乙酸镥

乙酸镥 基本信息
CAS号 18779-08-3 分子式 C6H11LuO7
分子量 370.11400 精确质量  369.99100
PSA  88.13000 LogP  -0.02290

基本信息 展开↓

CAS号:
18779-08-3
分子式:
C6H11LuO7
分子量:
370.11400
中文名称:
乙酸镥
英文名称:
LUTETIUM ACETATE
中文别名:
乙酸镥;
醋酸镥
英文别名:
LUTETIUM ACETATE;
LUTECIUM ACETATE;
aceticacid,lutetium(3++)salt;
lutetium(3+) acetate;
LUTETIUM(III) ACETATE HYDRATE;
Triacetic acid lutetium salt;
LUTETIUM (III) ACETATE;
Lutetium(III) acetate hydrate
精确分子量/精确质量:
369.99100
极性分子表面积/PSA:
88.13000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
242-566-3

生产制备方法及用途展开↓

制备方法


氧化镥(Ⅲ)10g加至500mL 50%醋酸水溶液中,用蒸气浴加热使溶。有时氧化镥(Ⅲ)需用蒸气浴加热一周,才能完全溶解。若加热一周后仍有少量氧化镥(Ⅲ)未能溶解,则需过滤。将清亮溶液放在75℃水浴上加热以蒸去大部分溶剂。冷却,晶体析出,滤集晶体,将其移入玻璃皿中,放在置有粒状氢氧化钠及高氯酸镁的真空保干器中进行干燥,所得产物为水合物。将水合物晶体置于真空干燥枪(阿布得哈顿干燥器)中,于75℃减压(抽真空)干燥至恒重,得到无水醋酸镥(Ⅲ)。

合成制备方法


氧化镥(Ⅲ)10g加至500mL 50%醋酸水溶液中,用蒸气浴加热使溶。有时氧化镥(Ⅲ)需用蒸气浴加热一周,才能完全溶解。若加热一周后仍有少量氧化镥(Ⅲ)未能溶解,则需过滤。将清亮溶液放在75℃水浴上加热以蒸去大部分溶剂。冷却,晶体析出,滤集晶体,将其移入玻璃皿中,放在置有粒状氢氧化钠及高氯酸镁的真空保干器中进行干燥,所得产物为水合物。

将水合物晶体置于真空干燥枪(阿布得哈顿干燥器)中,于75℃减压(抽真空)干燥至恒重,得到无水醋酸镥(Ⅲ)。

用途简介


物化性质展开↓

外观与性状:
白色结晶
沸点:
117.1ºC at 760 mmHg
闪点:
40ºC
稳定性相关:

与1,10菲咯啉作用得到热稳定络合物

其它信息:

1.       性状:无色固体,溶于水。具吸湿性。

2.       密度(g/mL,25/4℃):不确定

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):277~280

5.       沸点(ºC,常压):不确定

6.       沸点(ºC, 5.2kPa):不确定

7.       折射率:不确定

8.       闪点(ºC):不确定

9.       比旋光度(º):不确定

10.    自燃点或引燃温度(ºC):不确定

11.    蒸气压(kPa,25ºC):不确定

12.    饱和蒸气压(kPa,60ºC):不确定

13.    燃烧热(KJ/mol):不确定

14.    临界温度(ºC):不确定

15.    临界压力(KPa):不确定

16.    油水(辛醇/水)分配系数的对数值:不确定

17.    爆炸上限(%,V/V):不确定

18.    爆炸下限(%,V/V):不确定

19.    溶解性:不确定

安全信息展开↓

危险类别码:
R36/37/38:Irritating to eyes, respiratory system and skin .
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Lutetium (III) acetate hydrate(99.9%-Lu) (REO)    
   CAS Registry Number:       18779-08-3    
   Formula:       Lu(OOCCH3)3.XH2O    
   EINECS Number:       242-566-3    
   Chemical Family:       metal acetate salt    
   Synonym:       Acetic acid, lutetium(+3) salt, hydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       18779-08-3       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Ingestion:       Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).    

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a sealed container. Keep away from heat and moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       352.11    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents and active metals    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1、   氢键供体数量:0

2、   氢键受体数量:6

3、   可旋转化学键数量:0

4、   拓扑分子极性表面积(TPSA):120

5、   重原子数量:13

6、   表面电荷:0

7、   复杂度:25.5

8、   同位素原子数量:0

9、   确定原子立构中心数量:0

10、   不确定原子立构中心数量:0

11、   确定化学键立构中心数量:0

12、   不确定化学键立构中心数量:0

13、   共价键单元数量:4

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