2-[2-(2-乙基己氧基)乙氧基]乙醇

2-[2-(2-乙基己氧基)乙氧基]乙醇 基本信息
CAS号 19327-37-8 分子式 C12H26O3
分子量 218.33300 精确质量  218.18800
PSA  38.69000 LogP  2.37240

基本信息 展开↓

CAS号:
19327-37-8
分子式:
C12H26O3
分子量:
218.33300
中文名称:
2-[2-(2-乙基己氧基)乙氧基]乙醇
英文名称:
2-(2-octoxyethoxy)ethanol
中文别名:
2-[2-(2-乙基己氧基)乙氧基]乙醇;
n-辛基-二氧乙烯
英文别名:
2-(2-octoxyethoxy)ethanol;
Diethylene glycol monooctyl ether;
O-Octyl-diaethylenglykol;
C8E2;
Octyldiglycol;
n-octyl diglycol
精确分子量/精确质量:
218.18800
极性分子表面积/PSA:
38.69000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。

物化性质展开↓

密度:
0.919 g/mL at 20ºC(lit.)
沸点:
102ºC (0.4 mmHg)
闪点:
136ºC
折射率:
n20/D 1.441
蒸汽压:
6.59E-05mmHg at 25°C

安全信息展开↓

海关代码:
2909499000
危险类别码:
R19;R36/38
安全说明:
S24/25-S28
安全标志:
S28:接触皮肤之后,立即使用大量皂液洗涤。
S24/25:防止皮肤和眼睛接触。
危险标志:
Xi: Irritant;

合成路线查看所有的合成路线

  • 107-07-3

    2-氯乙醇

  • 19327-37-8

    2-[2-(2-乙基己氧基)乙氧基]乙醇

  • 75-21-8

    环氧乙烷

  • +

  • 111-87-5

    正辛醇

  • 19327-37-8

    2-[2-(2-乙基己氧基)乙氧基]乙醇

  • 111-85-3

    正辛基氯

  • +

  • 111-46-6

    二乙二醇

  • 19327-37-8

    2-[2-(2-乙基己氧基)乙氧基]乙醇

MSDS 展开↓

Name: N-Octyl-Dioxyethylene Material Safety Data Sheet
Synonym: Diethylene Glycol Monooctyl Ether; C8E
CAS: 19327-37-8
Section 1 - Chemical Product   MSDS Name:N-Octyl-Dioxyethylene Material Safety Data Sheet
Synonym:Diethylene Glycol Monooctyl Ether; C8E

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
19327-37-8 N-Octyl-Dioxyethylene ca 100 unlisted
Hazard Symbols: XI
Risk Phrases: 19 36/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
May form explosive peroxides. Irritating to eyes and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Isolate area and deny entry. Provide ventilation. Place under an inert atmosphere.

Section 7 - HANDLING and STORAGE
  Handling:
Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. If peroxide formation is suspected, do not open or move container. Avoid contact with air and sunlight. Unused chemicals should not be returned to the container. Do not distill since this removes peroxide-inhibitors.
Storage:
Do not store in direct sunlight. Store in a cool, dry, well-ventilated area away from incompatible substances. Deep freeze (below -20C). Regularly check inhibitor levels to maintain peroxide levels below 1%. Do not break the seal on the container until it is needed. Label the container with the date it was first opened.
Long-term storage is not recommended.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 19327-37-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear almost colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 102 deg C @ .40mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 136 deg C ( 276.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .9170g/cm3
Molecular Formula: C12H26O3
Molecular Weight: 218.30

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
On long term storage, substances with similar functional groups form explosive peroxides. Explosive peroxides may form on concentration.
Peroxides can be detonated by friction, impact, or heating. Tends to form explosive peroxides; especially when anhydrous. Peroxide formation may occur in containers that have been opened and remain in storage.
Conditions to Avoid:
Incompatible materials, exposure to air, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 19327-37-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-Octyl-Dioxyethylene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 19 May form explosive peroxides.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 19327-37-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 19327-37-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 19327-37-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2909499000

概述:
2909499000 其他醚醇及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

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