N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺

N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺 基本信息
CAS号 376355-58-7 分子式 C28H26NO2P
分子量 439.48500 精确质量  439.17000
PSA  29.52000 LogP  8.75040

基本信息 展开↓

CAS号:
376355-58-7
3D弹球模型:
立即前往扯扯看
分子式:
C28H26NO2P
分子量:
439.48500
中文名称:
N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺
英文名称:
N,N-bis[(1S)-1-phenylethyl]benzo[d][1,3,2]benzodioxaphosphepin-6-amine
中文别名:
N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺;
N,N-双[(1S)-(-)-苯乙基]二苯并[D,F][1,3,2]二氧磷杂七环-6-胺;
N,N-二[(1S)-1-苯基乙基]-二苯并[D,F][1,3,2]二氧杂磷杂卓-6-胺;
(S,S)-N-(5,7-二氧杂-6-磷杂二苯并[A,C]环庚烯-6-基)双(1-苯乙基)胺;
N,N-双-((S)-1-苯基乙基)二苯并[D,F][1,3,2]二氧杂膦-6-胺;
O,O′-(2,2′-联苯二基)N,N-双[(S)-1-苯基乙基]亚磷酰胺
英文别名:
N,N-bis[(1S)-1-phenylethyl]benzo[d][1,3,2]benzodioxaphosphepin-6-amine;
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;
BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite;
N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;
N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;
1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;
N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;
Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
精确分子量/精确质量:
439.17000
极性分子表面积/PSA:
29.52000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: JISGHECLGYELKD-VXKWHMMOSA-N

物化性质展开↓

熔点:
99-102ºC
沸点:
578.426ºC at 760 mmHg
闪点:
303.621ºC

合成路线查看所有的合成路线

  • 16611-68-0

    6-chlorodibenzo[d,f][1,3,2]dioxaphosphepine

  • +

  • 21003-56-5

    21003-56-5

  • ~91%

  • 376355-58-7

    N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺

  • 21003-56-5

    21003-56-5

  • 376355-58-7

    N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺

  • 1806-29-7

    2,2'-二羟基联苯

  • +

  • 777067-25-1

    [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride

  • 376355-58-7

    N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine    
   CAS Registry Number:       376355-58-7    
   Formula:       C28H26NO2P    
   EINECS Number:       none    
   Chemical Family:       phosphine-amine ligand    
   Synonym:       (5,7-Dioxa-6-phospha-dibenzo[a,c]cyclohepten-6-yl)-bis-(1(S)-(-)--phenyl-ethyl)-amine    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       376355-58-7       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin. Dust may be irritating to eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   The material will degrade on prolonged exposure to moisture. Store under an inert atmosphere of nitrogen or
   Handling and Storage:
   argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white powder    
   Molecular Weight:       439.49    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       prolonged exposure to moisture    
   Incompatibility:       oxidizing agents and halogens    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

上下游相关产品

上游产品

更多
  • 16611-68-0

    6-chlorodibenzo[d,f][1,3,2]dioxaphosphepine

  • 1806-29-7

    2,2'-二羟基联苯

  • 777067-25-1

    [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride

立即下载安装“化学加”APP
专业、功能强大,随时调用更加方便