高氯酸镥

高氯酸镥 基本信息
CAS号 14646-29-8 分子式 Cl3LuO12
分子量 473.31900 精确质量  471.78600
PSA  222.81000 LogP  0.64290

基本信息 展开↓

CAS号:
14646-29-8
分子式:
Cl3LuO12
分子量:
473.31900
中文名称:
高氯酸镥
英文名称:
lutetium(3+),triperchlorate
中文别名:
高氯酸镥;
LUTETIUM(III) PERCHLORATE SOLUTION 40爓T. % IN H2O;
水合高氯酸镥(III);
高氯酸镥 溶液
英文别名:
lutetium(3+),triperchlorate;
Lutetium triperchlorate;
Perchloric acid,lutetium(3+) salt (8CI,9CI);
Lutetium perchlorate;
Lutetiumperchlorate,octahydrate (7CI)
精确分子量/精确质量:
471.78600
极性分子表面积/PSA:
222.81000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
238-697-0

生产制备方法及用途展开↓

制备方法


将计量的氧化镥用热的稀高氯酸溶液处理。过滤后将滤液用旋转蒸发器在水浴上蒸发至干。

合成制备方法


将计量的氧化镥用热的稀高氯酸溶液处理。过滤后将滤液用旋转蒸发器在水浴上蒸发至干。

用途简介


物化性质展开↓

其它信息:

1. 性状:白色晶体。吸湿。

2. 密度(g/mL,25/4℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:未确定

安全信息展开↓

危险类别码:
R8
安全说明:
17-26-36
安全标志:
S17:远离可燃物质。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
危险标志:
O: Oxidizing agent;Xi: Irritant;

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Lutetium(III) perchlorate, 50% aqueous solution (99.9%-Lu) (REO)    
   CAS Registry Number:       14646-29-8    
   Formula:       Lu(ClO4)3    
   EINECS Number:       none    
   Chemical Family:       metal perchlorate salt    
   Synonym:       Perchloric acid, Lutetium(III) salt, aqueous solution    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       14646-29-8       50%       no data       no data    
   water       7732-18-5       50%       no data       no data    

Section 3: Hazards Identification
   Irritating to eyes, skin and respiratory tract. May be harmful if swallowed. May affect thyroid and kidney
   Emergency Overview:
   functions
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes moderate irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   No specific information is available on the physiological effects of ingestion. May cause gastrointestinal
   Ingestion:
   irritation, nausea, and vomiting.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Water spray    
   Keep sample area wet until fire is completely out. Once dry, product becomes a powerful oxidant, and will act
   Special Fire Fighting Procedures:
   as a source of oxygen to support combustion.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen chloride fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: May decompose explosively if allowed to dry under fire fighting conditions. Do not mix with combustibles.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Adsorb the liquid into vermiculite or other non combustible adsorbent.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container in a cool place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient hood.    
   If ventilation is not available a respirator should be worn. the use of respirators requires Respiratory Protection
   Respirator:
   Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless liq.    
   Molecular Weight:       473.32    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       Air and moisture stable liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Any contact with combustible matter, followed by evaporation of water.    
   None as aqueous solution. If dried, avoid reducing agents, organic matter, active metals, hydrazine, and
   Incompatibility:
   strong acids
   Decomposition Products:       Oxygen, Lutetium oxide, hydrogen chloride,    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Perchlorates, Inorganic, Aqueous solution, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 3211    
   Shipping Name (IATA):       Perchlorates, Inorganic, Aqueous solution, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 3211    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:471.786334 Da

8、标称质量:472 Da

9、平均质量:473.3188 Da

计算化学数据


1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:6

3、   氢键受体数量8

4、   可旋转化学键数量:0

5、   互变异构体数量:

6、   拓扑分子极性表面积(TPSA): 229

7、   重原子数量:22

8、   表面电荷:0

9、   复杂度:95.8

10、 同位素原子数量:0

11、 确定原子立构中心数量:0

12、 不确定原子立构中心数量:0

13、 确定化学键立构中心数量:0

14、 不确定化学键立构中心数量:0

15、 共价键单元数量:10
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