羰基双(三氟乙酸基)双(三苯基膦)钌(II)甲醇加合物

羰基双(三氟乙酸基)双(三苯基膦)钌(II)甲醇加合物 基本信息
CAS号 38596-61-1 分子式 C42H34F6O6P2Ru
分子量 911.72400 精确质量  912.07800
PSA  100.01000 LogP  7.40250

等价的CAS号:

38596-61-1,55222-16-7,80558-89-0

基本信息 展开↓

CAS号:
38596-61-1
3D弹球模型:
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分子式:
C42H34F6O6P2Ru
分子量:
911.72400
中文名称:
羰基双(三氟乙酸基)双(三苯基膦)钌(II)甲醇加合物
英文名称:
carbon monoxide,methanol,ruthenium,2,2,2-trifluoroacetic acid,triphenylphosphane
中文别名:
羰基双(三氟乙酸基)双(三苯基膦)钌(II)甲醇加合物;
双(三氟乙酸)羰基双(三苯基膦)钌(II)甲醇加合物;
羰基双(三氟乙酸)双(三苯基膦)钌;
双(三氟乙酸)双(三苯基膦)羰基钌
英文别名:
carbon monoxide,methanol,ruthenium,2,2,2-trifluoroacetic acid,triphenylphosphane;
CARBONYLBIS(TRIFLUOROACETATO)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)METHANOL ADDUCT;
Carbonylbis(trifluoroacetato)bis(triphenylphosphine)ruthenium(II)methanoladduct,min.98%;
Carbonylbis(trifluoroacetato)bis(triphenylphosphine)ruthenium(II) methanol adduct, min. 98%;
Carbonylbis(trifluoroacetato)bis(triphenylphosphine)rutheniuM(II) Methanol adduct,98%;
Bis(trifluoroacetato)carbonylbis(triphenylphosphine)rutheniuM(II) Methanol adduct;
Carbonylbis(trifluoroacetato)bis(triphenylphosphine)ruthenium;
NSC 244260
精确分子量/精确质量:
912.07800
极性分子表面积/PSA:
100.01000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: FDSSZHDREYJHRM-UHFFFAOYSA-L

物化性质展开↓

熔点:
230ºC (dec.)
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):230

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

毒理性展开↓

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Carbonylbis(trifluoroacetato)bis(triphenylphosphine)ruthenium (II) methanol adduct, min. 98%    
   CAS Registry Number:       38596-61-1    
   Formula:       RuCO[(C6H5)3P]2(CF3COO)2.xCH3OH    
   EINECS Number:       none    
   Chemical Family:       metal phosphine complex    
   Synonym:       Carbonylbis(triphenylphosphane)bis(trifluoroacetato)ruthenium (II) methanol adduct    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       38596-61-1       100%       2.5mg/m3 (as F)       205mg/m3 (as F)    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Inhalation, skin, eyes    
   Eye Contact:       Causes mild to moderate irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.    
   Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate
   Chronic Health Affects:       fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth    
   structure, kidney and liver damage.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite or sodium carbonate or other non flammable adsorbent and swept
   Spill and Leak Procedures:
   up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange xtl.    
   Molecular Weight:       879.71    
   Melting Point:       230° dec.    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorous pentoxide, organic fumes    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

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