acts a general anesthetic, respiratory depression, altered sleep time, effects on nerves,
   decreased weight gain, muscle weakness, and changes to the liver and blood. Toxic effects observed in the
   embryo and fetus of test animals.
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       For hexane: Possible mutagen    
   Tetratogenic Effects:       For hexane: Possible reproductive effector    

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SECTION 12: Ecological Information
   Ecological Information:       Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.    

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SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

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SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       I    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquid, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       I    
   UN ID Number (IATA):       UN# 1993    

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SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Not reportable under SARA 313    
   Second Ingredient:       Listed on the TSCA inventory. Reportable under SARA 313.    

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SECTION 16 - ADDITIONAL INFORMATION
N/A