FMOC-L-苯丙氨酸五氟苯酯

FMOC-L-苯丙氨酸五氟苯酯 基本信息
CAS号 86060-92-6 分子式 C30H20F5NO4
分子量 553.47600 精确质量 　553.13100
PSA 　64.63000 LogP 　6.82840
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目录
基本信息 物化性质 安全信息 合成路线 毒性 MSDS 上下游

基本信息 展开↓

CAS号：
86060-92-6
3D弹球模型：
立即前往扯扯看
分子式：
C30H20F5NO4
分子量：
553.47600
中文名称：
FMOC-L-苯丙氨酸五氟苯酯
英文名称：
(2,3,4,5,6-pentafluorophenyl) (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-phenylpropanoate
中文别名：
FMOC-L-苯丙氨酸五氟苯酯;
N-芴甲氧羰基-L-苯丙氨酸五氟苯酯
英文别名：
(2,3,4,5,6-pentafluorophenyl) (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-phenylpropanoate;
N-(9-Fluorenylmethoxycarbonyl)-L-phenylalanine pentafluorophenyl ester;
Fmoc-Phe-OC6F5;
Fmoc-phenylalanine pentafluorophenyl ester;
Fmoc-L-phenylalanine pentafluorophenyl ester;
Fmoc-D-Phe-OPfp;
Fmoc-L-Phe-OPfp;
Fmoc-Phe pentafluorophenyl ester;
Fmoc-Phe-OPfp
精确分子量/精确质量：
553.13100
极性分子表面积/PSA：
64.63000
油水分配系数/LogP：

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值，反映了物质在油水两相中的分配情况。其中、LogP值越大，说明该物质越亲油；反之，LogP值越小，则说明该物质越亲水。
贝尔斯坦号/MDL：
MFCD00065669
PubChem：
24871042
BRN：
4241247
InChI：
InChI=1/C30H20F5NO4/c31-23-24(32)26(34)28(27(35)25(23)33)40-29(37)22(14-16-8-2-1-3-9-16)36-30(38)39-15-21-19-12-6-4-10-17(19)18-11-5-7-13-20(18)21/h1-13,21-22H,14-15H2,(H,36,38)/t22-/m0/s1

物化性质展开↓

外观与性状：
白色晶体
密度：
1.399g/cm3
熔点：
149-151 °C(lit.)
沸点：
674.8ºC at 760 mmHg
闪点：
361.9ºC
折射率：
1.588
存储条件/存储方法：

2-8°C冷藏、密闭、干燥处

稳定性相关：

按规定使用和贮存的不会分解，避氧化物

其它信息：

1.      性状：白色粉末

2.      密度（g/mL25 ºC）：未确定

3.      相对蒸汽密度（g/mL,空气=1）：未确定

4.      熔点（ºC）：149-151

5.      沸点（ºC,常压）：未确定

6.      沸点（ºC0.35mmHg）：未确定

7.      折射率：未确定

8.      闪点（ºF）：未确定

9.      比旋光度（º）：未确定

10.   自燃点或引燃温度（ºC）：未确定

11.   蒸气压（kPa,）：未确定

12.   饱和蒸气压（kPa,60ºC）：未确定

13.   燃烧热（KJ/mol）：未确定

14.   临界温度（ºC）：未确定

15.   临界压力（KPa）：未确定

16.   油水（正辛醇/水）分配系数的对数值：未确定

17.   爆炸上限（%,V/V）：未确定

18.   爆炸下限（%,V/V）：未确定

19.   溶解性：未确定

安全信息展开↓

WGK_Germany：
3
德国有关水污染物质的分类清单
安全说明：
S22-S24/25
安全标志：
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。

合成路线查看所有的合成路线

  • 35661-40-6

    Fmoc-L-苯丙氨酸

  • +

  • 96157-57-2

    2,3,4,5,6-pentafluorophenol,sulfurous acid

  • →

    ~93%

  • 86060-92-6

    FMOC-L-苯丙氨酸五氟苯酯

  • 771-61-9

    五氟苯酚

  • +

  • 35661-40-6

    Fmoc-L-苯丙氨酸

  • →

    ~93%

  • 86060-92-6

    FMOC-L-苯丙氨酸五氟苯酯

  • 35661-40-6

    Fmoc-L-苯丙氨酸

  • +

  • 244633-31-6

    (2,3,4,5,6-pentafluorophenyl) 4-nitrobenzenesulfonate

  • →

    ~88%

  • 86060-92-6

    FMOC-L-苯丙氨酸五氟苯酯

毒理性展开↓

生态数据：

 

MSDS 展开↓

Name: N-(9-Fluorenylmethoxycarbonyl)-L-Phenylalanine Pentafluorophenyl Material Safety Data Sheet
Synonym: None
CAS: 86060-92-6
Section 1 - Chemical Product   MSDS Name:N-(9-Fluorenylmethoxycarbonyl)-L-Phenylalanine Pentafluorophenyl Material Safety Data Sheet
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
86060-92-6 N-(9-Fluorenylmethoxycarbonyl)-L-pheny ca 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 86060-92-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 151 - 152 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C30H20F5NO4
Molecular Weight: 553.49
Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 86060-92-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-(9-Fluorenylmethoxycarbonyl)-L-phenylalanine pentafluoroph - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
 
Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 86060-92-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 86060-92-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 86060-92-6 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

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