---

Section 1: Product Identification
   Chemical Name:       Vinyltriethylsilane(hexafluoroacetylacetonato)silver (I) (99.9%-Ag)    
   CAS Registry Number:       177279-28-6    
   Formula:       Ag(CF3COCHCOCF3)(C8H18Si)    
   EINECS Number:       None    
   Chemical Family:       metal beta-diketonate complexes    
   Synonym:       Vinyltriethylsilylsilver(I) (hexafluoroacetylacetonato)    

---

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       177279-28-6       100%       0.01mg/m3 (Ag sl)       0.01mg/m3 (Ag sl)    

---

Section 3: Hazards Identification
   Irritating to eyes, skin and respiratory tract. If inhaled or swallowed this compound may cause fluoride
   Emergency Overview:
   poisoning. Early symptoms include nausea, vomiting, diarrhea, and weakness
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes mild to severe irritation of the eyes    
   Causes slight to mild irritation of the skin. Contact with the skin can lead to formation of dark blotches (silver
   Skin Contact:
   staining)
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, convulsions, and
   Ingestion:
   fluoride poisoning.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Long term exposure to silver and silver salts can lead to the condition known as argyria - a general gray
   Chronic Health Affects:       pigmentation of the skin and mucous membranes. Chronic fluoride poisoning can cause severe bone    
   changes, loss of weight, and dental defects.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

---

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

---

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire material may emit toxic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

---

SECTION 6: Accidental Release Measures
   Small spills may be mixed with diatomaceous earth, sand, vermiculite, or other suitable inert material and
   Spill and Leak Procedures:
   swept up.

---

SECTION 7: Handling and Storage
   Handling and Storage:       Store and handle the product under an inert atmosphere of nitrogen or argon.`Store cold.    

---

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

---

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow liquid    
   Molecular Weight:       456.45    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       no data    
   Solubility in Water:       insoluble    

---

SECTION 10: Stability and Reactivity
   Stability:       air sensitive (store cold)    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       exposure to air or water    
   Incompatibility:       air, water, oxidizing agents, active metals    
   Decomposition Products:       carbon monoxide, carbon dioxide, organic fumes, hydrogen fluoride, and silver salts.    

---

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

---

SECTION 12: Ecological Information
   Ecological Information:       No information available    

---

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

---

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

---

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See category N740 for reporting.    
   Second Ingredient:       None    

---

SECTION 16 - ADDITIONAL INFORMATION
N/A