酸性黑 1

酸性黑 1 基本信息
CAS号 1064-48-8 分子式 C22H16N6O9S2.2Na
分子量 618.51100 精确质量 　618.02156
PSA 　272.67000 LogP 　7.94080
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目录
基本信息 制备方法与用途 物化性质 安全信息 化学图谱 毒性 MSDS 结构与计算数据 上下游

基本信息 展开↓

CAS号：
1064-48-8
3D弹球模型：
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分子式：
C22H16N6O9S2.2Na
分子量：
618.51100
中文名称：
酸性黑 1
英文名称：
2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-[2-(4-nitrophenyl)diazenyl]-6-(2-phenyldiazenyl)-, sodium salt (1:2)
中文别名：
酸性黑 1;
萘酚蓝;
萘黑10B;
酸性黑1/氨基黑10B;
酸性黑1;
氨基黑10B
英文别名：
2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-[2-(4-nitrophenyl)diazenyl]-6-(2-phenyldiazenyl)-, sodium salt (1:2);
2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-(phenylazo)-, disodium salt (9CI);
Amido Black 10B (6CI);
C.I. Acid Black 1 (7CI);
C.I. Acid Black 1, disodium salt (8CI);
Acid Black 1;
Acid Black 10A;
Acid Black 10B;
Acid Black 10BA;
Acid Black 10BN;
Acid Black 10BX;
Acid Black 12B;
Acid Black 4BN;
Acid Black 4BNU;
Acid Black 8GB;
Acid Black BRX;
Acid Black BX;
Acid Black Base M;
Acid Black H;
Acid Black JVS;
Acid Blue Black;
Acid Blue Black 10B;
Acid Blue Black 10BX;
Acid Blue Black B;
Acid Blue Black BG;
Acid Blue Black Double 600;
Acid Blue Black Sh;
Acid Leather Blue IGW;
Acid Leather Dark Blue G;
Acid Leather Fast Blue Black G;
Acidal Black 10B;
Acidal Black MV;
Acidal Navy Blue 3BR;
Aciderm Black E 10B;
Acilan Black 10B;
Airedale Black 2BG;
Amacid Black 10BR;
Amide Black 10B;
Amido Black;
Amido Blue Black 12B;
Apollo Acid Blue Black 10B;
Atul Acid Black 10BX;
Atul Acid Black BX;
Azanol Fast Acid Black 10B;
Azo Dark Blue C 2B;
Azo Dark Blue HR;
Azo Dark Blue S;
Azo Dark Blue SH;
BTK Black 10BX;
Best Acid Dark Blue B;
Black 401;
Black No. 401;
Blue Black 12B;
Blue Black SX;
Borunil Grey A 10B;
Boruta Black A;
Brasilan Black BS;
Brysoap Black 10B;
Bucacid Blue Black;
Buffalo Black NBR;
C.I. 20470;
Calcocid Blue Black;
Calcocid Blue Black 2R;
Colacid Black 10A;
Colocid Black 10BX;
Colorosacid Blue Black;
Comacid Blue Black B;
Conacid Black A;
Concorde Leather Blue TB;
Covalene Blue Black 6BN;
D & C Black 1;
D and C Black No. 1;
Daedo Acid Black 10BN;
Dermacid Blue G;
Diacid Blue Black 10B;
Dinacid Black 10BX;
Dyacid Black 10B;
Dycosacid Blue Black 10B;
Egacid Black 10B;
Eniacid Black IVS;
Eniacid Black SH;
Erio Black HA;
Eriosin Blue Black B;
Everlan Blue TB;
Fabracid Black S 10BR;
Fast Sulfon Black BN;
Fenazo Blue Black;
Hastings Acid Black 10BG;
Hastings Acid Black 10BR;
Hidacid Blue Black;
Hispacid Black 10B;
Indacid Black 10BX;
Japan Black 401;
Java Blue Black 10B;
Kayaku Acid Blue Black 10B;
Kemacid Black 10BX;
Kiton Black 2B;
Kiton Black HA;
Kiton Blue SM;
Leather Black 10B;
Leather Fast Blue Black G;
Libacid Black 10BX;
Metamine Blue Black;
Mitsui Acid Blue Black;
Monacid Black 10BX;
Multacid Black 10B;
Multicuer Black 10B;
Naphthalene Black 12B;
Naphthalene Black 12BN;
Naphthazine Blue Black 6BN;
Naphthol Black 12B;
Naphthol Blue Black;
Naphthol Blue Black 10B;
Naphthol Blue Black 12B;
Naphthol Blue Black 6B;
Naphthol Blue Black B;
Naphthol Blue Black BC;
Naphthol Blue Black CWC;
Naphthol Blue Black G;
Naphthol Blue Black T;
Naphthylamine Black 10B;
Naphthylamine Black 10BN;
Naphthylamine Black 10BR;
Naphthylamine Black 10BR-CF;
Naphthylamine Black 4B;
Naphtocard Black 12B;
Napththalene Black 12B;
Neelicol Naphthol Blue Black;
Pacid Black 10BX;
Pontacyl Blue Black SX;
Pontacyl Blue Black SXR;
Ravi Acid Black 10BX;
Rifa Acid Blue Black 10B;
Rifa Acid Blue Black 10BN;
Rifa Leather Black P;
Ritacid Black 10B;
Romexal Black 10A;
Sandolan Black E-HL;
Sandopel Blue P;
Simacid Black 10B;
Solar Blue Black;
Special Black 10B;
Tertracid Blue Black NB;
Triacid Blue Black 10B;
Triacid Naphthol Blue;
Vicoacid Black 10BX;
Victacid Black 10BX;
Vondamol Light Black 10B;
Wool Navy Blue 2B
精确分子量/精确质量：
618.02156
极性分子表面积/PSA：
272.67000
油水分配系数/LogP：

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值，反映了物质在油水两相中的分配情况。其中、LogP值越大，说明该物质越亲油；反之，LogP值越小，则说明该物质越亲水。
贝尔斯坦号/MDL：
MFCD00004017
EINECS：
213-903-1
BRN：
5374263
InChI：
InChI=1/C22H16N6O9S2.2Na/c23-19-18-12(11-17(39(35,36)37)21(22(18)29)27-24-13-4-2-1-3-5-13)10-16(38(32,33)34)20(19)26-25-14-6-8-15(9-7-14)28(30)31;;/h1-11,24H,23H2,(H,32,33,34)(H,35,36,37);;/q;2*+1/p-2/b26-25+,27-21+;;

生产制备方法及用途展开↓

制备方法

以 H 酸、对硝基苯胺、苯胺为原料,首先将对硝基苯胺重氮化,于酸性条件下与 H 酸偶合,然后将苯胺重氮化,于碱性条件下与前述偶合产物进行第二次偶合即得产物。经盐析、过滤、干燥、粉碎得成品。。

合成制备方法

1.对硝基苯胺重氮化,与H酸偶合得单偶氮化合物.将苯胺重氮化,与上述单偶化合物偶合而得原料消耗(kg/t)H酸（100%） 240 亚硝酸钠 107对硝基苯胺（100%） 110 碳酸钠（98%） 192苯胺（99%） 66 氢氧化钠（100%）83 .

以 H 酸、对硝基苯胺、苯胺为原料，首先将对硝基苯胺重氮化，于酸性条件下与 H 酸偶合，然后将苯胺重氮化，于碱性条件下与前述偶合产物进行第二次偶合即得产物。经盐析、过滤、干燥、粉碎得成品。

 

用途简介

主要用于羊毛、蚕丝、锦纶及其混纺织物的染色和印花,也可用于拼色

用途

1.酸性黑 10B 主要用于羊毛、蚕丝、锦纶及其混纺织物的染色和直接印花。匀染性较差。可与酸性橙 II (C.I.Acid Orange 7) 拼混成酸性黑 ATT，用途广泛。也用于皮革、纸张、肥皂、木制品、生物、医药、化妆品的着色和制造墨水。

2.色谱分析员试剂，生物染色剂，氧化还原指示剂。

 

物化性质展开↓

外观与性状：
暗红色至黑色粉末
密度：
1.05 g/mL at 20 °C
闪点：
30 °C
水溶解性：
10 G/L (25 ºC)
存储条件/存储方法：

1.密封干燥保存。

稳定性相关：

1.常温常压下稳定，避免氧化物接触

2.水溶液加浓盐酸生成绿光蓝色沉淀； 加氢氧化钠溶液生成蓝色沉淀

3.避免吸入本品的粉尘，避免了与眼睛及皮肤接触。

其它信息：

1.       性状：黑褐色粉末。

2.       密度（g/mL,20℃）： 1.05

安全信息展开↓

海关代码：
3204120000
WGK_Germany：
3
德国有关水污染物质的分类清单
危险类别码：
R36/37/38
安全说明：
26-36-37/39-45-36/37/39-23-16
RTECS号：
QJ6196000
危险标志：
Xi:Irritant

化学图谱

  1. 萘蓝黑红外图谱(IR1)

  2. 萘蓝黑红外图谱(IR2)

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毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QJ6196000
CHEMICAL NAME :
2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-((4-nitrophenyl)azo)-6-(phenylazo )-, disodium salt
CAS REGISTRY NUMBER :
1064-48-8
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C22-H16-N6-O9-S2.2Na
MOLECULAR WEIGHT :
618.54

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
50 ug/plate
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 22,188,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81698 No. of Facilities: 591 (estimated) No. of Industries: 10 No. of Occupations: 23 No. of Employees: 6615 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81698 No. of Facilities: 1816 (estimated) No. of Industries: 20 No. of Occupations: 45 No. of Employees: 51898 (estimated) No. of Female Employees: 26897 (estimated)
生态数据：

对水是稍微有害的，不要让未稀释或大量的产品接触地下水，水道或者污水系统，若无政府许可，勿将材料排入周围环境储存

MSDS 展开↓

Name: Acid Black 1 Material Safety Data Sheet
Synonym: Naphthol blue black; Amido Schwarz
CAS: 1064-48-8
Section 1 - Chemical Product   MSDS Name:Acid Black 1 Material Safety Data Sheet
Synonym:Naphthol blue black; Amido Schwarz
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1064-48-8 C.I. Acid Black 100.0% 213-903-1
Hazard Symbols: XN
Risk Phrases: 20/21 33
Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin. Danger of cumulative effects.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid contact with eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1064-48-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: black
Odor: Not available
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C22H14N6O9S2Na2
Molecular Weight: 616.48
Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, none reported, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of sulfur, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 1064-48-8: QJ6196000 LD50/LC50:
Not available.
Carcinogenicity:
C.I. Acid Black - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
 
Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1064-48-8: 1
Canada
CAS# 1064-48-8 is listed on Canada's DSL List.
CAS# 1064-48-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1064-48-8 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm3/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10-24cm3）：无可用的

7、单一同位素质量：616.005906 Da

8、标称质量：616 Da

9、平均质量：616.4909 Da

计算化学数据

1、   氢键供体数量：2

2、   氢键受体数量：14

3、   可旋转化学键数量：4

4、   互变异构体数量：26

5、   拓扑分子极性表面积（TPSA）：250

6、   重原子数量：41

7、   表面电荷：0

8、   复杂度：1230

9、   同位素原子数量：0

10、   确定原子立构中心数量：0

11、   不确定原子立构中心数量：0

12、   确定化学键立构中心数量：1

13、   不确定化学键立构中心数量：0

14、   共价键单元数量：3

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