9-(环氧-2-甲基)-9H-咔唑

9-(环氧-2-甲基)-9H-咔唑 基本信息
CAS号 52131-82-5 分子式 C15H13NO
分子量 223.27000 精确质量  223.10000
PSA  17.46000 LogP  3.19330

基本信息 展开↓

CAS号:
52131-82-5
3D弹球模型:
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分子式:
C15H13NO
分子量:
223.27000
中文名称:
9-(环氧-2-甲基)-9H-咔唑
英文名称:
9-(oxiran-2-ylmethyl)carbazole
中文别名:
9-(环氧-2-甲基)-9H-咔唑;
9-(2-环氧乙烷基甲基)咔唑;
9-(环氧乙烷-2-基甲基)-9H-咔唑;
9-(环氧乙烷-2-基甲基)咔唑;
9-环氧丙基咔唑
英文别名:
9-(oxiran-2-ylmethyl)carbazole;
[(carbazol-9-yl)methyl]oxirane;
2-(9-carbazolyl)methyloxirane;
9-(2-oxiranylmethyl)carbazole;
9-(2,3-epoxypropyl)-9H-carbazole;
9-(oxiran-2-ylmethyl)-9H-carbazole;
N-(2,3-Epoxypropyl)-carbazole;
9-(2,3-epoxypropyl)carbazole;
BB_SC-0614;
2-(carbazol-9-ylmethyl)oxirane
精确分子量/精确质量:
223.10000
极性分子表面积/PSA:
17.46000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: VAJIZAPXBKMPRO-UHFFFAOYSA-N

物化性质展开↓

密度:
1.25g/cm3
熔点:
110ºC
沸点:
409.7ºC at 760 mmHg
闪点:
201.6ºC
折射率:
1.677

安全信息展开↓

海关代码:
2933990090
危险类别码:
36/37/38
安全说明:
26-36/37/39

合成路线查看所有的合成路线

  • 86-74-8

    咔唑

  • +

  • 106-89-8

    环氧氯丙烷

  • ~90%

  • 52131-82-5

    9-(环氧-2-甲基)-9H-咔唑

  • 86-74-8

    咔唑

  • +

  • 3132-64-7

    环氧溴丙烷

  • ~69%

  • 52131-82-5

    9-(环氧-2-甲基)-9H-咔唑

  • 3998-04-7

    9-prop-2-enylcarbazole

  • ~14%

  • 52131-82-5

    9-(环氧-2-甲基)-9H-咔唑

MSDS 展开↓

Name: 9-(Oxiran-2-ylmethyl)-9H-carbazole 97% Material Safety Data Sheet
Synonym:
CAS: 52131-82-5
Section 1 - Chemical Product   MSDS Name:9-(Oxiran-2-ylmethyl)-9H-carbazole 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
52131-82-5 9-(Oxiran-2-ylmethyl)-9H-carbazole 97% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 52131-82-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 110 - 112 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C15H13NO
Molecular Weight: 223

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, ammonia.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 52131-82-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
9-(Oxiran-2-ylmethyl)-9H-carbazole - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 52131-82-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 52131-82-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 52131-82-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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