硫酸镍铵

硫酸镍铵 基本信息
CAS号 15699-18-0 分子式 H3N.H2O4S.1/2Ni
分子量 288.90234 精确质量 　287.92321
PSA 　178.10000 LogP 　0.81860
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目录
基本信息 制备方法与用途 物化性质 安全信息 毒性 MSDS 结构与计算数据

基本信息 展开↓

CAS号：
15699-18-0
分子式：
H3N.H2O4S.1/2Ni
分子量：
288.90234
中文名称：
硫酸镍铵
英文名称：
Sulfuric acid, ammonium nickel(2+) salt (2:2:1)
中文别名：
硫酸镍铵;
carbon monooxide - osmium (4:1);
4,4'-methanediylbis(3-hydroxynaphthalene-2-carboxylic acid) - 1-methyl-2-[(E)-2-thiophen-2-ylethenyl]-1,4,5,6-tetrahydropyrimidine (1:1);
pyrante;
(6R,7R)-7-{[(2R)-2-amino-2-phenylacetyl]amino}-3-methyl-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid hydrate (1:1);
D-Cephalexin;
Cephalexin;
N-(Tert-Butyl)-2-Chloroacetamide;
Abilit;
Aiglonyl;
N-[(1-ethylpyrrolidin-3-yl)methyl]-2-methoxy-5-sulfamoylbenzamide;
(2S)-1-ethyl-2-({[(2-methoxy-5-sulfamoylphenyl)carbonyl]amino}methyl)pyrrolidinium;
(2R)-1-ethyl-2-({[(2-methoxy-5-sulfamoylphenyl)carbonyl]amino}methyl)pyrrolidinium;
N-(1-Ethyl-pyrrolidin-2-ylmethyl)-2-methoxy-5-sulfamoyl-benzamide;
(+-)-sulpiride;
N-3-Sulfopropylpyridiniumbetaine;
pyridinium,1-(3-sulfopropyl)-,hydroxide,innersalt;
Pyridinium,1-(3-sulfopropyl)-,innersalt;
Pyridium-1-Propane-3-sulfonate;
3-(1-Pyridinio)-1-propanesulfonate 2 M Solution;
Ndsb-2013-(1-Pyridinio)-1-Propanesulfonate;
PpsNickelPlating3-(1-Pyridinio)-1-Propanesulfonate;
Pyridinium propyl sulfobetaine
英文别名：
Sulfuric acid, ammonium nickel(2+) salt (2:2:1);
Ammonium nickel sulfate ((NH4)2Ni(SO4)2) (6CI,7CI);
Diammonium nickel disulfate;
Nickel ammonium sulfate;
Nickel ammonium sulfate (Ni(NH4)2(SO4)2)
精确分子量/精确质量：
287.92321
极性分子表面积/PSA：
178.10000
油水分配系数/LogP：

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值，反映了物质在油水两相中的分配情况。其中、LogP值越大，说明该物质越亲油；反之，LogP值越小，则说明该物质越亲水。
EINECS：
239-793-5
InChI：
InChI=1/H3N.Ni.H2O4S/c;;1-5(2,3)4/h1H3;;(H2,1,2,3,4)/q;+2;/p-1

生产制备方法及用途展开↓

制备方法

1.制法由热的硫酸镍饱和溶液和热的硫酸铵饱和溶液经酸化后混合而得。

合成制备方法

1.制法

由热的硫酸镍饱和溶液和热的硫酸铵饱和溶液经酸化后混合而得。

 

用途简介

用于电镀银、电镀黑镍和刷镀镍电解液中，也用于化学镀镍、浸镍溶液中。

用途

用于电镀银、电镀黑镍和刷镀镍电解液中，也用于化学镀镍、浸镍溶液中。

物化性质展开↓

外观与性状：
暗绿色晶体
熔点：
85-89 °C(lit.)
沸点：
330ºC at 760mmHg
水溶解性：
Soluble
存储条件/存储方法：

存于密闭容器内， 置于凉爽、 通风处， 避免接触强酸、 硫。

稳定性相关：

1.加热时失去结晶水变为黄色结晶粉末。

2.皮肤接触过敏， 症状为发痒、 发红， 而后出现皮疹， 高度暴露或重复暴露会伤肺，引起咳嗽、气短、肺积水、气喘，对心脏、肝、肾有损害。

其它信息：

1.       性状：蓝绿色结晶或结晶性粉末。略有风化性。

2.       密度（g/mL,25/4℃）：1.923

3.       相对蒸汽密度（g/mL,空气=1）：未确定

4.       熔点（ºC）：85-89

5.       沸点（ºC,常压）：未确定

6.       沸点（ºC,5.2kPa）：未确定

7.       折射率：未确定

8.       闪点（ºC）：未确定

9.       比旋光度（º）：未确定

10.    自燃点或引燃温度（ºC）：未确定

11.    蒸气压（kPa,25ºC）：未确定

12.    饱和蒸气压（kPa,60ºC）：未确定

13.    燃烧热（KJ/mol）：未确定

14.    临界温度（ºC）：未确定

15.    临界压力（KPa）：未确定

16.    油水（辛醇/水）分配系数的对数值：未确定

17.    爆炸上限（%,V/V）：未确定

18.    爆炸下限（%,V/V）：未确定

19.溶解性：易溶于水，不溶于乙醇。

安全信息展开↓

WGK_Germany：
3
德国有关水污染物质的分类清单
危险类别码：
R45
安全说明：
S53-S22-S36/37-S45
RTECS号：
WS6061000
危险标志：
T

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WS6050000
CAS REGISTRY NUMBER :
15699-18-0
LAST UPDATED :
199712
DATA ITEMS CITED :
37
MOLECULAR FORMULA :
O8-S2.Ni.2H4-N
MOLECULAR WEIGHT :
286.93

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FDRLI* Food & Drug Research Laboratories, Inc., Papers. (P.O. Box 107, Rt. 17C, Waverly, NY 14892-0107) Volume(issue)/page/year: 8005A,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
68100 ug/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
19600 ug/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
926 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
68100 ug/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
43 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,257,1990 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Ni)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen JAN 1993 OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;Carcinogen (insoluble compounds) JAN 1993 OEL-FRANCE:TWA 1 mg(Ni)/m3 JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen (insoluble compounds) JAN 1993 OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3 JAN 1993 OEL-RUSSIA:STEL 0.05 mg(Ni)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Ni)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THAILAND:TWA 1 mg(Ni)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4948 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 7 (estimated)

MSDS 展开↓

Name: Ammonium Nickel Sulfate Material Safety Data Sheet
Synonym: Nickel ammonium sulfate
CAS: 15699-18-0
Section 1 - Chemical Product   MSDS Name:Ammonium Nickel Sulfate Material Safety Data Sheet
Synonym:Nickel ammonium sulfate
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
15699-18-0 Nickel ammonium sulfate 100 % 239-793-5
Hazard Symbols: XN
Risk Phrases: 22 40 42/43
Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Possible risks of irreversible effects. May cause sensitization by inhalation and skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Dust is irritating to the respiratory tract. May cause allergic respiratory reaction.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section.
Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid contact with skin and eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Soluble in hot water.
Specific Gravity/Density: Not available.
Molecular Formula: O8S2Ni.2H4N
Molecular Weight: 286.8746
Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of sulfur, nickel oxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 15699-18-0: WS6050000 LD50/LC50:
CAS# 15699-18-0: Oral, rat: LD50 = 400 mg/kg.
Carcinogenicity:
Nickel ammonium sulfate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
  For further information, contact Fisher Scientific.
Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
 
CDG/CPL
IMO
No information available.
IATA
No information available.
RID/ADR
No information available.
Canadian TDG
No information available.
Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Possible risks of irreversible effects.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 22 Do not inhale dust.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 15699-18-0:
Canada
CAS# 15699-18-0 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 15699-18-0 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 15699-18-0:. OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3. OEL-A
USTRALIA:TWA 1 mg(Ni)/m3. OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compo
unds). OEL-BELGIUM:TWA 1 mg(Ni)/m3. OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni)
/m3;STEL 0.25 mg(Ni)/m3. OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen. OE
L-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds). OEL-FINLAND:TWA 0.1 m
g(Ni)/m3;Carcinogen. OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble
compounds). OEL-FRANCE:TWA 1 mg(Ni)/m3. OEL-GERMANY;Carcinogen
UNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds). OEL-HUNGARY:STE
L 0.005 mg(Ni)/m3;Carcinogen. OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen. OE
L-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3. OEL-THE NETHERLANDS:TWA 1 mg(Ni)/
m3 (insoluble compounds). OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3. OEL-RUS
SIA:STEL 0.05 mg(Ni)/m3. OEL-SWEDEN:TWA 0.5 mg(Ni)/m3. OEL-SWITZERLAND
:TWA 0.5 mg(Ni)/m3 (insoluble compounds). OEL-SWITZERLAND:TWA 0.5 mg(N
i)/m3;Carcinogen JAN9. OEL-THAILAND:TWA 1 mg(Ni)/m3. OEL-UNITED KINGDO
M:TWA 0.5 mg(Ni)/m3 (insoluble compounds). OEL-UNITED KINGDOM:TWA 1 mg
(Ni)/m3
IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 15699-18-0 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:1

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积89.6

7.重原子数量:7

8.表面电荷:-1

9.复杂度:62.2

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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