三甲基硅烷

三甲基硅烷 基本信息
CAS号 993-07-7 分子式 C3H10Si
分子量 74.19700 精确质量  74.05520
PSA  0.00000 LogP  1.10290

基本信息 展开↓

CAS号:
993-07-7
分子式:
C3H10Si
分子量:
74.19700
中文名称:
三甲基硅烷
英文名称:
TRIMETHYLSILANE
中文别名:
三甲基硅烷;
Methylchlorosilane;
Silane, chloromethyl-;
Methylchlorosilane [UN2534] [Poison gas];
UN2534;
chloro-methyl-silicon;
2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol;
Phenol, 4-((4,6-bis(octylthio)-s-triazin-2-yl)amino)-2,6-di-tert-butyl-(8CI);
4-{[4,6-bis(octylsulfanyl)-1,3,5-triazin-2-yl]amino}-2,6-di-tert-butylphenol;
Antioxidant 565;
2,4-Bis-(octylthio)-6-(3,5-di-tert-butyl-4-hydroxyanilino)-1,3,5-triazine;
Rhodamine 6G;
Sodium (2S-(2alpha,5alpha,6beta))-6-(((2-ethoxy-1-naphthyl)carbonyl)amino)-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo(3.2.0)heptane-2-carboxylate;
sodium 6-{[(2-ethoxynaphthalen-1-yl)carbonyl]amino}-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylate;
sodium (2S,5R,6R)-6-{[(2-ethoxynaphthalen-1-yl)carbonyl]amino}-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylate;
4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid, 6-[[(2-ethoxy-1-naphthalenyl)carbonyl]amino]-3,3-d;
Nafcillin sodium;
SC 9376;
Spirolactone SC 14266;
UNII-78O20X9J0U;
17alpha-Pregna-4,6-d
英文别名:
TRIMETHYLSILANE;
Trimethylsilyl hydride,2-Methyl-2-silapropane;
2-Methyl-2-silapropane;
trimethyl-silane;
SILICON TRIMETHYL;
trimethylsilicon;
trimethyl-silan
精确分子量/精确质量:
74.05520
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
213-603-0
InChI:
InChI=1/C3H10Si/c1-4(2)3/h4H,1-3H3

物化性质展开↓

密度:
0.63
熔点:
-135.9ºC
沸点:
6.7ºC
闪点:
<-29ºC

安全信息展开↓

海关代码:
2931900090
危险类别码:
R12
安全说明:
9-16-26-33
安全标志:
S9:保持容器在一个有良好通风放的场所。
S16:远离火源。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S33:采取防护措施防止静电发生。

合成路线查看所有的合成路线

  • 16853-85-3

    氢化铝锂

  • +

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    三甲基氯硅烷

  • ~79%

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    三甲基硅烷

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  • ~69%

  • 993-07-7

    三甲基硅烷

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Trimethylsilane, 97%    
   CAS Registry Number:       993-07-7    
   Formula:       (CH3)3SiH    
   EINECS Number:       213-603-0    
   Chemical Family:       organosilicon compounds    
   Synonym:       Silane, trimethyl    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       993-07-7       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin, eyes, and respiratory tract.    
   Primary Routes of Exposure:       Inhalation, skin, eyes.    
   Eye Contact:       May cause moderate irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   May cause irritation to the nose, mucous membranes and respiratory tract. May be harmful through inhalation.
   Inhalation:
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes and mucous membranes. May be harmful through inhalation.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       <-4°F    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       Burning material may emit toxic and corrosive fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Highly flammable. Material readily ignited with flames, sparks, friction or heat.

SECTION 6: Accidental Release Measures
   The material will evaporate rapidly at room temperature. Leave the area unless fitted with a self-contained
   Spill and Leak Procedures:       breathing apparatus or until the vapors have dispersed. Larger spills can be absorbed into vermiculite or other    
   suitable noncombustible adsorbent. Sweep up the material and dispose of properly.

SECTION 7: Handling and Storage
   Handling and Storage:       The material is stored in steel cylinder.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       gas    
   Molecular Weight:       74.2    
   Melting Point:       -135.9°    
   Boiling Point:       6.7°C    
   Vapor Pressure:       no data    
   Specific Gravity:       0.638 (6.7°)    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with heat or ignition sources.    
   Incompatibility:       Strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, silicon dioxide, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Liquefied Gas, Flammable, N.O.S.    
   Hazard Class (CFR):       2.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       UN# 3161    
   Shipping Name (IATA):       Liquefied Gas, Flammable, N.O.S.    
   Hazard Class (IATA):       2.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       UN# 3161    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:4

8.表面电荷:0

9.复杂度:8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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