草酸三钾铁三水合物

草酸三钾铁三水合物 基本信息
CAS号 5936-11-8 分子式 C6FeK3O12
分子量 437.19700 精确质量  436.76500
PSA  199.29000 LogP  -6.77110

基本信息 展开↓

CAS号:
5936-11-8
分子式:
C6FeK3O12
分子量:
437.19700
中文名称:
草酸三钾铁三水合物
英文名称:
POTASSIUM TRIOXALATOFERRATE(III)
中文别名:
草酸三钾铁三水合物;
三草酸铁(III)钾三水合物;
草酸铁钾;
三草酸高铁酸钾三水合物
英文别名:
POTASSIUM TRIOXALATOFERRATE(III);
POTASSIUM FERRIC OXALATE TRIHYDRATE;
POTASSIUM TRIS(OXALATO)FERRATE(III) TRIHYDRATE;
POTASSIUM TRIS(OXALATE)FERRATE (III) TRIHYDRATE;
FERRIC POTASSIUM OXALATE;
IRON (III) TRIPOTASSIUM OXALATE;
IRON(III) TRIPOTASSIUM OXALATE TRIHYDRATE;
Irontripotassiumoxalatetrihydrate
精确分子量/精确质量:
436.76500
极性分子表面积/PSA:
199.29000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00150450
EINECS:
238-954-7

物化性质展开↓

外观与性状:
绿色晶体
密度:
2.133^2^0
熔点:
100ºC (loss of 3 H2O)
存储条件/存储方法:

 

稳定性相关:

 

其它信息:

 

安全信息展开↓

包装等级:
III
风险类别:
6.1
危险类别码:
36/37/38
安全说明:
26-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

化学图谱

  1. 三草酸高铁酸钾三水合物红外图谱(IR1)

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毒理性展开↓

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Potassium tris(oxalato)ferrate(III) trihydrate    
   CAS Registry Number:       5936-11-8    
   Formula:       K3Fe(C2O4)3.3H2O    
   EINECS Number:       none    
   Chemical Family:       organometallic complexes    
   Synonym:       Ferrate(3-), tris(oxalato)-, potassium    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       5936-11-8       100%       1mg/m3 (as Fe - soluble)       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and mucous membranes. Harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, eyes    
   Eye Contact:       Causes mild to severe irritation of the eyes.    
   Skin Contact:       Causes mild to severe irritation of the skin.    
   Inhalation:       Dust is irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Harmful if swallowed. May cause kidney damage.    
   A mild to severe irritant to skin, eyes and respiratory tract. Ingestion causes severe irritation to the mouth,
   Acute Health Affects:
   esophagus and stomach.
   The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
   Chronic Health Affects:
   may be present.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       dry chemical, carbon dioxide, or foam.    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic and corrosive fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry place in a tightly sealed container away from light.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       green xtl    
   Molecular Weight:       437.20 (491.25)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       light sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents and active metals    
   Decomposition Products:       iron oxide, potassium carbonate, and carbon monoxide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:436.765038Da

8、标称质量:437Da

9、平均质量:437.1969Da

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