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Section 1: Product Identification
   Chemical Name:       (1R,2R)-2-(Diphenylphosphino)-2,3-dihydro-1H-inden-1-amine, min. 97% (10wt% in THF)    
   CAS Registry Number:       1091606-70-0    
   Formula:       C21H20NP    
   EINECS Number:       none    
   Chemical Family:       aminophosphine ligand    
   Synonym:       (1R,2R)-2-(Diphenylphosphano)-2,3-dihydro-1H-inden-1-amine    

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Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       1091606-70-0       10%       no data       no data    
   THF       109-99-9       90%       50ppm       590mg/m3    

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Section 3: Hazards Identification
   Harmful if swallowed. Inhalation may cause dizziness, headache and shortness of breath. Irritating to skin,
   Emergency Overview:
   eyes and respiratory tract. Possible risk of harm to the unborn child.
   Primary Routes of Exposure:       Inhalation, skin, eyes    
   Eye Contact:       Causes moderate irritation to the eyes.    
   Skin Contact:       Causes moderate to severe irritation of the skin.    
   Harmful by inhalation. May cause coughing, headache and drowsiness. Irritating to the nose, mucous
   Inhalation:
   membranes and respiratory tract.
   Ingestion:       Harmful if swallowed. THF can cause liver damage.    
   Inhalation of vapors causes drowsiness. May cause chest pains, coughing, dizziness, headache and
   Acute Health Affects:
   unsciousness. Possible risk of harm to the unborn child. Irritating to skin and eyes.
   Tetrahydrofuran is an eye and mucous membrane irritant and can cause liver and kidney damage. Possible
   Chronic Health Affects:
   risk of irreversible effects.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

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SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
   Flash Point:       1F (THF)    
   Autoignition Temperature:       610F (THF)    
   Explosion Limits:       1.8% (LEL) 11.8% (UEL)    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Highly flammable material. Vapors can form explosive mixtures with air.

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SECTION 6: Accidental Release Measures
   Eliminate all potential spark sources. Small spills can be absorbed into vermiculite or other chemical adsorbent
   Spill and Leak Procedures:
   suitable for flammable materials. Sweep up the mixture and dispose of properly.

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SECTION 7: Handling and Storage
   Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry, well
   Handling and Storage:
   ventilated place.

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SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

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SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless to pale yellow liq.    
   Molecular Weight:       317.36    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       160mm/Hg@25C(THF)    
   Specific Gravity:       0.89g/cm2 (THF)    
   Odor:       ethereal    
   Solubility in Water:       reacts with water    

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SECTION 10: Stability and Reactivity
   Stability:       air sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       heat, ignition sources, contact with moisture    
   Incompatibility:       water, oxidizing agents, halogens, air and mineral acids    
   Decomposition Products:       carbon monoxide, carbon dioxide, nitrogen oxides, phosphorous oxides and organic fumes    

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SECTION 11: Toxicological Information
   Title compound: No information available in the RTECS files. THF: Inhalation(human); TCLo: 25000ppm.
   Oral(rat); LD50: 1650mg/kg. Inhalation(rat); LC50: 21000ppm/3H. Intraperitoneal(rat); LD50: 2900mg/kg.
   RTECS Data:
   Inhalation(mouse); LCLo: 24000mg/m3/2H. Inhalation(rabbit); LC: >1200ppm/4H. Oral(guinea pig); LDLo:
   500mg/kg. Inhalation(rat); TCLo: 1800ppm/6H/2Y-1.
   Carcinogenic Effects:       THF: Data available    
   Mutagenic Effects:       THF: Possible mutagen    
   Tetratogenic Effects:       THF: Possible reproductive effector    

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SECTION 12: Ecological Information
   Ecological Information:       No information available    

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SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

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SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       I    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquid, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       I    
   UN ID Number (IATA):       UN# 1993    

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SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Not reportable under SARA 313.    
   Second Ingredient:       Listed in the TSCA inventory. Not regulated under SARA    

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SECTION 16 - ADDITIONAL INFORMATION
N/A