二水六氟乙酰丙酮钙

二水六氟乙酰丙酮钙 基本信息
CAS号 203863-17-6 分子式 C10H6CaF12O6
分子量 490.21000 精确质量  489.96000
PSA  71.06000 LogP  3.96120

基本信息 展开↓

CAS号:
203863-17-6
分子式:
C10H6CaF12O6
分子量:
490.21000
中文名称:
二水六氟乙酰丙酮钙
英文名称:
calcium,(Z)-1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,dihydrate
中文别名:
二水六氟乙酰丙酮钙
英文别名:
calcium,(Z)-1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,dihydrate;
Calcium hexafluoroacetylacetonate dihydrate
精确分子量/精确质量:
489.96000
极性分子表面积/PSA:
71.06000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。

物化性质展开↓

外观与性状:
灰白色粉末
熔点:
135-140ºC
沸点:
230-240ºC
其它信息:

1.      性状:未确定

2.      密度(g/mL20 ºC):未确定

3.      相对蒸汽密度(g/mL,空气=1)未确定

4.      熔点(ºC):135-140

5.      沸点(ºC,常压):230-240

6.      沸点(ºC5mmHg):未确定

7.      折射率:未确定

8.      闪点(ºC5mmHg):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

安全信息展开↓

危险标志:
Xi

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Calcium hexafluoroacetylacetonate dihydrate, 97%    
   CAS Registry Number:       203863-17-6    
   Formula:       Ca(CF3COCHCOCF3)2.2H2O    
   EINECS Number:       none    
   Chemical Family:       metal fluorobeta-diketonate complexes    
   Synonym:       Tris-hexafluoroacetylacetonate)calcium; tris(1,1,1,5,5,5-hexafluoro-2,4-pentandionato)calcium    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       203863-17-6       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and mucous membranes.    
   Primary Routes of Exposure:       Ingestion ,inhalation of dust, skin, eyes    
   Eye Contact:       Irritating to eyes. May cause redness and pain.    
   Skin Contact:       Mildly irritating to skin. May cause itching and redness.    
   Inhalation:       Inhalation of dust can lead to irritation of the respiratory tract, causing coughing and sore throat.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate
   Chronic Health Affects:       fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth    
   structure, kidney and liver damage.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       dry chemical, carbon dioxide, water fog, or foam.    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and corrosive hydrogen fluoride.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a tightly sealed container in a cool, dry place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       off-white powder    
   Molecular Weight:       454.18 (486.18)    
   Melting Point:       135-140°    
   Boiling Point:       dec.230-240°    
   Vapor Pressure:       sublimes (180°C/.07mm)    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide, calcium oxide, hydrogen fluoride, carbonyl fluoride, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A
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