二(异丙基氨基)二甲基硅烷

二(异丙基氨基)二甲基硅烷 基本信息
CAS号 6026-42-2 分子式 C8H22N2Si
分子量 174.35900 精确质量  174.15500
PSA  24.06000 LogP  2.46600

基本信息 展开↓

CAS号:
6026-42-2
3D弹球模型:
立即前往扯扯看
分子式:
C8H22N2Si
分子量:
174.35900
中文名称:
二(异丙基氨基)二甲基硅烷
英文名称:
N-[dimethyl-(propan-2-ylamino)silyl]propan-2-amine
中文别名:
二(异丙基氨基)二甲基硅烷;
1,1-Dimethyl-n,n’-bis(1-methylethyl)-silanediamin Di(Isopropylamino)Dimethylsilane Bis(isopropylamino)dimethylsilane Di(isopropylamino)dimethylsilane95+% Dimethylsilanediylbis(isopropylamine) N,N'-Diisopropyldimethylsilanediamine α,α-Dimethyl-N,N'-bis(1-m
英文别名:
N-[dimethyl-(propan-2-ylamino)silyl]propan-2-amine;
EINECS 227-885-8;
Bis-isopropylamino-dimethyl-silan;
1,1-Dimethyl-N,N'-diisopropylsilanediamine
精确分子量/精确质量:
174.15500
极性分子表面积/PSA:
24.06000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD01861707
EINECS:
227-885-8
InChI:
The Key: UNOQITWAUFOMKI-UHFFFAOYSA-N

物化性质展开↓

外观与性状:
透明无色液体
密度:
0.812g/cm3
沸点:
148ºC
闪点:
50.1ºC
折射率:
1.411-1.415
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。

稳定性相关:

常温常压下稳定,避免与不相容材料,热源接触。
与水,酸,碱,醇,铝,氯酸盐,铜,锌反应。

其它信息:

1.      性状:无色透明有氨味的液体

2.      密度(g/mL,25):0.798

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):148

6.      沸点(ºC11mmHg):47-48

7.      折射率(n20/D)1.411-1.416

8.      闪点(ºC):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(mmHg,20ºC):未确定

12.   饱和蒸气压(kPa,25ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:与水反应

安全信息展开↓

海关代码:
2931900090
危险类别码:
R36/37/38
安全说明:
S26-S37-S39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi

合成路线查看所有的合成路线

  • 75-31-0

    异丙胺

  • +

  • 75-78-5

    二氯二甲基硅烷

  • ~90%

  • 6026-42-2

    二(异丙基氨基)二甲基硅烷

  • 6026-03-5

    1-chloro-N-isopropyl-1,1-dimethylsilanamine

  • 6026-42-2

    二(异丙基氨基)二甲基硅烷

MSDS 展开↓

Name: Di(isopropylamino)dimethylsilane 95% Material Safety Data Sheet
Synonym:
CAS: 6026-42-2
Section 1 - Chemical Product   MSDS Name:Di(isopropylamino)dimethylsilane 95% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6026-42-2 Di(isopropylamino)dimethylsilane 95% 227-885-8
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. Contact with the eyes may cause corneal damage.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. Ingestion causes severe burns of the mouth and stomach.
Inhalation:
Causes respiratory tract irritation. May cause lung damage. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use carbon dioxide or dry chemical.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6026-42-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Clear liquid
Color: colorless
Odor: amine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: C8H20Si
Molecular Weight: 144.2255

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Water, oxidizing agents, acids, bases, alcohols, aluminum, copper, chlorates, zinc.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 6026-42-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Di(isopropylamino)dimethylsilane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 6026-42-2: No information available.
Canada
CAS# 6026-42-2 is listed on Canada's DSL List.
CAS# 6026-42-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6026-42-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:4

5.互变异构体数量:无

6.拓扑分子极性表面积24.1

7.重原子数量:11

8.表面电荷:0

9.复杂度:98.7

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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    1-chloro-N-isopropyl-1,1-dimethylsilanamine

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