二氯(N,N,N’,N’-四甲基乙二胺)钯

二氯(N,N,N’,N’-四甲基乙二胺)钯 基本信息
CAS号 14267-08-4 分子式 C6H16Cl2N2Pd
分子量 293.53100 精确质量  291.97300
PSA  6.48000 LogP  1.48860

基本信息 展开↓

CAS号:
14267-08-4
3D弹球模型:
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分子式:
C6H16Cl2N2Pd
分子量:
293.53100
中文名称:
二氯(N,N,N’,N’-四甲基乙二胺)钯
英文名称:
Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)
中文别名:
二氯(N,N,N’,N’-四甲基乙二胺)钯;
二氯(N,N,N',N'-四甲基乙二胺)钯;
顺-二氯(N,N,N`,N`-四甲基乙烯二胺)钯(II)
英文别名:
Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II);
N,N,N',N'-tetramethylethylenediamine palladium(II) chloride;
Palladium,dichloro(N,N,N',N'-tetramethyl-1,2-ethanediamine-N,N')-,(sp-4-2);
cis-dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II);
(N,N,N',N'-tetramethylethylenediamine)PdCl2;
Palladium,dichloro(N,N,N',N'-tetramethylethylenediamine);
(N,N,N',N'-tetramethylethylenediamine)dichloridopalladium(II);
[Pd(tmen)Cl2];
DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II);
Cl2Pd(II)(TMEDA);
dichloro(N,N,N',N'-tetramethylethylene-diamine)pa
精确分子量/精确质量:
291.97300
极性分子表面积/PSA:
6.48000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00075317
PubChem:
24861301
InChI:
InChI=1/C6H16N2.2ClH.Pd/c1-7(2)5-6-8(3)4;;;/h5-6H2,1-4H3;2*1H;/q;;;+2/p-2

物化性质展开↓

熔点:
245ºC (dec.)(lit.)
沸点:
121ºC at 760 mmHg
闪点:
10ºC
蒸汽压:
14.9mmHg at 25°C
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.      性状:无可用

2.      密度(g/mL,25/4):无可用

3.      相对蒸汽密度(g/mL,空气=1):无可用

4.      熔点(ºC):245

5.      沸点(ºC,常压):无可用

6.      沸点(ºC,5.2kPa):无可用

7.      折射率:无可用

8.      闪点(ºC):无可用

9.      比旋光度(º):无可用

10.   自燃点或引燃温度(ºC):无可用

11.   蒸气压(kPa,25ºC):无可用

12.   饱和蒸气压(kPa,60ºC):无可用

13.   燃烧热(KJ/mol):无可用

14.   临界温度(ºC):无可用

15.   临界压力(KPa):无可用

16.   油水(辛醇/水)分配系数的对数值:无可用

17.   爆炸上限(%,V/V):无可用

18.   爆炸下限(%,V/V):无可用

19.   溶解性:无可用

安全信息展开↓

危险类别码:
R36/37/38
安全说明:
37/39-26
危险标志:
Xi: Irritant;

合成路线查看所有的合成路线

  • 21264-30-2

    21264-30-2

  • +

  • 110-18-9

    四甲基乙二胺

  • ~98%

  • 14267-08-4

    二氯(N,N,N’,N’-四甲基乙二胺)钯

  • 570397-18-1

    dichloro-(1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene)palladium

  • +

  • 110-18-9

    四甲基乙二胺

  • ~97%

  • 14267-08-4

    二氯(N,N,N’,N’-四甲基乙二胺)钯

  • 14592-56-4

    双(乙腈)氯化钯(II)

  • +

  • 110-18-9

    四甲基乙二胺

  • ~97%

  • 14267-08-4

    二氯(N,N,N’,N’-四甲基乙二胺)钯

毒理性展开↓

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       cis-Dichloro(N,N,N'N'-tetramethylethylenediamine)palladium(II), 99%    
   CAS Registry Number:       14267-08-4    
   Formula:       C6H16Cl2N2Pd    
   EINECS Number:       none    
   Chemical Family:       organometallic complex    
   Synonym:       cis-ichloroN,N,N',N'-Tetramethyl-ethane-1,2-diamine)palladium(II)    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       14267-08-4       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow powder    
   Molecular Weight:       293.53    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide, palladium oxide and organic fumes    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、  摩尔体积(cm3/mol):无可用       

3、  等张比容(90.2K):无可用

4、  表面张力(dyne/cm):无可用

5、  极化率:无可用

计算化学数据


1、  疏水参数计算参考值(XlogP):无可用

2、  氢键供体数量:0

3、  氢键受体数量:2

4、  可旋转化学键数量:3

5、  拓扑分子极性表面积(TPSA):6.5

6、  重原子数量:11

7、  表面电荷:0

8、  复杂度:45.2

9、  同位素原子数量:0

10、  确定原子立构中心数量:0

11、  不确定原子立构中心数量:0

12、  确定化学键立构中心数量:0

13、  不确定化学键立构中心数量:0

14、  共价键单元数量:2

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