1,2-二(三氯甲硅基)乙烷

1,2-二(三氯甲硅基)乙烷 基本信息
CAS号 2504-64-5 分子式 C2H4Cl6Si2
分子量 296.94200 精确质量  293.79800
PSA  0.00000 LogP  4.29700

基本信息 展开↓

CAS号:
2504-64-5
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分子式:
C2H4Cl6Si2
分子量:
296.94200
中文名称:
1,2-二(三氯甲硅基)乙烷
英文名称:
trichloro(2-trichlorosilylethyl)silane
中文别名:
1,2-二(三氯甲硅基)乙烷;
1,1,1,4,4,4-六氯二甲硅基乙烯;
1,2-双(三氯甲硅基)乙烷;
1,2-二(三氯甲硅烷基)乙烷;
1,2-双(三氯硅基)乙烷
英文别名:
trichloro(2-trichlorosilylethyl)silane;
hexa-Si-chloro-Si,Si'-ethanediyl-bis-silane;
1,1,1,4,4,4-hexachloro-1,4-disilabutane;
1,2-BIS(TRICHLOROSILYL)ETHANE;
ethane-1,2-diylbis(trichlorosilane);
hexachlorodisilethylene;
hexachloroethylenedisilane;
Ethylenebis(trichlorosilane);
Silane,1,2-ethanediylbis(trichloro;
1,2-Bis(trichlorosilyl)ethane;
1,1,1,4,4,4-Hexachlorodisilethylene
精确分子量/精确质量:
293.79800
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00013601
EINECS:
219-710-9
PubChem:
24868315
BRN:
1753707
InChI:
The Key: WDVUXWDZTPZIIE-UHFFFAOYSA-N

物化性质展开↓

密度:
1.483 g/mL at 25 °C(lit.)
熔点:
27-29 °C(lit.)
沸点:
202 °C(lit.)
闪点:
149 °F
折射率:
n20/D 1.475(lit.)
蒸汽压:
0.492mmHg at 25°C
其它信息:

1.      性状:未确定

2.      密度(g/mL, ,25℃):1.483

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):27-29

5.      沸点(ºC,常压):202

6.      沸点(ºC  0.3mmHg):未确定

7.      折射率n20/D):1.475

8.      闪点(ºC65

9.      比旋光度():未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(Pa,20ºC):未确定

12.   饱和蒸气压(kPa, 0ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

安全信息展开↓

WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R14
安全说明:
S26-S36/37/39-S43-S45
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S43:灭火时使用...(某种合适的灭火装置名称)。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C: Corrosive;

合成路线查看所有的合成路线

  • 75-94-5

    乙烯基三氯硅烷

  • ~94%

  • 2504-64-5

    1,2-二(三氯甲硅基)乙烷

  • 5283-66-9

    辛基三氯硅烷

  • +

  • 107-06-2

    1,2-二氯乙烷

  • ~52%

  • 2504-64-5

    1,2-二(三氯甲硅基)乙烷

  • 74-86-2

    乙炔

  • ~49%

  • 2504-64-5

    1,2-二(三氯甲硅基)乙烷

化学图谱

  1. 1,2-二(三氯甲硅基)乙烷红外图谱(IR1)

  2. 1,2-二(三氯甲硅基)乙烷质谱(MS)

  3. 1,2-二(三氯甲硅基)乙烷核磁图(13CNMR)

  4. 1,2-二(三氯甲硅基)乙烷核磁图(1HNMR)

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MSDS 展开↓


Section I.Chemical Product and Company Identification
    Chemical Name 1,2-Bis(trichlorosilyl)ethane
    Portland OR
    Synonym        Silane, 1,1'-(1,2-ethanediyl)bis[1,1,1-trichloro- (CA    
    INDEX NAME)
    Chemical Formula        C2H4Cl6Si2    
    2504-64-5
    CAS Number

Section II.        Composition and Information on Ingredients    
    Chemical Name        CAS Number Percent (%)        TLV/PEL        Toxicology Data    
    1,2-Bis(trichlorosilyl)ethane        2504-64-5        Min. 95.0 (T) Not available.        Not available.    

Section III. Hazards Identification
    Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous
    Acute Health Effects
    membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal
    damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
    coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
    CARCINOGENIC EFFECTS : Not available.
    Chronic Health Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or
    prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.

Section IV.        First Aid Measures    
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15    
    minutes. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing    
    before reuse. Thoroughly clean shoes before reuse. Get medical attention.
    Inhalation        If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
    improve.
    Ingestion        DO NOT INDUCE VOMITING. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing,    
    perform mouth-to-mouth resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible
    indication that the toxic material was ingested; the absence of such signs, however, is not conclusive.

Section V.        Fire and Explosion Data    
    200°C (392°F)
    Auto-Ignition
    Flammability        May be combustible at high temperature.    
    Flammable Limits        Not available.    
    Flash Points        78°C (172.4°F).    
    Combustion Products        These products are toxic carbon oxides (CO, CO2), halogenated compounds. Silicates.    
    WARNING: Highly toxic HCl gas is produced during combustion.
    Fire Hazards        Not available.    
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards
    Risks of explosion of the product in presence of static discharge: Not available.
    Fire Fighting Media        SMALL FIRE: Use DRY chemical powder.    
    and Instructions        LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.    
    Consult with local fire authorities before attempting large scale fire-fighting operations.
    Continued on Next Page
    1,2-Bis(trichlorosilyl)ethane

Section VI.        Accidental Release Measures    
    Spill Cleanup        Corrosive material. Moisture sensitive material.    
    Stop leak if without risk. If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal
    Instructions
    container. If the product is in its liquid form: Absorb with DRY earth, sand or other non-combustible material. DO NOT get
    water inside container. Absorb with an inert material and put the spilled material in an appropriate waste disposal. DO NOT
    touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas;
    dike if needed. Eliminate all sources of ignition. Consult federal, state, and/or local authorities for assistance on disposal.

Section VII. Handling and Storage
    CORROSIVE. MOISTURE SENSITIVE. HANDLE AND STORE UNDER ARGON. Keep container dry. Keep away from
    Handling and Storage
    heat. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool place. Avoid
    Information
    excessive heat and light. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. Wear suitable protective
    clothing. If you feel unwell, seek medical attention and show the label when possible. Treat symptomatically and
    supportively.
    Always store away from incompatible compounds such as oxidizing agents, moisture.

Section VIII. Exposure Controls/Personal Protection
    Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
    Engineering Controls
    threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
    Face shield. Lab coat. Dust respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
    Personal Protection
    specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
    Not available.
    Exposure Limits

Section IX. Physical and Chemical Properties
    Physical state @ 20°C        Liquid. (White, lumps.)        Solubility    
    Not available.
    1.483 (water=1)
    Specific Gravity
    Molecular Weight        296.94        Partition Coefficient        Not available.    
    Boiling Point        Not available.        Vapor Pressure        <0.13 kPa (@ 25°C)    
    28°C (82.4°F) (freezing point)        Not available.    
    Melting Point        Vapor Density    
    Refractive Index        Not available.        Volatility        Not available.    
    Not available.        Not available.    
    Critical Temperature        Odor    
    Not available.        Not available.    
    Viscosity        Taste    

Section X.        Stability and Reactivity Data    

This material is stable if stored under proper conditions. (See Section VII for instructions)
    Stability
    Conditions of Instability        Avoid excessive heat and light. Moisture sensitive.    
    Incompatibilities
    Reactive with strong oxidizing agents, moisture.

Section XI. Toxicological Information
    Not available.
    RTECS Number
    Eye Contact. Ingestion. Inhalation. Skin contact.
    Routes of Exposure
    Not available.
    Toxicity Data
    Chronic Toxic Effects        CARCINOGENIC EFFECTS : Not available.    
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or
    prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
    Acute Toxic Effects        Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous    
    membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal
    damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
    coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
    Continued on Next Page
    1,2-Bis(trichlorosilyl)ethane

Section XII.        Ecological Information    
    Ecotoxicity        Not available.    
    Not available.
    Environmental Fate

Section XIII. Disposal Considerations
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
    Waste Disposal
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
    DOT Classification        DOT Class 8: Corrosive material    
    PIN Number
    Proper Shipping Name        Chlorosilanes, corrosive, n.o.s.    
    II
    Packing Group (PG)
    DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.    
    (EPA)
    WHMIS Classification        CLASS E: Corrosive liquid.    
    On NDSL
    (Canada)
    EINECS Number (EEC) 219-710-9
    EEC Risk Statements        R34- Causes burns.    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1   摩尔折射率:57.84

2   摩尔体积(m3/mol):201.3

3   等张比容(90.2K):460.6

4   表面张力(dyne/cm):27.4

5 极化率(10-24cm3):22.93

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:10

8.表面电荷:0

9.复杂度:87.3

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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