Version 1.4
    Regulation (EC) No 1907/2006

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    1 - Product and Company Information

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    Product Name        DIMETHYLALUMINUM CHLORIDE, 1.0M    
    SOLUTION IN HEXANES

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    2 - Hazards Identification

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    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Reacts violently with water, liberating extremely flammable gases.
    Spontaneously flammable in air. Toxic by inhalation, in contact
    with skin and if swallowed. Causes burns.

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    3 - Composition/Information on Ingredients

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    Product Name        CAS #        EC no        Annex I    
    Index Number
    DIMETHYLALUMINUM CHLORIDE, 1.0M None        None        None    
    SOLUTION IN HEXANES
    Formula        C2H6AlCl    
    Molecular Weight 92,5100 AMU

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    4 - First Aid Measures

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    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER EYE CONTACT
    Assure adequate flushing of the eyes by separating the eyelids
    with fingers.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately.

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    5 - Fire Fighting Measures

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    CONDITIONS OF FLAMMABILITY
    Reacts with water to liberate flammable and/or explosive gas.
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    Catches fire if exposed to air.
    EXTINGUISHING MEDIA
    Suitable: Dry chemical powder.
    Unsuitable: Do not use water.
    Explosion Hazards: Container explosion may occur under fire
    conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.
    SPECIFIC METHOD(S) OF FIRE FIGHTING
    Use water spray to cool fire-exposed containers.

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    6 - Accidental Release Measures

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    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area. Shut off all sources of ignition.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Cover with dry-lime, sand, or soda ash. Place in covered
    containers using non-sparking tools and transport outdoors.
    Ventilate area and wash spill site after material pickup is
    complete.

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    7 - Handling and Storage

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    HANDLING
    Directions for Safe Handling: Do not get in eyes, on skin, on
    clothing. Do not breathe vapor.
    STORAGE
    Conditions of Storage: Keep tightly closed. Keep away from heat,
    sparks, and open flame. Store in a cool dry place.
    Incompatible Materials: Do not allow contact with water
    SPECIAL REQUIREMENTS: Air sensitive.

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    8 - Exposure Controls / Personal Protection

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    ENGINEERING CONTROLS
    Safety shower and eye bath. Use only in a chemical fume hood.
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Where risk assessment shows air-purifying respirators
    are appropriate use a dust mask type N95 (US) or type P1 (EN 143)
    respirator.
    Hand Protection: Wear heavy rubber gloves.
    Eye Protection: Chemical safety goggles.
    Special Protective Measures: Impervious protective clothing.
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    Faceshield (8-inch minimum).

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    9 - Physical and Chemical Properties

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    pH N/A
    BP/BP Range        N/A    
    MP/MP Range        N/A    
    Flash Point        - 18,000 °C.        Method: closed cup    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    SG/Density        0,7010 g/cm3    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

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    10 - Stability and Reactivity

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    STABILITY
    Conditions to Avoid: Moisture.
    Materials to Avoid: Oxygen, Oxidizing agents, Alcohols, Acids
    Reacts violently with water.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Hydrogen chloride gas, Aluminum
    oxide Carbon monoxide, Carbon dioxide.

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    11 - Toxicological Information

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    SIGNS AND SYMPTOMS OF EXPOSURE
    Symptoms of exposure may include burning sensation, coughing,
    wheezing, laryngitis, shortness of breath, headache, nausea, and
    vomiting. Inhalation may result in spasm, inflammation and edema
    of the larynxand bronchi, chemical pneumonitis, and pulmonary
    edema. Material is extremely destructive to tissue of the mucous
    membranes and upper respiratory tract, eyes, and skin.
    Neurotoxic effects. Warning: contains n-hexane (CAS#110-54-3) a
    suspected neurotoxin.
    ROUTE OF EXPOSURE
    Multiple Routes: Harmful if swallowed, inhaled, or absorbed
    through skin. Causes burns.

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    12 - Ecological Information

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    No data available.

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    13 - Disposal Considerations

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    SUBSTANCE DISPOSAL
    Place the material which has been previously covered or mixed with
    dry sand, lime, or soda ash in a large metal pan outdoors. Slowly
    add portions of dry butanol until reaction ceases. Cautiously add
    water from a distance until material has been flooded completely.
    Observe all federal, state, and local environmental regulations.

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    14 - Transport Information

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    RID/ADR
    UN#: 3394
    Class: 4.2
    PG: I
    Subrisk: 4.3
    Proper Shipping Name: Organometallic substance,
    liquid, pyrophoric, water-reactive
    IMDG
    UN#: 3394
    Class: 4.2
    PG: I
    Subrisk: 4.3
    Proper Shipping Name: Organometallic substance,
    liquid, pyrophoric, water-reactive
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 3394
    Class: 4.2
    PG: I
    Subrisk: 4.3
    Proper Shipping Name: Organometallic substance,
    liquid, pyrophoric, water-reactive
    Inhalation Packing Group I: No
    Technical Name: Required

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    15 - Regulatory Information

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    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: F-C
    Highly Flammable. Corrosive.
    R-PHRASES: 14/15-17-23/24/25-34
    Reacts violently with water, liberating extremely flammable
    gases. Spontaneously flammable in air. Toxic by inhalation, in
    contact with skin and if swallowed. Causes burns.
    S-PHRASES: 16-26-36/37/39-45
    Keep away from sources of ignition - no smoking. In case of
    contact with eyes, rinse immediately with plenty of water and
    seek medical advice. Wear suitable protective clothing, gloves,
    and eye/face protection. In case of accident or if you feel
    unwell, seek medical advice immediately (show the label where
    possible).
    Caution: Substance not yet fully tested (EU).

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    16 - Other Information
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    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A