(+)-3,3-二氯-2,N-环氧-外型-10,2-莰烷磺内酰胺

(+)-3,3-二氯-2,N-环氧-外型-10,2-莰烷磺内酰胺 基本信息
CAS号 127184-05-8 分子式 C10H13Cl2NO3S
分子量 298.18600 精确质量  296.99900
PSA  58.06000 LogP  2.90210

基本信息 展开↓

CAS号:
127184-05-8
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分子式:
C10H13Cl2NO3S
分子量:
298.18600
中文名称:
(+)-3,3-二氯-2,N-环氧-外型-10,2-莰烷磺内酰胺
英文名称:
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
中文别名:
(+)-3,3-二氯-2,N-环氧-外型-10,2-莰烷磺内酰胺;
(+)-8,8-二氯樟脑磺哑嗪
英文别名:
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine;
()-3,3-Dichloro-2,N-epoxy-exo-10,2-bornanesultam;
[2R-(2|A,4a|A,7|A,8aR*)]-8,8-Dichlorotetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide;
(+)-((8,8-Dichlorocamphoryl)sulfonyl)oxaziridine
精确分子量/精确质量:
296.99900
极性分子表面积/PSA:
58.06000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: HAMBQYFZDBYWHU-JYMQCGNZSA-N

物化性质展开↓

密度:
1.687 g/cm3
熔点:
181-186ºC
沸点:
390.471ºC at 760 mmHg
闪点:
189.95ºC
折射率:
1.648

安全信息展开↓

包装等级:
III
风险类别:
5.1
安全说明:
S22-S24/25

合成路线查看所有的合成路线

  • 127184-04-7

    (1S)-(-)-(7,7-Dichloro-10-camphorsulfonyl)imine

  • ~90%

  • 127184-05-8

    (+)-3,3-二氯-2,N-环氧-外型-10,2-莰烷磺内酰胺

  • 60886-80-8

    (1S)-(-)-樟脑内磺酰亚胺

  • 127184-05-8

    (+)-3,3-二氯-2,N-环氧-外型-10,2-莰烷磺内酰胺

MSDS 展开↓

Name: (+)-[(8 8-Dichlorocamphoryl)sulfonyl]oxazi ridine Material Safety Data Sheet
Synonym: (+)-3,3-Dichloro-2,N-epoxy-exo-10,2-bornanesulta
CAS: 127184-05-8
Section 1 - Chemical Product   MSDS Name:(+)-[(8 8-Dichlorocamphoryl)sulfonyl]oxazi ridine Material Safety Data Sheet
Synonym:(+)-3,3-Dichloro-2,N-epoxy-exo-10,2-bornanesulta

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
127184-05-8 (+)-[(8,8-Dichlorocamphoryl)sulfonyl]o unlisted
Hazard Symbols: Not available.
Risk Phrases:

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Keep under a nitrogen blanket.
Refrigerator (approx 4C).

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 180 - 181 deg C
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C10H13Cl2NO3S
Molecular Weight: 298.18

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 127184-05-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  For further information, contact Fisher Scientific.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
CDG/CPL
IMO
Not regulated as a hazardous material.
IATA
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Canadian TDG
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 127184-05-8:
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
WHMIS: Not available.
CAS# 127184-05-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 127184-05-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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