异丙基甲基二氯硅烷

异丙基甲基二氯硅烷 基本信息
CAS号 18236-89-0 分子式 C4H10Cl2Si
分子量 157.11 精确质量  155.99288
PSA  0.00 A2 LogP  2.691±0.394

基本信息 展开↓

CAS号:
18236-89-0
3D弹球模型:
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分子式:
C4H10Cl2Si
分子量:
157.11
中文名称:
异丙基甲基二氯硅烷
英文名称:
Silane, dichloromethyl(1-methylethyl)-
中文别名:
异丙基甲基二氯硅烷;
甲基异丙基二氯硅烷;
CCRIS 2663;
Cyclopenta(c)pyran-7-carboxaldehyde, 4-((acetyloxy)methyl)-;
Cyclopenta(c)pyran-7-carboxaldehyde, 4-(hydroxymethyl)-, acetate;
(7-formylcyclopenta[c]pyran-4-yl)methyl acetate;
Baldrinal;
1,2-dimyristoyl-sn-glycero-3-phospho-choline monohydrate;
1-methylethyl 4-bromo-α-(4-bromophenyl)-α-hydroxybenzeneacetate;
propan-2-yl bis(4-bromophenyl)(hydroxy)acetate;
Bromopropylate;
3-chloropropyl methyl dimethoxyl silane;
γ-chloropropylmethylbimethoxy silane;
1,3-bis(4-methoxyphenyl)propane-1,3-dionato;
(3-chloropropyl)dimethoxymethyl-Silane;
(4-chloro-1,1-dimethoxybutyl)silane;
γ-Chloropropyl methyldimethoxy silane;
γ-Chloropropylmethyldimethoxysilane;
trans-Zearalenone;
(S-(E))-3,4,5,6,9,10-Hexahydro-14,16-dihydroxy-3-methyl-1H-2-benzoxacyclotetradecin-1,7(8H)-dione;
1H-2-Benzoxacyclotetradecin-1,7(8H)-dione, 3,4,5,6,9,10-hexahydro-14,16-dihydroxy-3-methyl-, (3S,11E)-;
1H-2-Benzoxacyclotetradecin-1,7(8H)-dione, 3,4,5,6,9,10-hexahydro-14,16-dihydroxy-3-methyl-, (S)-(-)-;
(3S,11E)-14,16-dihydroxy-3-methyl-3,
英文别名:
Silane, dichloromethyl(1-methylethyl)-;
dichloro-methyl-propan-2-ylsilane;
Methylisopropyldichlorosilane;
sNpLADQpTPduuUP@;
Isopropylmethyldichlorosilane;
Dichlor-isopropyl-methyl-silan;
Dichlor-methyl-isopropyl-silan
精确分子量/精确质量:
155.99288
极性分子表面积/PSA:
0.00 A2
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00054830
InChI:
InChI=1/C4H10Cl2Si/c1-4(2)7(3,5)6/h4H,1-3H3

物化性质展开↓

外观与性状:
透明无色液体
密度:
1.023±0.06 g/cm3
沸点:
123.1±8.0 °C
闪点:
18.4±16.0 °C
水溶解性:
Sparingly Soluble (0.25 g/L)
折射率:
1.425-1.428
蒸汽压:
16.3mmHg at 25°C
蒸汽密度:
16.3 Torr
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):1.033

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):121

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:1.425-1.428

8.       闪点(ºC):14

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

安全信息展开↓

海关代码:
2931900090
危险类别码:
R34
安全说明:
45-36/37/39-25
安全标志:
S16:远离火源。
S25:避免接触眼睛。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C: Corrosive;

合成路线查看所有的合成路线

  • 75-79-6

    甲基三氯硅烷

  • +

  • 75-26-3

    溴代异丙烷

  • 18236-89-0

    异丙基甲基二氯硅烷

  • 75-79-6

    甲基三氯硅烷

  • +

  • 1068-55-9

    异丙基氯化镁

  • 18236-89-0

    异丙基甲基二氯硅烷

  • 2227-32-9

    异丙基甲基一氯一氢硅烷

  • 18165-88-3

    methyl(propan-2-yl)silane

  • +

  • 18236-89-0

    异丙基甲基二氯硅烷

毒理性展开↓

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓

Name: Isopropylmethyldichlorosilane 97% Material Safety Data Sheet
Synonym:
CAS: 18236-89-0
Section 1 - Chemical Product   MSDS Name:Isopropylmethyldichlorosilane 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
18236-89-0 Isopropylmethyldichlorosilane 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns. May cause conjunctivitis. May cause blindness.
Contact with the eyes may cause corneal damage.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 18236-89-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Clear liquid
Color: colorless
Odor: hydrochloric odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 121 deg C @ 760 mmH
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: Not available.
Molecular Formula: (CH3)2CHSi(Cl)2CH3
Molecular Weight: 157.0615

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Water, oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 18236-89-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Isopropylmethyldichlorosilane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 18236-89-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 18236-89-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 18236-89-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

分子结构与计算化学数据展开↓

分子结构数据


1   摩尔折射率:38.95

2   摩尔体积m3/mol):153.4

3   等张比容90.2K):324.7

4   表面张力3.0 dyne/cm):420.0

5   极化率0.5 10-24cm3):15.44

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:7

8.表面电荷:0

9.复杂度:60.7

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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