三羰基亚硝酰基钴

三羰基亚硝酰基钴 基本信息
CAS号 14096-82-3 分子式 C3CoNO4
分子量 172.97000 精确质量  172.91600
PSA  29.43000 LogP  -0.40690

基本信息 展开↓

CAS号:
14096-82-3
3D弹球模型:
立即前往扯扯看
分子式:
C3CoNO4
分子量:
172.97000
中文名称:
三羰基亚硝酰基钴
英文名称:
COBALT TRICARBONYL NITROSYL
中文别名:
三羰基亚硝酰基钴;
Cobalt tricarbonyl nitrosyl
英文别名:
COBALT TRICARBONYL NITROSYL;
Co(CO)3NO;
Cobalt,tricarbonylnitrosyl-,(T-4);
TRICARBONYLNITROSYLCOBALT
精确分子量/精确质量:
172.91600
极性分子表面积/PSA:
29.43000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00016014
EINECS:
237-945-5
InChI:
The Key: RVSVSZMFMFSHQQ-UHFFFAOYSA-N

物化性质展开↓

密度:
1,47 g/cm3
熔点:
-11ºC
沸点:
50ºC
存储条件/存储方法:

常温密闭避光,通风干燥惰性气体下

稳定性相关:

常温常压下稳定

避免的物料:氧化物 卤素 空气 热

其它信息:

1.      性状:深红色液体

2.      密度(g/mL,25/4):2.09

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):-1.05

5.      沸点(ºC,常压):48.6

6.      沸点(ºC,5.2kPa):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度º):未确定

10.   自燃点或引燃温度(ºC):不适用的

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:不能拌和的或难以拌和的

安全信息展开↓

包装等级:
II
风险类别:
6.1
危险类别码:
20/21/22-40
安全说明:
26-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

毒理性展开↓

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;     

在眼睛上面:刺激的影响;没有已知的敏化影响。

生态数据:

对水体是危害的,即使小量产品不能接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Cobalt tricarbonyl nitrosyl    
   CAS Registry Number:       14096-82-3    
   Formula:       Co(CO)3NO    
   EINECS Number:       237-945-5    
   Chemical Family:       metal carbonyl complexes    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       14096-82-3       100%       0.02mg/m3       no data    

Section 3: Hazards Identification
   Harmful by inhalation, in contact with skin and if swallowed. Inhalation can lead to headaches and dizziness.
   Emergency Overview:
   Prolonged exposure can lead to convulsions and coma.
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May cause mild irritation to the eyes.    
   Skin Contact:       Harmful in contact with skin. May cause mild irritation to the skin.    
   Inhalation:       Harmful through inhalation. Inhalation could lead to dizziness and headache.    
   Ingestion:       Harmful if swallowed.    
   Harmful by inhalation, in contact with skin and if swallowed. Inhalation can lead to headaches and dizziness.
   Acute Health Affects:
   Prolonged exposure can lead to convulsions and coma.
   Chronic Health Affects:       No information on long term exposure.    
   NTP:       No    
   IARC:       Yes    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as
   Inhalation:
   possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital.
   Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious).
   Ingestion:
   Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry chemical or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus.
   Hazardous Combustion and       carbon monoxide, carbon dioxide, and cobalt oxides.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable liquid. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small quantities can be mixed with sodium carbonate or vermiculite and swept up. If large quantities are
   Spill and Leak Procedures:
   spilled, and ventilation is not available, personnel should be fitted with a self- contained breathing apparatus.

SECTION 7: Handling and Storage
   Handling and Storage:

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling chemical substances.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       This product should be handled in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance 29 CFR 1910.134.
   Ventilation:       This product should be handled in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       dark red liq.    
   Molecular Weight:       172.97    
   Melting Point:       no data    
   Boiling Point:       50°C    
   Vapor Pressure:       no data    
   Specific Gravity:       1.47    
   Odor:       musty odor    
   Solubility in Water:       Insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air sensitive, (store cold)    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       prolonged contact with air.    
   Incompatibility:       Oxidizing agents and halogens    
   Decomposition Products:       carbon dioxide, carbon monoxide, cobalt oxides.    

SECTION 11: Toxicological Information
   RTECS Data:       No specific information available on this product.    
   Carcinogenic Effects:       Possible carcinogen (as Co)    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available.    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of this material according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, toxic, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       6.1    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1992    
   Shipping Name (IATA):       Flammable liquid, toxic, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       6.1    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1992    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N096 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:172.915932Da

8、标称质量:173Da

9、平均质量:172.9696Da

立即下载安装“化学加”APP
专业、功能强大,随时调用更加方便