二甲基(乙酰丙酮)黄金(III)

二甲基(乙酰丙酮)黄金(III) 基本信息
CAS号 14951-50-9 分子式 C7H13AuO2
分子量 326.14300 精确质量  326.05800
PSA  26.30000 LogP  2.12520

基本信息 展开↓

CAS号:
14951-50-9
3D弹球模型:
立即前往扯扯看
分子式:
C7H13AuO2
分子量:
326.14300
中文名称:
二甲基(乙酰丙酮)黄金(III)
英文名称:
Dimethyl(acetylacetonate)gold(III), 98% (99.9%-Au)
中文别名:
二甲基(乙酰丙酮)黄金(III)
英文别名:
Dimethyl(acetylacetonate)gold(III), 98% (99.9%-Au);
DIMETHYL(ACETYLACETONATE)GOLD(III);
Dimethyl(acetylacetonate)gold(III),98%(99.9%-Au);
Tris-(2,4-pentanedionato)-dimethylgold;
dimethylgold(III) acetylacetonate;
Dimethyl(acetylacetonate)gold (III), 98% (99.9%-Au) **MUST SHIP OVERNIGHT/DRY ICE**;
DiMethyl(acetylacetonate)gold(III) (99.9%-Au)
精确分子量/精确质量:
326.05800
极性分子表面积/PSA:
26.30000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: UPMKWHDSHRUVSU-FGSKAQBVSA-M

物化性质展开↓

熔点:
81-82ºC
沸点:
25ºC 0,01mm
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):81-82

5.       沸点(ºC,常压):25/0.01mm

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

安全信息展开↓

海关代码:
2918300090
危险类别码:
36/37/38
安全说明:
26-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

毒理性展开↓

生态数据:

 

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Dimethyl(acetylacetonate)gold (III), 98% (99.9%-Au) **MUST SHIP OVERNIGHT/DRY ICE**    
   CAS Registry Number:       14951-50-9    
   Formula:       (CH3)2(C5H7O2)Au    
   EINECS Number:       None    
   Chemical Family:       metal alkyl    
   Synonym:       Dimethylgold (III) acetylacetonate; Dimethylgold (III) 2,5-pentanedionate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       14951-50-9       100%       no data       no data    

Section 3: Hazards Identification
   May be irritating to skin, eyes, and respiratory tract. Exposure to gold compounds may damage kidney
   Emergency Overview:
   function and reduce blood cell count.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Dust may be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion may lead to dermatitis, dizziness, metallic taste, abdominal cramps, vomiting, bloody diarrhea,
   Ingestion:
   weakness, and convulsions.
   May cause irritation to the eyes, skin and respiratory tract, impairment of kidney and bone marrow function,
   Acute Health Affects:
   abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
   Chronic Health Affects:       Prolonged exposure to gold compounds may lead to reduced red and white blood cell generation.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite, or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store under inert atmosphere in a tightly sealed container. Store cold.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to off-white xtl.    
   Molecular Weight:       326.6    
   Melting Point:       81-82°C    
   Boiling Point:       subl. ~25°C/0.01mm    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       (store cold)    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents and active metals    
   Decomposition Products:       carbon monoxide, carbon dioxide, and gold.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2918300090

概述:
2918300090 其他含醛基或酮基不含其他含氧基羧酸(包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物). 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

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