二氯化二硒

二氯化二硒 基本信息
CAS号 10025-68-0 分子式 Cl2Se2
分子量 228.82600 精确质量  229.77100
PSA  0.00000 LogP  0.61740

基本信息 展开↓

CAS号:
10025-68-0
3D弹球模型:
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分子式:
Cl2Se2
分子量:
228.82600
中文名称:
二氯化二硒
英文名称:
chloroselanyl selenohypochlorite
中文别名:
二氯化二硒;
一氯化硒;
氯化亚硒(I)
英文别名:
chloroselanyl selenohypochlorite;
selenium monochloride;
dichlorodiselenane;
monoselenium monochloride;
Selenium chloride;
Diselenium dichloride;
Se2Cl2;
Diselendichlorid;
EINECS 233-037-8
精确分子量/精确质量:
229.77100
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00011226
EINECS:
233-037-8
InChI:
The Key: VIEXQFHKRAHTQS-UHFFFAOYSA-N

生产制备方法及用途展开↓

制备方法


1.反应装置为一带滴液漏斗的圆底烧瓶。将115g新升华的SeO2放入烧瓶中,并加入500mL浓盐酸(36%~37%)使其溶解,再加入235g硒,然后从滴液漏斗中滴入浓硫酸,直至不再有HCl气体发生为止。反应生成的红色的Se2Cl2沉在反应器的底部,冷却后用分液漏斗将其分离出来。用浓硫酸将反应产物洗涤数次,或将其溶于发烟硫酸中,然后通HCl将其析出。产物中存在残余硫酸可用无水BaCl2处理后,在隔绝外界湿气的条件下用玻璃砂芯漏斗过滤。收率可达90%左右。2.反应装置为一带气体导入管的蒸馏烧瓶,气体导入管插至瓶底,烧瓶上接一下降的冷凝管并与接受瓶相联,从接受瓶上引出一气体导出管,经一装有酸的洗涤瓶后直接通到通风橱的排气管中。将300g发烟硫酸(含30%SO3)装入蒸馏瓶中,在摇动下将100g粉末状的硒加入其中。将干燥的HCl气体通入反应混合物中,并小心地加热蒸馏瓶,使硒刚刚开始挥发。不久接受瓶中就开始有Se2Cl2滴下。调节蒸馏速度,使其在2h内约馏出130g产物。粗产品可用少量发烟硫酸与其混合摇荡数次,至不再呈绿色为止。最后与制法1一样用无水BaCl2进行处理。

合成制备方法


1.反应装置为一带滴液漏斗的圆底烧瓶。将115g新升华的SeO2放入烧瓶中,并加入500mL浓盐酸(36%~37%)使其溶解,再加入235g硒,然后从滴液漏斗中滴入浓硫酸,直至不再有HCl气体发生为止。反应生成的红色的Se2Cl2沉在反应器的底部,冷却后用分液漏斗将其分离出来。用浓硫酸将反应产物洗涤数次,或将其溶于发烟硫酸中,然后通HCl将其析出。产物中存在残余硫酸可用无水BaCl2处理后,在隔绝外界湿气的条件下用玻璃砂芯漏斗过滤。收率可达90%左右。

2.反应装置为一带气体导入管的蒸馏烧瓶,气体导入管插至瓶底,烧瓶上接一下降的冷凝管并与接受瓶相联,从接受瓶上引出一气体导出管,经一装有酸的洗涤瓶后直接通到通风橱的排气管中。将300g发烟硫酸(含30%SO3)装入蒸馏瓶中,在摇动下将100g粉末状的硒加入其中。将干燥的HCl气体通入反应混合物中,并小心地加热蒸馏瓶,使硒刚刚开始挥发。不久接受瓶中就开始有Se2Cl2滴下。调节蒸馏速度,使其在2h内约馏出130g产物。粗产品可用少量发烟硫酸与其混合摇荡数次,至不再呈绿色为止。最后与制法1一样用无水BaCl2进行处理。

用途简介


用作分析试剂、还原剂。

用途


用作分析试剂、还原剂。[11]

物化性质展开↓

外观与性状:
暗棕色红色液体
密度:
2.73 g/mL at 25 °C(lit.)
熔点:
-85°C
沸点:
127°C
闪点:
127°C
存储条件/存储方法:
库房通风低温干燥,与酸类,食品分开储运
稳定性相关:

1.稳定性[6]  稳定

2.禁配物[7]  强氧化剂、强酸、强碱、磷、钾、过氧化钾、过氧化钠

3.避免接触的条件[8]  潮湿空气

4.聚合危害[9]  不聚合

其它信息:

1.性状:深棕红色油状液体[1]

2.熔点(℃):-85[2]

3.沸点(分解,℃):130[3]

4.相对密度(水=1):2.77[4]

5.溶解性:溶于氯仿、苯、四氯化碳、二硫化碳。[5]

安全信息展开↓

包装等级:
II
风险类别:
8
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R23/24/25
安全说明:
22-26-36/37/39-45
RTECS号:
VS7855000
危险标志:
T: Toxic;

合成路线查看所有的合成路线

  • 7791-23-3

    氧氯氢酸酯

  • +

  • 7719-12-2

    三氯化磷

  • 10026-03-6

    四氯化硒

  • +

  • 10025-68-0

    二氯化二硒

  • 7440-36-0

  • +

  • 7791-23-3

    氧氯氢酸酯

  • 7647-18-9

    氯化锑(V)

  • +

  • 10025-91-9

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  • 10025-67-9

    二氯化二硫

  • +

  • 1015938-55-2

    diselenium dibromide

  • 136429-85-1

    136429-85-1

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  • 136429-86-2

    136429-86-2

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  • 136448-74-3

    136448-74-3

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  • 136429-87-3

    136429-87-3

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  • 10025-68-0

    二氯化二硒

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VS7855000
CHEMICAL NAME :
Selenium chloride
CAS REGISTRY NUMBER :
10025-68-0
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
Cl2-Se2
MOLECULAR WEIGHT :
228.82
毒理学数据:

1.急性毒性 暂无资料

2.刺激性 暂无资料

生态数据:

1.通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

2.生态毒性 暂无资料

3.生物降解性 暂无资料

4.非生物降解性 暂无资料

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Selenium (I) chloride (99%-Se)    
   CAS Registry Number:       10025-68-0    
   Formula:       Se2Cl2    
   EINECS Number:       none    
   Chemical Family:       metal halide    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10025-68-0       100%       0.2mg/m3 (as Se)       0.2mg/m3 (as Se)    

Section 3: Hazards Identification
   Emergency Overview:       Harmful by inhalation, in contact with skin and if swallowed. Corrosive to skin and eyes.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes burns to the eyes.    
   Skin Contact:       Causes burns to the skin.    
   Inhalation:       Harmful by inhalation. Inhalation of vapors will lead to burning of the respiratory tract.    
   Ingestion:       Harmful if swallowed. Caustic burns to the gastrointestinal system may occur.    
   Harmful by inhalation, in contact with skin and if swallowed. Corrosive to skin, eyes and respiratory tract and
   Acute Health Affects:
   cause eye, skin burns, dyspnea (breathing difficulty), and pulmonary edema
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       Carbon dioxide, sand, dry chemical powder.    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic chlorine and hydrochloric acid fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.
   Spill and Leak Procedures:       Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams    
   will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
   Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume
   Handling and Storage:
   hood. Prolonged exposure to the atmosphere may lead to degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       red liq.    
   Molecular Weight:       228.53    
   Melting Point:       -85°    
   Boiling Point:       130°C dec.    
   Vapor Pressure:       no data    
   Specific Gravity:       2.77    
   Odor:       Pungent odor.    
   Solubility in Water:       reacts with water    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       water, mineral acids and active metals    
   Decomposition Products:       with moisture: hydrochloric acid and selenium oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Avoid release to groundwater or waterways. Very toxic to aquatic organisms. May cause long-term adverse
   Ecological Information:
   effects.

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Corrosive liquids, Toxic, N.O.S.    
   Hazard Class (CFR):       8    
   Additional Hazard Class (CFR):       6.1    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 2922    
   Shipping Name (IATA):       Corrosive liquid, Toxic, N.O.S.    
   Hazard Class (IATA):       8    
   Additional Hazard Class (IATA):       6.1    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 2922    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See category code N725 for reporting    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:229.770749Da

8、标称质量:230Da

9、平均质量:228.826Da

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:4

8.表面电荷:0

9.复杂度:6

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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