硝酸镨

硝酸镨 基本信息
CAS号 15878-77-0 分子式 H12N3O15Pr
分子量 435.01400 精确质量  434.93400
PSA  262.02000 LogP  0.46650

基本信息 展开↓

CAS号:
15878-77-0
分子式:
H12N3O15Pr
分子量:
435.01400
中文名称:
硝酸镨
英文名称:
Praseodymium nitrate
中文别名:
硝酸镨;
硝酸镨(III)六水合物
英文别名:
Praseodymium nitrate;
Praseodymium(Iii) Nitrate Hexahydrate,Reacton,Reo);
Praseodymium trinitrate hexahydrate;
Praseodymium(Iii) Nitrate Hexahydrate;
praseodymium(3+),trinitrate,hexahydrate
精确分子量/精确质量:
434.93400
极性分子表面积/PSA:
262.02000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00149826
EINECS:
233-796-5
PubChem:
24855350
InChI:
InChI=1/3NO3.6H2O.Pr/c3*2-1(3)4;;;;;;;/h;;;6*1H2;/q3*-1;;;;;;;+3

生产制备方法及用途展开↓

制备方法


萃取法:氯化稀土溶液为原料,用P204-煤油-HCl-ReCl3体系萃取,可将稀土混合物分成轻、中、重稀土三组。萃余液La-Nd组轻稀土,按草酸盐沉淀次序为:钐、钕、镨、铈、镧,将其进行分离。可将草酸盐沉淀生成可溶性络合物后再沉淀使其分离,经烘干、灼烧得氧化镨后用硝酸溶解,经结晶、分离得硝酸镨。其反应式如下:

合成制备方法


萃取法:氯化稀土溶液为原料,用P204-煤油-HCl-ReCl3体系萃取,可将稀土混合物分成轻、中、重稀土三组。萃余液La-Nd组轻稀土,按草酸盐沉淀次序为:钐、钕、镨、铈、镧,将其进行分离。可将草酸盐沉淀生成可溶性络合物后再沉淀使其分离,经烘干、灼烧得氧化镨后用硝酸溶解,经结晶、分离得硝酸镨。其反应式如下:

用途简介


实验用试剂。特种合金。用于三元催化剂,化学试剂等其他行业。

用途


 实验用试剂。特种合金。用于三元催化剂,化学试剂等其他行业。

物化性质展开↓

外观与性状:
绿黄色-绿色晶体
密度:
2.233 g/cm3
熔点:
56ºC
沸点:
83ºC at 760 mmHg
折射率:
1.476
蒸汽压:
49.8mmHg at 25°C
存储条件/存储方法:

常温密闭避光,通风干燥

稳定性相关:

常温常压下稳定

避免的物料: 还原剂 易化材料 酸 碱 金属粉末

其它信息:

1. 性状:绿色针状结晶。

2. 密度(g/mL,25/4℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:易溶于水和醇。

安全信息展开↓

包装等级:
III
风险类别:
5.1
WGK_Germany:
2
德国有关水污染物质的分类清单
危险类别码:
R8;R20;R21;R22;R36;R37;R38
安全说明:
S17-S26-S27-S36/37/39
RTECS号:
TU1400000
安全标志:
S17:远离可燃物质。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S27:立刻除去所有污染衣物。
:
危险标志:
O: Oxidizing agent;Xi: Irritant;

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TU1400000
CAS REGISTRY NUMBER :
15878-77-0
LAST UPDATED :
199106
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
N3-O9.Pr.6H2-O
MOLECULAR WEIGHT :
435.06
WISWESSER LINE NOTATION :
PR N-O3*3 &QH 6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
245 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
290 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963
毒理学数据:

急性毒性:小鼠口经LD50:3500 mg/kg

           小鼠腹腔LD50: 245mg/kg;大鼠LD50: 290mg/kg

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Praseodymium (III) nitrate hexahydrate (99.9%-Pr) (REO)    
   CAS Registry Number:       15878-77-0    
   Formula:       Pr(NO3)3.6H2O    
   EINECS Number:       233-796-5    
   Chemical Family:       metal nitrate salts    
   Synonym:       Nitric acid, praseodymium(3+) salt, hexahydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       15878-77-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes slight to mild irritation of the eyes    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       light green xtl.    
   Molecular Weight:       326.92 (435.02)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high
   Conditions to Avoid:
   temperatures.
   Incompatibility:       reducing agents, organic matter, phosphorus and sulfur    
   Decomposition Products:       nitrogen oxides and praseodymium salts    

SECTION 11: Toxicological Information
   Oral (rat); LD50: 3500 mg/kg. Intraperitoneal (rat); LD50: 245 mg/kg. Intraperitoneal (mouse); LD50: 290
   RTECS Data:
   mg/kg.
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1477    
   Shipping Name (IATA):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1477    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N511 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:6

3.氢键受体数量:15

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积195

7.重原子数量:19

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:10

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