二(四甲基环戊二烯基)铬(II)

二(四甲基环戊二烯基)铬(II) 基本信息
CAS号 82066-37-3 分子式 C18H26Cr
分子量 294.39500 精确质量  294.14400
PSA  0.00000 LogP  5.16380

基本信息 展开↓

CAS号:
82066-37-3
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分子式:
C18H26Cr
分子量:
294.39500
中文名称:
二(四甲基环戊二烯基)铬(II)
英文名称:
BIS(TETRAMETHYLCYCLOPENTADIENYL)CHROMIUM
中文别名:
二(四甲基环戊二烯基)铬(II);
双(四甲基环戊二烯)铬;
双(四甲基环戊二烯)铬(II)
英文别名:
BIS(TETRAMETHYLCYCLOPENTADIENYL)CHROMIUM;
1,1',2,2',3,3',4,4'-Octamethylchromocene;
Bis(tetramethylcyclopentadienyl)chromium(II);
Bis(tetramethylcyclopentadienyl)chromium,min.
精确分子量/精确质量:
294.14400
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD01862451
PubChem:
24880034
InChI:
The Key: ZZGBWOCGOOZKCQ-UHFFFAOYSA-N

物化性质展开↓

外观与性状:
暗红色晶体
熔点:
106-111ºC (dec.)(lit.)
存储条件/存储方法:

2-8°C冷藏、密闭、干燥处

稳定性相关:

按规定使用和贮存的不会分解,避氧化物、空气、水分

其它信息:

1.      性状:暗红色结晶

2.      密度(g/mL25 ºC):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):106-111

5.      沸点(ºC, 常压):未确定

6.      沸点(ºC0.35mmHg):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(正辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

安全信息展开↓

危险类别码:
R20/21/22
安全说明:
S36
安全标志:
S36:穿戴合适的防护服装。
危险标志:
Xn

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Bis(tetramethylcyclopentadienyl)chromium, min. 98%    
   CAS Registry Number:       82066-37-3    
   Formula:       [(CH3)4C5H]2Cr    
   EINECS Number:       none    
   Chemical Family:       metallocene    
   Synonym:       1,1',2,2',3,3',4,4'-Octamethylchromocene    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       82066-37-3       100%       0.5mg/m3 (as Cr)       0.5mg/m3 (as Cr)    

Section 3: Hazards Identification
   May be irritating to eyes, skin and respiratory tract. Chromium (III), a possible metabolite, has acted as a
   Emergency Overview:
   tumorigen and mutagen in animal studies.
   Primary Routes of Exposure:       Ingestion, inhalation of dust.    
   Eye Contact:       May cause slight to mild irritation of the eyes    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       May be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information on the physiological effects of ingestion of this specific compound.    
   Acute Health Affects:       May be irritating to skin, eyes and respiratory tract.    
   It is possible that prolonged exposure could result in formation of Chromium (III) salts in the human body.
   Chronic Health Affects:       Although less toxic than Chromium (VI), some animal studies show Chromium (III) to act as a mutagen and    
   tumorigen.
   NTP:       Yes    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating and toxic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable solid.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Store in a tightly sealed container. Handle and store under an inert atmosphere of nitrogen or argon.
   Handling and Storage:
   Exposure to air may result in degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       red xtl.    
   Molecular Weight:       294.40    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air sensitive solid    
   Hazardous Polymerization:       none    
   Contact with oxygen. Keep away from heat and ignition sources including open flame and electrostatic
   Conditions to Avoid:
   discharge.
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes and chromium oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available from the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable solids, Organic, N.O.S.    
   Hazard Class (CFR):       4.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1325    
   Shipping Name (IATA):       Flammable solid, Organic, N.O.S.    
   Hazard Class (IATA):       4.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1325    

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory    
   SARA (Title 313):       Title compound: see Category Code N090 for reporting    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A
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