1,2-双(二氯膦)-1,2-二甲基肼

1,2-双(二氯膦)-1,2-二甲基肼 基本信息
CAS号 37170-64-2 分子式 C2H6Cl4N2P2
分子量 261.84200 精确质量  259.87600
PSA  33.66000 LogP  4.17400

基本信息 展开↓

CAS号:
37170-64-2
3D弹球模型:
立即前往扯扯看
分子式:
C2H6Cl4N2P2
分子量:
261.84200
中文名称:
1,2-双(二氯膦)-1,2-二甲基肼
英文名称:
1,2-bis(dichlorophosphanyl)-1,2-dimethylhydrazine
中文别名:
1,2-双(二氯膦)-1,2-二甲基肼
英文别名:
1,2-bis(dichlorophosphanyl)-1,2-dimethylhydrazine;
1,2-BIS(DICHLOROPHOSPHINO)-1,2-DIMETHYLHYDRAZINE;
1,2-Bis(dichlorophosphino)-1,2-dimethylhydrazine,min.98%;
1,2-BIS(DICHLOROPHOSPHINO)-1, 2-DIMETHYLHYDRAZINE, MIN. 98%
精确分子量/精确质量:
259.87600
极性分子表面积/PSA:
33.66000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: QUBGOLWADXVEJJ-UHFFFAOYSA-N

物化性质展开↓

存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

安全信息展开↓

海关代码:
2928000090
危险类别码:
20/21/22-36/37/38
安全说明:
26-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

合成路线查看所有的合成路线

  • 540-73-8

    1,2-二甲基肼

  • 37170-64-2

    1,2-双(二氯膦)-1,2-二甲基肼

  • 3478-74-8

    2,3,5,6,7,8-hexamethyl-2,3,5,6,7,8-hexaza-1,4-diphosphabicyclo[2.2.2]octane

  • 37170-64-2

    1,2-双(二氯膦)-1,2-二甲基肼

毒理性展开↓

生态数据:

 

 

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       1,2-Bis(dichlorophosphino)-1,2-dimethylhydrazine, min. 98%    
   CAS Registry Number:       37170-64-2    
   Formula:       Cl2PN(CH3)N(CH3)PCl2    
   EINECS Number:       none    
   Chemical Family:       organophosphorus compound    
   Synonym:       None    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       37170-64-2       100%       no data       no data    

Section 3: Hazards Identification
   Harmful by inhalation and if swallowed. Inhalation of vapors may lead to headache and dizziness. Corrosive to
   Emergency Overview:
   skin, eyes and mucous membranes.
   Primary Routes of Exposure:       Ingestion, skin, inhalation    
   Eye Contact:       Causes burns to the eyes.    
   Skin Contact:       Causes burns to the skin.    
   The material has a pungent odor. Inhalation may lead to headaches and dizziness. Corrosive to nose and
   Inhalation:
   mucous membranes.
   Ingestion:       Harmful if swallowed.    
   Acute Health Affects:       Harmful by inhalation and if swallowed. Corrosive to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite or other suitable absorbents. Spillage in areas not adequately
   Spill and Leak Procedures:       ventilation will require an evacuation of site. Emergency response teams will require self-contained breathing    
   apparatus. Spill should be absorbed into vermiculite or other suitable absorbent.

SECTION 7: Handling and Storage
   Handling and Storage:       Material must be handled and stored under an inert atmosphere of nitrogen or argon.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective gloves and clothing.    
   Ventilation:       Material has a pungent odor. Always handle material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material has a pungent odor. Always handle material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless to slightly cloudy liq.    
   Molecular Weight:       261.84    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       acidic odor    
   Solubility in Water:       reacts with water    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture-sensitive liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with air and moisture    
   Incompatibility:       water, oxidizing agents and halogens    
   carbon dioxide, carbon monoxide, phosphorus pentoxide, nitrogen oxides, hydrogen chloride, and organic
   Decomposition Products:
   fumes.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Corrosive liquids, N.O.S.    
   Hazard Class (CFR):       8    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1760    
   Shipping Name (IATA):       Corrosive liquid, N.O.S.    
   Hazard Class (IATA):       8    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1760    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2928000090

概述:
2928000090 其他肼(联氨)及胲(羟胺)的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据


1.疏水参数计算参考值(XlogP):3.4

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积6.5

7.重原子数量:10

8.表面电荷:0

9.复杂度:89.3

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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