高纯三甲基铟

高纯三甲基铟 基本信息
CAS号 3385-78-2 分子式 C3H9In
分子量 159.92200 精确质量  159.97400
PSA  0.00000 LogP  1.75140

基本信息 展开↓

CAS号:
3385-78-2
3D弹球模型:
立即前往扯扯看
分子式:
C3H9In
分子量:
159.92200
中文名称:
高纯三甲基铟
英文名称:
trimethylindigane
中文别名:
高纯三甲基铟;
三甲基铟;
三甲基銦;
三甲基铟(TMI)
英文别名:
trimethylindigane;
Trimethylindium;
Trimethylindane;
Indium,trimethyl
精确分子量/精确质量:
159.97400
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
222-200-9
InChI:
The Key: IBEFSUTVZWZJEL-UHFFFAOYSA-N

生产制备方法及用途展开↓

合成制备方法


以In和Mg为原料与CH3I反应,经解络、分馏等纯化手段可制得高纯三甲基铟。

用途


主要用作金属有机化学气相沉积(MOCVD)工艺外延生长磷化铟和其他含铟化合物半导体光电功能材料的原材料。

物化性质展开↓

外观与性状:
白色晶体
密度:
1.568 g/cm3
熔点:
88ºC
闪点:
-18ºC
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:常温常压下为无色透明,具有特殊臭味的升华性无色结晶。

2.       密度(g/mL,25/4℃):1.568

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):88

5.       沸点(ºC,常压):134

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):-18

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

安全信息展开↓

风险类别:
4.2
海关代码:
2931900090
危险类别码:
14-17-34
安全说明:
7-16-43-45
安全标志:
S7:保持容器紧密封闭。
S16:远离火源。
S43:灭火时使用...(某种合适的灭火装置名称)。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。

合成路线查看所有的合成路线

  • 10025-82-8

    氯化铟

  • +

  • 7439-95-4

  • +

  • 74-88-4

    甲基碘

  • ~91%

  • 3385-78-2

    高纯三甲基铟

  • 331815-64-6

    hexakis(trimethylindium) 1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane adduct

  • 3385-78-2

    高纯三甲基铟

  • 329955-33-1

    trimethylindium bis(N,N,N',N'-tetramethyl-4,4'-methylenebis(aniline)) adduct

  • 3385-78-2

    高纯三甲基铟

毒理性展开↓

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Trimethylindium, elec. gr. (99.999%-In) PURATREM **S STEEL CYL EXTRA** **Can be ampouled**    
   CAS Registry Number:       3385-78-2    
   Formula:       (CH3)3In    
   EINECS Number:       222-200-9    
   Chemical Family:       metal alkyl    
   Synonym:       Indium, trimethyl    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       3385-78-2       100%       0.1mg/m3 (as In)       no data    

Section 3: Hazards Identification
   Pyrophoric material. Ignites spontaneously on contact with air causing thermal burns. Burning solid/liquid
   Emergency Overview:
   clings to clothing and skin.
   Primary Routes of Exposure:       Inhalation, skin, eyes    
   Eye Contact:       Dust causes severe thermal burns to eyes. Irritating fumes.    
   Skin Contact:       Solid ignites. Hard to extinguish burning gel on the skin and clothing.    
   White fumes from burning solid irritating to the tissues of the nose, mucous membranes, and respiratory tract.
   Inhalation:
   Ingestion:       Ingestion of burning solid is unlikely.    
   Solid is pyrophoric and bursts into flames causing severe thermal burns. Dense white smoke is irritating to
   Acute Health Affects:
   skin, eyes and respiratory tract.
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       -1°F    
   Autoignition Temperature:       pyrophoric    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes of indium oxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Pyrophoric material. Material will ignite spontaneously in contact with air.

SECTION 6: Accidental Release Measures
   The material will ignite spontaneously in air. Burning material may release toxic fumes. Leave the area unless
   Spill and Leak Procedures:
   fitted with a self-contained breathing apparatus. Smother fire with dry powder. Do not use water.

SECTION 7: Handling and Storage
   Store cold. Handle and store the material under an inert atmosphere of nitrogen or argon. Prepare for the
   Handling and Storage:
   possibility of fire in transfer lines and containers after use. Keep away from heat.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       Wear a full face shield, lab apron and suitable gloves.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       159.92    
   Melting Point:       88°    
   Boiling Point:       136°C    
   Vapor Pressure:       no data    
   Specific Gravity:       1.568    
   Odor:       none    
   Solubility in Water:       reacts vigorously with water    

SECTION 10: Stability and Reactivity
   Stability:       heat sensitive, moisture sensitive, pyrophoric    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with air    
   Incompatibility:       oxygen, halogens, oxidizing agents and water    
   Decomposition Products:       carbon dioxide, carbon monoxide, indium oxide, organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Organometallic substance, Solid,Pyrophoric,Water-reactive    
   Hazard Class (CFR):       4.2    
   Additional Hazard Class (CFR):       4.3    
   Packaging Group (CFR):       I    
   UN ID Number (CFR):       UN# 3393    
   Shipping Name (IATA):       Forbidden    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       UN# 3393    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:4

8.表面电荷:0

9.复杂度:8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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