二氨合钯硝酸盐

二氨合钯硝酸盐 基本信息
CAS号 14852-83-6 分子式 H6N4O4Pd
分子量 232.49200 精确质量  231.94200
PSA  111.46000 LogP  1.14900

基本信息 展开↓

CAS号:
14852-83-6
分子式:
H6N4O4Pd
分子量:
232.49200
中文名称:
二氨合钯硝酸盐
英文名称:
Diamminepalladium (II) nitrite
中文别名:
二氨合钯硝酸盐;
亚硝酸二氨合钯(Ⅱ)溶液
英文别名:
Diamminepalladium (II) nitrite;
PALLADIUM DIAMINE NITRITE;
Diamminedinitropalladium
精确分子量/精确质量:
231.94200
极性分子表面积/PSA:
111.46000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
238-918-0

物化性质展开↓

密度:
1.027 g/mL at 25ºC
熔点:
230ºC(lit.)
其它信息:

1. 性状:未确定

2. 密度(g/mL,25/4):1.027

3. 相对蒸汽密度(g/mL,空气=1未确定

4. 熔点(ºC):230

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:未确定

安全信息展开↓

危险类别码:
R36/37/38
安全说明:
S26-S36
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
危险标志:
Xi: Irritant;

化学图谱

  1. 亚硝酸二氨合钯(Ⅱ)溶液红外图谱(IR1)

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MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Diamminepalladium (II) nitritesolution (5% Pd)    
   CAS Registry Number:       14852-83-6    
   Formula:       Pd(NH3)2(NO2)2    
   EINECS Number:       238-918-0    
   Chemical Family:       metal-ammine complexes    
   Synonym:       DiammineBis(nitro)palladium, Diamminenitropalladium (II), Diamminenitro palladium    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       14852-83-6       10%       no data       no data    
   water       7732-18-5       90%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes mild to moderate irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Nitrite poisoning results in the blood loosing its capacity to carry oxygen..    
   Irritating to skin, eyes, mucous membranes, and respiratory tract. Nitrite poisoning causes, dizziness, collapse,
   Acute Health Affects:
   rapid heart beat, irregular breathing, coma, convulsions, and death.
   The chronic toxicological properties of this compound have not been thoroughly investigated. Unrecognized
   Chronic Health Affects:
   hazards may be present.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       water, carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic fumes.    
   Decomposion Products:
   Oxidizer when dry. A combustible material upon which the liquid has dried will burn in the absence of oxygen.
   Unusual Fire or Explosion Hazards:

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless to light yellow liq.    
   Molecular Weight:       232.47    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       material is a water solution    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals    
   Decomposition Products:       nitrogen oxides and palladium salts (when water is removed and residue is heated to decomposition)    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Not regulated by Title 313.    
   Second Ingredient:       Listed in the TSCA inventory. Not regulated.    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:231.942388 Da

8、标称质量:232 Da

9、平均质量:232.492 Da

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