氢化锶

氢化锶 基本信息
CAS号 13598-33-9 分子式 Sr
分子量 87.62000 精确质量  87.90560
PSA  0.00000 LogP  0.00000

基本信息 展开↓

CAS号:
13598-33-9
分子式:
Sr
分子量:
87.62000
中文名称:
氢化锶
英文名称:
STRONTIUM HYDRIDE
中文别名:
氢化锶
英文别名:
STRONTIUM HYDRIDE;
strontiumhydride(srh2);
strontium dihydride;
Strontium hydride, 99.5% (metals basis);
Dihydridestrontium;
Einecs 237-065-1;
StrontiuM hydride (99.5%-Sr)
精确分子量/精确质量:
87.90560
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
237-065-1

生产制备方法及用途展开↓

合成制备方法


氢化锶的制备方法与氢化钙的相同。其氢化温度为400~500℃。

物化性质展开↓

稳定性相关:

氢化锶为无色的、有光泽的正交结晶。相对密度3.27。化学活泼性由CaH2到BaH2依次递增。与水猛烈反应生成氢气。

安全信息展开↓

包装等级:
II
风险类别:
4.3

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Strontium hydride (99.5%-Sr)    
   CAS Registry Number:       13598-33-9    
   Formula:       SrH2    
   EINECS Number:       237-065-1    
   Chemical Family:       metal hydride    
   Synonym:       Strontium dihydride    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       13598-33-9       100%       no data       no data    

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. Inhalation of fine dust will cause severe irritation or caustic burns to
   Emergency Overview:
   respiratory system, skin and eyes.
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust    
   Eye Contact:       Corrosive to eyes. May cause severe eye damage.    
   Skin Contact:       Causes severe irritation and chemical burns to the skin.    
   Inhalation:       Harmful by inhalation. Dust causes severe irritation to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Harmful if swallowed. Material reacts with moisture causing chemical burns to the mouth and throat.    
   With moisture or human contact, hydride rapidly forms caustic alkali hydroxide with evolution of heat. Severe
   Acute Health Affects:
   irritation or chemical burns will result.
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Class D metal fire agent, dry salt, limestone or sand.    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, burning hydride may produce alkaline fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable solid. Dust may form explosive mixtures with air. Evolves flammable hydrogen with water.

SECTION 6: Accidental Release Measures
   Remove sources of ignition. Do not raise dust. Mix with vermiculite or other suitable dry adsorbent and sweep
   Spill and Leak Procedures:
   up.

SECTION 7: Handling and Storage
   Store material in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from
   Handling and Storage:
   heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       -60mesh gray pwdr.    
   Molecular Weight:       89.64    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       reacts with water    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture and mineral acids. Reaction with mineral acids can release flammable hydrogen gas.    
   Incompatibility:       mineral acids, water, oxidizing agents, alcohols, carbonyl compounds and halogens    
   Decomposition Products:       hydrogen (in presence of moisture) and strontium oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available.    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Metal hydrides, Water-reactive, N.O.S.    
   Hazard Class (CFR):       4.3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       I    
   UN ID Number (CFR):       UN# 1409    
   Shipping Name (IATA):       Metal hydrides, Water-reactive, N.O.S.    
   Hazard Class (IATA):       4.3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       I    
   UN ID Number (IATA):       UN# 1409    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       Not reportable under SARA 313.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A
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