左旋葡萄糖酮

左旋葡萄糖酮 基本信息
CAS号 37112-31-5 分子式 C6H6O3
分子量 126.11000 精确质量  126.03200
PSA  35.53000 LogP  -0.13320

基本信息 展开↓

CAS号:
37112-31-5
3D弹球模型:
立即前往扯扯看
分子式:
C6H6O3
分子量:
126.11000
中文名称:
左旋葡萄糖酮
英文名称:
levoglucosenone
中文别名:
左旋葡萄糖酮;
Cyclohexylidenecyanoacetic acid;
3-methylbenzene-1,2-dicarboxylate;
Dmc 2-Chloro-1,3-Dimethylimidazolidinium Chloride;
2-chloro-1,3-dimethylimidazolidinium chloride;
5-methoxy-1H-benzimidazole-2-thiol;
5-methoxybenzimidazolin-2-thione;
5-methoxybenzimidazolin-2-mercapto;
5-methoxy-1,3-dihydro-benzoimidazole-2-thione;
5-Methoxy-1,3-dihydro-benzimidazol-2-thion;
1,3-dihydro-5-methoxy-2H-benzimidazole-2-thione;
Methoxy-2-mercaptobenzimidazole,5-;
2-MERCAPTO-5-METHOXY-1H-BENZIMIDAZOLE;
5-METHOXY-2-THIOBENZIMIDAZOLE;
5-METHOXY-1H-BENZO[D]IMIDAZOLE-2-THIOL;
TIMTEC-BB SBB000219;
5-Methoxy-2-mercaplobenzinidazole;
Esomeprazole EP impurities;
2-Mercapto-5-methoxybenzimidazole;
HSDB 3583;
Kaminax;
Lukadin;
Mikavir;
NSC 177001;
O-3-Amino-3-deoxy-alpha-D-glucopyranosyl-(1-4)-O-(6-amino-6-deoxy-alpha-D-glucopyranosyl-(1-6))-N(sup 3)-(4-amino-L-2-hydroxybutyryl)-2-deoxy-L-streptamine;
Pierami;
UNII-84319SGC3C;
D-Streptamine, O-3-amino-3-deoxy-alpha-D-glucopyranosyl-(1-6)-O-(6-amino-6-deoxy-alpha-D-glucopyranosyl-(1-4))-N1-(4-amino-2-hydroxy-
英文别名:
levoglucosenone;
LEVOGLUCOSENONE;
Levoglucosenone
精确分子量/精确质量:
126.03200
极性分子表面积/PSA:
35.53000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
InChI=1/C6H6O3/c7-5-2-1-4-3-8-6(5)9-4/h1-2,4,6H,3H2/t4?,6-/m1/s1

物化性质展开↓

密度:
1.329g/cm3
沸点:
254.4ºC at 760mmHg
闪点:
98.2ºC
折射率:
1.516

安全信息展开↓

海关代码:
2932999099

合成路线查看所有的合成路线

  • 50705-28-7

    .beta.-D-threo-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-

  • ~86%

  • 37112-31-5

    左旋葡萄糖酮

  • 58394-28-8

    .beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-

  • ~80%

  • 37112-31-5

    左旋葡萄糖酮

  • 152492-81-4

    152492-81-4

  • ~41%

  • 37112-31-5

    左旋葡萄糖酮

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JG7020000
CHEMICAL NAME :
6,8-Dioxabicyclo(3.2.1)oct-2-en-4-one, (1S)-
CAS REGISTRY NUMBER :
37112-31-5
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-H6-O3
MOLECULAR WEIGHT :
126.12

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
2 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 227,117,1989

MSDS 展开↓

  Levoglucosenone      Revision number: 5    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Levoglucosenone    
    
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None    
    No signal word
  Signal word
  Hazard statements        None    
    None
  Precautionary statements:

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Components:        Levoglucosenone    
  Percent:        >96.0%(GC)    
  CAS Number:        37112-31-5    
  Chemical Formula:        C6H6O3    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with    
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Unsuitable extinguishing Solid streams of water
  media:
  Levoglucosenone

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent generation of vapour or mist. Wash hands and face thoroughly after
    handling.
    Use a ventilation, local exhaust if vapour or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store away from incompatible materials such as oxidizing agents.
    Light-sensitive
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be    
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Vapor respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
    Clear
  Form:
  Colour:        Yellow - Reddish yellow    
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        113°C/0.4kPa    
    No data available
  Flash point:
  Flammability or explosive
  limits:
  Lower:        No data available    
    No data available
  Upper:
  Relative density:        1.31    
  Solubility(ies):
  [Water]        No data available    
  Levoglucosenone

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  [Other solvents]        No data available    

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available    
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: cyt-ham-lng 2 mg/L
  Carcinogenicity:
  IARC =        No data available    
    No data available
  NTP =
  Reproductive toxicity:        No data available    
    JG7020000
  RTECS Number:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Levoglucosenone


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2932999099

概述:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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