cas号： 15522-71-1 ，名称：三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III) 的性质/作用/用途-化学加百科

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III) 基本信息
CAS号	15522-71-1	分子式	C33H60EuO6
分子量	704.79000	精确质量	705.36000
PSA	102.42000	LogP	7.82070

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基本信息物化性质安全信息合成路线化学图谱毒性 MSDS 海关数据结构与计算数据上下游

基本信息展开↓

CAS号：: 15522-71-1
3D弹球模型：: 立即前往扯扯看
分子式：: C33H60EuO6
分子量：: 704.79000
中文名称：: 三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)
英文名称：: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III)
中文别名：: 三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III);
三(2,2,6,6-四甲基-3,5-庚二酮酸)铕;
三(2,2,6,6-四甲基-3,5-庚二酸)铕
英文别名：: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III);
Europium(III)-tris-(2,2,6,6-tetramethyl-3,5-heptanedionate);
Tris(2,2,6,6-tetraMethyl-3,5-heptanedionato)europiuM(III);
Europium tris(2,2,6,6-tetramethyl-3,5-heptanedionate);
Europium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)
精确分子量/精确质量：: 705.36000
极性分子表面积/PSA：: 102.42000
油水分配系数/LogP：: LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值，反映了物质在油水两相中的分配情况。其中、LogP值越大，说明该物质越亲油；反之，LogP值越小，则说明该物质越亲水。
贝尔斯坦号/MDL：: MFCD00000019
EINECS：: 239-565-5
InChI：: InChI=1/3C11H20O2.Eu/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;

物化性质展开↓

熔点：: 188-89ºC
沸点：: 275ºC
闪点：: 109.7ºC
蒸汽压：: 0.00138mmHg at 25°C
存储条件/存储方法：: 常温密闭避光，通风干燥
稳定性相关：: 常温常压下稳定

避免的物料：水分/潮湿氧化物酸
其它信息：: 1. 性状：未确定

2. 密度（g/mL,25/4℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：未确定

4. 熔点（ºC）：187-191

5. 沸点（ºC,常压）：275

6. 沸点（ºC,5.2kPa）：未确定

7. 折射率：未确定

8. 闪点（ºC）：未确定

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（kPa,25ºC）：未确定

12. 饱和蒸气压（kPa,60ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：未确定

安全信息展开↓

海关代码：: 2914509090
危险类别码：: R36/37/38
安全说明：: S26-S36/37/39
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

合成路线查看所有的合成路线

499204-17-0

499204-17-0
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15522-71-1

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)

化学图谱

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕红外图谱(IR1)
三(2,2,6,6-四甲基-3,5-庚二酮酸)铕红外图谱(IR2)

MSDS 展开↓

  Tris(2,2,6,6-tetramethyl-3,5-      Revision number: 5
  heptanedionato)europium(III) [NMR Shift Reagent]
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) [NMR Shift Reagent]

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None
  Signal word        No signal word
  Hazard statements        None
  Precautionary statements:        None

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Substance
  Substance/mixture:
  Components:        Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) [NMR Shift Reagent]
    ....
  Percent:
  CAS Number:        15522-71-1
    Eu(dpm)3 , Europium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)
  Synonyms:
  Chemical Formula:        C33H57EuO6

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
    Get medical advice/attention if you feel unwell. Rinse mouth.
  Ingestion:
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water spray, carbon dioxide.
  Suitable extinguishing
  media:
  Tris(2,2,6,6-tetramethyl-3,5-
  heptanedionato)europium(III) [NMR Shift
  Reagent]

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store under inert gas.
    Protect from moisture.
    Store away from incompatible materials such as oxidizing agents.
    Hygroscopic
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
    Crystal- Powder
  Form:
  Colour:        Pale yellow - Yellow
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:190°C
  Boiling point/range:        No data available
    No data available
  Flash point:
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        No data available
  Solubility(ies):
  Tris(2,2,6,6-tetramethyl-3,5-
  heptanedionato)europium(III) [NMR Shift
  Reagent]

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
[Water] No data available
[Other solvents] No data available

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
    No data available
  Crustacea:
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
    No data available
  Henry's Law
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Tris(2,2,6,6-tetramethyl-3,5-
  heptanedionato)europium(III) [NMR Shift
  Reagent]

SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码：2914509090

概述：: 2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%
申报要素：: 品名, 成分含量, 用途, 丙酮报明包装
摘要/Summary：: HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

分子结构与计算化学数据展开↓

计算化学数据

1、疏水参数计算参考值（XlogP）：

2、氢键供体数量：0

3、氢键受体数量：6

4、可旋转化学键数量：12

5、互变异构体数量：4

6、拓扑分子极性表面积（TPSA）：102

7、重原子数量：40

8、表面电荷：0

9、复杂度：189

10、同位素原子数量：0

11、确定原子立构中心数量：0

12、不确定原子立构中心数量：0

13、确定化学键立构中心数量：0

14、不确定化学键立构中心数量：0

15、共价键单元数量：4

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