高氯酸铕

高氯酸铕 基本信息
CAS号 36907-40-1 分子式 Cl3EuO12
分子量 450.31600 精确质量  449.76700
PSA  222.81000 LogP  0.64290

基本信息 展开↓

CAS号:
36907-40-1
分子式:
Cl3EuO12
分子量:
450.31600
中文名称:
高氯酸铕
英文名称:
Europium(3+) triperchlorate
中文别名:
高氯酸铕
英文别名:
Europium(3+) triperchlorate;
EUROPIUM(III) PERCHLORATE;
Europium (III) perchlorate 50% aqueous sol.;
EuropiumperchlorateaqueoussolEu;
EUROPIUM (III) PERCHLORATE, 50% AQUEOUS SOLUTION (99.9%-EU) (REO);
50%aqueoussolution(99.9%-eu)(reo);
EUROPIUM(III) PERCHLORATE, 50% AQUEOUS SOL.: (99.9% EU) (REO);
EUROPIUM(III) PERCHLORATE, 50% AQUEOUS SOLUTION;
Europium(Ⅲ)Perchlorate
精确分子量/精确质量:
449.76700
极性分子表面积/PSA:
222.81000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。

生产制备方法及用途展开↓

合成制备方法


将氧化铕(Ⅲ)在白金坩埚中加热1h。然后将其溶解在30%高氯酸中。将溶液蒸发至干。

物化性质展开↓

密度:
1.487 g/mL at 25 °C
存储条件/存储方法:

密封、在 0 ºC下保存

稳定性相关:

常规情况下不会分解,没有危险反映。溶于水和乙醇。

 

 

其它信息:

1.       性状:无色或淡粉色晶体。

2.       密度(g/mL,20 ºC):1.487 g/mL at 25 °C

安全信息展开↓

危险类别码:
8-34
安全说明:
17-26-36/37/39-45
危险标志:
O: Oxidizing agent;C: Corrosive;

毒理性展开↓

生态数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Europium (III) perchlorate, 50% aqueous solution (99.9%-Eu)(REO)    
   CAS Registry Number:       36907-40-1    
   Formula:       Eu(ClO4)3    
   EINECS Number:       none    
   Chemical Family:       metal perchlorate salt    
   Synonym:       Perchloric acid, Europium(III) salt, aqueous solution    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       36907-40-1       50%       no data       no data    
   water       7732-18-5       50%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes moderate irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   No specific information is available on the physiological effects of ingestion. May cause gastrointestinal
   Ingestion:
   irritation, nausea, and vomiting.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Water spray    
   Keep sample area wet until fire is completely out. Once dry, product becomes a powerful oxidant, and will act
   Special Fire Fighting Procedures:
   as a source of oxygen to support combustion.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen chloride fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: May decompose explosively if allowed to dry under fire fighting conditions. Do not mix with combustibles.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Adsorb the liquid into vermiculite or other non combustible adsorbent.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container in a cool place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an effeicient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an effeicient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless liq.    
   Molecular Weight:       450.31    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       Air and moisture stable liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Any contact with combustible matter, followed by evaporation of water.    
   None as aqueous solution. If dried, avoid reducing agents, organic matter, active metals, hydrazine, and
   Incompatibility:
   strong acids
   Decomposition Products:       Oxygen, Europium oxide, hydrogen chloride,    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Perchlorates, Inorganic, Aqueous solution, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 3211    
   Shipping Name (IATA):       Perchlorates, Inorganic, Aqueous solution, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 3211    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1、   疏水参数计算参考值(XlogP):未确定

2、   氢键供体数量:0

3、   氢键受体数量:12

4、   可旋转化学键数量:0

5、   拓扑分子极性表面积(TPSA):223

6、   重原子数量:16

7、   表面电荷:0

8、   复杂度:95.8

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:4

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:4

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